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フェンクロルホス

フェンクロルホス 化学構造式
299-84-3
CAS番号.
299-84-3
化学名:
フェンクロルホス
别名:
コルラン;ビオゼン;チオりん酸O,O-ジメチルO-(2,4,5-トリクロロフェニル);ナンコール;O,O-ジメチル-O-(2,4,5-トリクロロフェニル)ホスフォロチオエート;トロレン;コルラン【農薬】;フェンクロルホス;ホスホロチオ酸O-(2,4,5-トリクロロフェニル)O,O-ジメチル;ロンネル;チオりん酸ジメチル(2,4,5-トリクロロフェニル);フェンクロルホス標準品;チオりん酸O,O‐ジメチル‐O‐(2,4,5‐トリクロロフェニル) (別名 ロンネル);フェンクロルホス標準液;ロンネル STANDARD;ロンネル Standard, 100 µg/mL in MeOH;ロンネル, 1000 µg/mL in Hexane
英語化学名:
FENCHLORPHOS
英語别名:
et14;et57;Ronne;Rovan;smear;ET 14;ET 57;RONNEL;Blitex;Karlan
CBNumber:
CB4233642
化学式:
C8H8Cl3O3PS
分子量:
321.55
MOL File:
299-84-3.mol

フェンクロルホス 物理性質

融点 :
41.0℃
沸点 :
97℃
比重(密度) :
1.485 g/cm3 (25 ºC)
蒸気圧:
5.29 at 20 °C, 18.6 at 30 °C (Freed et al., 1977)
屈折率 :
1.5585 (589.3 nm 20℃)
闪点 :
-18 °C
貯蔵温度 :
APPROX 4°C
溶解性:
Soluble in acetone, carbon tetrachloride, ether, kerosene, methylene chloride, and toluene (Windholz et al., 1983)
外見 :
solid
色:
White to light brown, waxy solid
Merck :
13,8337
BRN :
1885571
Henry's Law Constant:
8.46 at 25 °C (approximate - calculated from water solubility and vapor pressure)
暴露限界値:
NIOSH REL: TWA 10 mg/m3, IDLH 300 mg/m3; OSHA PEL: TWA 15 mg/m3; ACGIH TLV: TWA 10 mg/m3.
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  Xn,N,F
Rフレーズ  21/22-50/53-67-65-38-11
Sフレーズ  25-36/37-60-61-62
RIDADR  UN 1145 3/PG 2
WGK Germany  3
RTECS 番号 TG0525000
HSコード  29201900
毒性 LD50 in male, female rats (mg/kg): 1250, 2630 orally (Gaines)
消防法 危-4-1-II
安衛法 57,57-2
絵表示(GHS)
注意喚起語 Warning
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P501 内容物/容器を...に廃棄すること。

フェンクロルホス 価格 もっと(9)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-080N ロンネル
Ronnel
299-84-3 10mg ¥4400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-8140-17 ロンネル
Ronnel, 1000 ug/mL in Hexane
299-84-3 1mL ¥7400 2018-12-26 購入
関東化学株式会社(KANTO) 49827-46 フェンクロルホス標準品
Fenchlorphos standard
299-84-3 100mg ¥12000 2018-12-13 購入
関東化学株式会社(KANTO) 49864-91 フェンクロルホス標準液
Fenchlorphos standard solution
299-84-3 10mL ¥13000 2018-12-13 購入
Sigma-Aldrich Japan 45485 フェンクロルホス PESTANAL?, analytical standard
Fenchlorphos PESTANAL?, analytical standard
299-84-3 100mg ¥11000 2018-12-25 購入

フェンクロルホス 化学特性,用途語,生産方法

外観

白色, 結晶~結晶性粉末

溶解性

水に不溶(44mg/l)。有機溶剤に可溶。アセトンに溶け、水にほとんど溶けない。

用途

農薬?殺虫剤

効能

殺虫薬

農薬用途

動物薬、殺虫剤

使用上の注意

不活性ガス封入

化学的特性

Powder or granules. Insoluble in water; soluble in most organic solvents.

化学的特性

Ronnel is a white to light tan crystalline solid.

使用

Insecticide.

一般的な説明

White to light-tan crystalline solid. Mp: 41° C, Density :1.49 g cm-3 at 25°C. Biocidal (toxic to all animal life in differing degrees) by its action as a cholinesterase inhibitor. Used as an insecticide. Degrades readily in the environment by hydrolysis and oxidation.

反応プロフィール

FENCHLORPHOS is non-flammable and non-combustible. Decomposes with heating to evolve toxic and corrosive vapors (hydrogen chloride, phosphorus oxides, sulfur oxides). Incompatible with strong oxidizing agents.

危険性

Toxic by ingestion and inhalation. Cholinesterase inhibitor, use may be restricted. Questionable carcinogen.

安全性プロファイル

Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. A cholinesterase inhibitor. An experimental teratogen. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of Cl-, POx, and SOx. See also PARATHION and CHLOROPHENOLS.

職業ばく露

Ronnel is both an organochlorine and organophosphorus compound; potential danger to those involved in manufacture, formulation and application of this insecticide for farm (livestock) and household uses. Degrades readily in the environment by hydrolysis and oxidation .

