五硫化リン

五硫化リン 化学構造式
1314-80-3
CAS番号.
1314-80-3
化学名:
五硫化リン
别名:
五硫化二りん;五硫化りん;十硫化四りん;硫化りん(V)
英語名:
Phosphorus pentasulfide
英語别名:
PHOSPHORUS SULFIDE;PHOSPHORUS PENTASULPHIDE;Phosphorous Pentasulfide;sulfurphosphide;Phosphorussulfid;sirnikfosforecny;Phosphoricsulfide;osphorus pentasulf;Phosphoric Sulphide;rcrawastenumberu189
CBNumber:
CB5853038
化学式:
PS5
分子量:
191.3
MOL File:
1314-80-3.mol

五硫化リン 物理性質

融点 :
286 °C
沸点 :
514°C
比重(密度) :
2.09 g/mL at 25 °C(lit.)
貯蔵温度 :
Flammables area
溶解性:
reacts with H2O; soluble in CS2
外見 :
色:
黄色から緑色
PH:
1 (10g/l, H2O, 20℃)
臭い (Odor):
腐った卵の臭い
水溶解度 :
反応する
安定性::
Hygroscopic, Moisture Sensitive
InChIKey:
HWVAJUNEPOKXLF-UHFFFAOYSA-N
CAS データベース:
1314-80-3(CAS DataBase Reference)
EPAの化学物質情報:
Phosphorus pentasulfide (1314-80-3)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  F,Xn,N
Rフレーズ  11-20/22-29-50
Sフレーズ  61
RIDADR  UN 1340 4.3/PG 2
WGK Germany  3
RTECS 番号 TH4375000
13-21
自然発火温度 142 °C
国連危険物分類  4.3
容器等級  II
HSコード  28139000
有毒物質データの 1314-80-3(Hazardous Substances Data)
毒性 LD50 orally in Rabbit: 389 mg/kg LD50 dermal Rabbit 3160 mg/kg
IDLA 250 mg/m3
消防法 危-2-PS-II
化審法 1-564
安衛法 57,57-2
毒劇物取締法 II
絵表示(GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
注意喚起語 危険
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H228 可燃性固体 可燃性固体 1
2
危険
警告
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H260 水に触れると自然発火するおそれのある可燃性 /引火性ガスを発生 水反応可燃性化学品 1 危険 GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H400 水生生物に強い毒性 水生環境有害性、急性毒性 1 警告 GHS hazard pictograms P273, P391, P501
注意書き
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P223 激しい反応と火災の発生の危険があるため、水と接 触させないこと。
P231+P232 湿気を遮断し、不活性ガス下で取り扱うこと。
P273 環境への放出を避けること。
P301+P312 飲み込んだ場合:気分が悪い時は医師に連絡する こと。

五硫化リン 価格 もっと(7)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
関東化学株式会社(KANTO) 19672-3A 五硫化りん
Phosphorus pentasulfide
1314-80-3 500g ¥15500 2024-03-01 購入
関東化学株式会社(KANTO) 19672-1A 五硫化りん
Phosphorus pentasulfide
1314-80-3 1kg ¥24800 2024-03-01 購入
Sigma-Aldrich Japan 232106 五硫化リン 99%
Phosphorus pentasulfide 99%
1314-80-3 5g ¥10400 2024-03-01 購入
Sigma-Aldrich Japan 232106 五硫化リン 99%
Phosphorus pentasulfide 99%
1314-80-3 100g ¥16200 2024-03-01 購入
関東化学株式会社(KANTO) 821024-1 五硫化二リン
di‐Phosphorus pentasulfide
1314-80-3 100g ¥7100 2024-03-01 購入

五硫化リン 化学特性,用途語,生産方法

説明

Phosphorus pentasulfide, is a nonmetallic inorganic compound . It is a yellow to greenish-yellow crystalline mass with an odor similar to hydrogen sulfide. It is a dangerous fire risk and ignites by friction or in contact with water. Boiling point is 995°F (535°C) and ignition temperature is 287°F (141°C). It decomposes upon contact with water or moist air, liberating toxic and flammable hydrogen-sulfide gas. Specific gravity is 2.09, so it is heavier than water. It is toxic by inhalation, with a TLV of 1 mg/m3 of air. The four-digit UN identification number is 1340. The NFPA 704 designation is health 2, flammability 1, and reactivity 2. Primary uses are in insecticides, safety matches, ignition compounds, and sulfonation.

