ニトロオキシクロリド

ニトロオキシクロリド 化学構造式
14545-72-3
CAS番号.
14545-72-3
化学名:
ニトロオキシクロリド
别名:
次亜塩素酸ニトリル;ニトロキシクロリド;クロロニトラート;ニトロオキシクロリド;硝酸塩素;クロロ ニトラート
英語名:
Nitric acid chlorine salt
英語别名:
Chloronitrate;Nitroxychloride;Nitrooxy chloride;Nitryl hypochlorite;Nitric acid chlorine salt;Nitryl hypochlorite ((NO2)(ClO)) (9CI)
CBNumber:
CB52315691
化学式:
ClNO3
分子量:
97.46
MOL File:
14545-72-3.mol

ニトロオキシクロリド 物理性質

融点 :
-107°C
沸点 :
18°C
外見 :
Colorless to pale yellow, mobile liquid

安全性情報

ニトロオキシクロリド 価格

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入

ニトロオキシクロリド 化学特性,用途語,生産方法

定義

A compound that slows the rate of destruction of ozone.

調製方法

A refrigerated pocket-shaped receiver is used to sublime an excess of N2O5 directly onto Cl2O in a high vacuum. The receiver containing the Cl2O (equivalent to 5 ml of liquid) is placed in liquid nitrogen so that only the portion holding the Cl2O is cooled, and the N2O5 thus deposits on the Cl2O as a solid. After releasing the vacuum, the receiver is removed from the high-vacuum apparatus, closed off using a drying tube, and placed in a refrigerating bath at —78°C. While the bath is slowly warmed to between —20 and 0°C (over 15 hours), the components react slowly. The ClNO3 thus formed is still contaminated with chlorine (an impurity of the Cl2O) and excess N2O5. To eliminate the chlorine, which is difficult to separate, the reaction product is heated to 30°C in a water bath and refluxed for one hour. The upper half of the reaction vessel (serving as a condenser) is cooled by a ring-shaped cup filled with Dry Ice. The chlorine is volatilized in this procedure, while the excess N2O5 is decomposed to NO2 and O2. The ClNO3 is then distilled at — 90°C in a high vacuum, leaving behind the NO2.
Cl2O+N2O5=2ClNO3

危険性

Explosive reaction with metals, metal chlorides, alcohols, ethers, and most organic materials.

ニトロオキシクロリド 上流と下流の製品情報

原材料

準備製品


ニトロオキシクロリド 生産企業

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  • 14545-72-3
  • Chloronitrate
  • Nitric acid chlorine salt
  • Nitrooxy chloride
  • Nitroxychloride
  • Nitryl hypochlorite
  • Nitryl hypochlorite ((NO2)(ClO)) (9CI)
  • 次亜塩素酸ニトリル
  • ニトロキシクロリド
  • クロロニトラート
  • ニトロオキシクロリド
  • 硝酸塩素
  • クロロ ニトラート
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