環境運命予測

Chemical/Physical. Though no products were identified, the reported hydrolysis halflife at pH 7.4 and 70°C using a 1:4 ethanol/water mixture is 10.2–10.4 hours (Freed et al., 1977). Ronnel decomposed at elevated temperatures on five clay surfaces, each treated with hydrogen, calcium, magnesium, aluminum and iron ions. At temperatures <950°C (125, 300 and 750°C), bentonite clays impregnated with technical ronnel (18.6 wt %) decomposed to 2,4,5-trichlorophenol and a rearrangement product tentatively identified as O-methyl S-methyl-O-(2,4,5-trichlorophenyl) phosphorothioate (Rosenfield and Van Valkenburg, 1965). At 950°C, only the latter product formed. It was postulated that this compound resulted from an acid-catalyzed molecular rearrangement reaction. Ronnel also undergoes base-catalyzed hydrolysis at elevated temperatures. Products include methanol and a new compound that is formed via cleavage of a methyl group from one of the methoxy groups, which is then bonded to the sulfur atom (Rosenfield and Van Valkenburg, 1965).
Ronnel is stable to hydrolysis over the pH range of 5–6 (Mortland and Raman, 1967). However, in the presence of a Cu(II) salt (as cupric chloride) or when present as the exchangeable Cu(II) cation in montmorillonite clays, ronnel is completely hydrolyzed via first-order kinetics in <24 hours at 20°C. The calculated half-life of ronnel at 20°C for this reaction is 6.0 hours. It was suggested that decomposition in the presence of Cu(II) was a result of coordination of the copper atom through the oxygen or sulfur on the phosphorus atom resulting in the cleavage of the side chain containing the phosphorus atom forming O,O-ethyl-O-phosphorothioate and 1,2,4-trichlorobenzene (Mortland and Raman, 1967).
Emits very toxic fumes of chlorides, sulfur and phosphorus oxides when heated to decomposition (Lewis, 1990).

輸送方法

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

不和合性

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo- sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Store at temperatures <25-30℃. Organothiophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides

廃棄物の処理

Incineration with added flam- mable solvent in furnace equipped with afterburner and alkali scrubber . In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesti- cide containers. Must be disposed properly by following package label directions or by contacting your local or fed- eral environmental control agency, or by contacting your regional EPA office.

フェンクロルホス 上流と下流の製品情報

原材料

準備製品


フェンクロルホス 生産企業

Global( 51)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
Mainchem Co., Ltd.
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Hubei Jusheng Technology Co.,Ltd.
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027-59599243 sales@jushengtech.com CHINA 28236 58
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027-59338440 sales@guangaobio.com CHINA 23049 58
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028-86757656 aikeshiji@163.com China 9755 55
9ding chemical ( Shanghai) Limited 4009209199
86-021-52271987 sales@9dingchem.com China 22544 55
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 sale@aladdin-e.com China 24986 65

299-84-3(フェンクロルホス)キーワード:


  • 299-84-3
  • KORLAN(R)
  • ETROLENE
  • FENCHLORPHOS
  • DOW ET-14
  • RONNEL
  • RONNEL(R)
  • O,O-DIMETHYL O-(2,4,5-TRICHLOROPHENYL) PHOSPHOROTHIATE
  • O,O-DIMETHYL-O-[2,4,5-TRICHLOROPHENYL]-PHOSPHOROTHIOATE
  • NANKOR(R)
  • VIOZENE(R)
  • TROLENE
  • Blitex
  • Dermafos
  • Dermafosu
  • dermafosu(polish)
  • Dermaphos
  • Dimethyl (2,4,5-trichlorophenyl) phosphorothionate
  • Dimethyl O-(2,4,5-trichlorophenyl) thiophosphate
  • Dimethyl trichlorophenyl thiophosphate
  • dimethyltrichlorophenylthiophosphate
  • Fenchlorfosu
  • fenchlorfosu(polish)
  • Fenchlorophos
  • Fenclofos
  • Gesektin K
  • Karlan
  • Korlan
  • Korlane
  • Moor Man's Medicated Rid-Ezy
  • moorman’smedicatedrid-ezy
  • コルラン
  • ビオゼン
  • チオりん酸O,O-ジメチルO-(2,4,5-トリクロロフェニル)
  • ナンコール
  • O,O-ジメチル-O-(2,4,5-トリクロロフェニル)ホスフォロチオエート
  • トロレン
  • コルラン【農薬】
  • フェンクロルホス
  • ホスホロチオ酸O-(2,4,5-トリクロロフェニル)O,O-ジメチル
  • ロンネル
  • チオりん酸ジメチル(2,4,5-トリクロロフェニル)
  • フェンクロルホス標準品
  • チオりん酸O,O‐ジメチル‐O‐(2,4,5‐トリクロロフェニル) (別名 ロンネル)
  • フェンクロルホス標準液
  • ロンネル STANDARD
  • ロンネル Standard, 100 µg/mL in MeOH
  • ロンネル, 1000 µg/mL in Hexane
  • 防疫用殺虫剤
  • 駆虫薬
  • 有機リン系殺虫剤
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