化学的特性

Phosphorus pentasulfide is a greenish-gray to yellow, crystalline solid with an odor of rotten eggs. The Odor Threshold is 0.005 ppm.
Phosphorus pentasulfide

使用

Phosphorus pentasulfide is used in the manufacture of lubricant additives, pesticides, safety matches, and flotation agents.

一般的な説明

A greenish yellow solid with an odor of rotten eggs that may paralyze the sense of smell at hazardous concentrations in air. Density 2.04 g / cm3. Phosphorus pentasulfide is used for making lube oil additives, insecticides, flotation agents, safety matches, blown asphalt, and other products and chemicals.

空気と水の反応

Highly flammable. May heat and spontaneously ignite in presence of moisture [Haz. Chem. Data. 1969]. Reaction with water forms toxic hydrogen sulfide gas and phosphoric acid. Dangerous when wet.

反応プロフィール

PHOSPHORUS PENTASULFIDE reacts vigorously with strong oxidants. Exothermically violent decomposition reaction with water, steam or acids to produce irritating fumes of phosphorus pentaoxide and highly toxic hydrogen sulfide gas. May ignite in contact with limited amounts of water [Haz. Chem. Data, 1975, p. 239]. Can be ignited by sparks or friction and its dust presents an explosion hazard in air at sufficient concentrations. Hydrogen sulfide gas evolved from reactions with water may also form explosive mixtures with air.

健康ハザード

Phosphorus pentasulfide is an irritant to the skin and eyes. Inhalation of its vapors can cause irritation of the respiratory passage. Oral toxicity of this compound in rats was found to be moderate.
LD50 value, oral (rats): 389 mg/kg (NIOSH 1986)
Phosphorus pentasulfide can readily produce highly toxic hydrogen sulfide in the presence of moisture. Other toxic products from its combustion are sulfur dioxide and phosphorus pentoxide (corrosive)..

火災危険

Special Hazards of Combustion Products: Products of combustion include sulfur dioxide and phosphorus pentoxide, which are irritating, toxic and corrosive.

安全性プロファイル

A poison by ingestion. A severe eye and skin irritant. Readily liberates toxic hydrogen sulfide and phosphorus pentoxide and evolves heat on contact with moisture. Dangerous fire hazard in the form of dust when exposed to heat or flame. Spontaneous heating in the presence of moisture. Moderate explosion hazard in solid form by spontaneous chemical reaction. Reacts with water, steam, or acids to produce toxic and flammable vapors; can react vigorously with oxidizing materials. Incompatible with air, alcohols, water. To fight fire, use CO2snow, dry chemical, or sand. Used as an intermedate in manufacturing lubricant addltives, insecticides, and fertilizer agents. When heated to decomposition it emits highly toxic fumes of SO, and PO,. See also HYDROGEN SULFIDE.

職業ばく露

Phosphorus pentasulfide is used as an intermediate in the manufacture of lubricant additives; insecticides, flotation agents; lubricating oil; ignition compounds; and matches. It is also used to introduce sulfur into rubber, and organic chemicals, such as pharmaceuticals.

輸送方法

UN1340 Phosphorus pentasulfate, free from yellow or white phosphorus, Hazard Class: 4.3; Labels: 4.3-Dangerous when wet material, 4.1-flammable solid.

純化方法

Purify P2S5 by extraction and crystallisation with CS2, using a Soxhlet extractor, and is heated in a CO2 atmosphere at 150o to remove solvent. It liberates H2S in moist air. HARMFUL VAPOURS. [Klements in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 568 1963.]

不和合性

Flammable solid; dust may form explosive mixture with air. Contact with water forms phosphorus pentoxide and an explosive mixture of hydrogen sulfide with air. Phosphorus pentasulfide is incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, ammonia, strong acids, strong bases, alcohols. Reaction with water or moisture in the air releases heat, hydrogen sulfide (H2S), sulfur dioxide, and phosphoric acid. Pyrophoric hazard, may self-ignite in moist air.

廃棄物の処理

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Decompose with water, forming phosphoric acid, sulfuric acid and hydrogen sulfide. Provisions must be made for scrubbing hydrogen sulfide emissions. The acids may then be neutralized and diluted slowly to solution of soda ash and slaked lime with stirring, then flush to sewer with large volumes of water.

五硫化リン 上流と下流の製品情報

原材料

準備製品

クロロチオりん酸ジメチル 1,3-ジヒドロ-7-クロロ-5-フェニル-2H-1,4-ベンゾジアゼピン-2-チオン 4-SULFANYLNICOTINIC ACID チオりん酸O,O-ジメチルO-(2-クロロ-4-ニトロフェニル) Dimethylphenyl dithiophosphate,sodium salt 6-メルカプトプリン (2-(トリフルオロメチル)チアゾール-5-イル)メタノール トルレスタット ジチオりん酸O,O-ジエチルS-[(4-クロロフェニルチオ)メチル] 2,4-ジメチルチアゾール ジチオりん酸O,O-ジエチルS-(6-クロロ-2-オキソベンゾオキサゾール-3(2H)-イル)メチル α,β-ジチオ二りん酸Oα,Oα,Oβ,Oβ-テトラエチル チオりん酸ジエチル4-ニトロフェニル 5,6-ジアミノピリミジン-4(1H)-チオン 3-メチル-2-ベンゾチアゾリノンヒドラゾン塩酸塩一水和物 チオ酢酸 ホスホロジチオ酸O-エチルO-[4-(メチルチオ)フェニル]S-プロピル 6-(METHYLTHIO)PYRIMIDINE-4,5-DIAMINE ヘプタメチレンイミン 2,5-ジメチルチオフェン クアゼパム ホスメット 4-ヒドロキシベンゾニトリル 2-メチルチアゾリン O,O-dialkyl thiophosphoryl chloride 6-メルカプトプリン 水和物 チオりん酸O,O-ジメチルO-[p-シアノフェニル] チオアセトアミド Malathion emulsifiable concentrate ローソン試薬 ジチオりん酸 O,O-ジエチル チオりん酸O,O-ジメチルO-(3,5,6-トリクロロ-2-ピリジニル) 6-メトキシ-2-メチルベンゾチアゾール 5-フルオロ-2-メチルベンゾチアゾール Antioxidant and antiseptic agent T202 ジチオりん酸水素O,O-ジメチル ジチオりん酸O-(2,4-ジクロロフェニル)O-エチルS-プロピル フルフリルメルカプタン ブロチゾラム 7-(トリフルオロメチル)-4-キノリンチオール

五硫化リン 生産企業

Global( 207)Suppliers
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1314-80-3(五硫化リン)キーワード:


  • 1314-80-3
  • phosphoruspentasulfide,freefromyellowandwhitephosphorus
  • Phosphoruspersulfide
  • Phosphorusper-sulfide
  • Phosphorussulfid
  • phosphorussulfide(p2s5)
  • rcrawastenumberu189
  • sirnikfosforecny
  • Sulfur phosphide (R)
  • diphosphorus pentasulphide phosphorus pentasulphide
  • Phosphoric Sulphide
  • Phosphorus (V) sulfide, distilled
  • osphorus pentasulf
  • Phosphorus pentasulf
  • di-Phosphorus pentasulfide for synthesis
  • pentasulfuredephosphore
  • pentasulfuredephosphore(french)
  • Phosphoricsulfide
  • phosphoruspentasulfide(p4s10)
  • sirnikfosforecny(czech)
  • sulfurphosphide
  • tetraphosphorusdecasulfide
  • DI-PHOSPHORUS PENTASULFIDE
  • diphosphorus pentasulphide
  • BIPHOSPHORUS PENTASULFIDE
  • THIOPHOSPHORIC ANHYDRIDE
  • PHOSPHORUS(V) SULFIDE
  • PHOSPHORUS PENTASULFIDE
  • PHOSPHORUS PERSULPHIDE
  • Phosphorus(Ⅴ)sulfide
  • PHOSPHORUS PENTASULFIDE (DRUMS), APPROX. 98%
  • 五硫化二りん
  • 五硫化りん
  • 十硫化四りん
  • 硫化りん(V)
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