トリス(4-フルオロフェニル)ホスフィン 化学特性,用途語,生産方法
外観
白色~わずかにうすい黄色、結晶~結晶性粉末
用途
有機合成原料。
使用上の注意
不活性ガス封入。
化学的特性
white to light yellow crystal powde
使用
Tris(4-fluorophenyl)phosphine (TFPP) and tris(2,2,2- trifluoroethyl) phosphite (TTFP) were used as flame-retarding additives in Li-ion battery clectrolytes.
Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.
製造方法
with 4-bromofluorobenzene, magnesium, and phosphorous (III) trichloride.3 Alternatively, reduction of tris(4-fluorophenyl)phosphine oxide with an iron catalyst.
一般的な説明
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency.
Click here for more information.
合成
Tris (4-fluorophenyl)phosphine oxide could be used as a starting material to synthesize Tris(4-fluorophenyl)phosphine. Into the reactor were added 0.2 mmol of tris(4-fluorophenyl)phosphine oxide, 0.36 mmol of trifluoroacetic anhydride, and 1 ml of dioxane as a solvent. Stir at room temperature under a nitrogen atmosphere for 30 min; after the reaction, continue adding 0.2 mmol of sodium bicarbonate, 0.24 mmol of 15-Crown-5, and 1.2 mmol of sodium hydride under a nitrogen environment. Under 150 ℃, stir for 24 hours, stop the reaction, cool to room temperature, and distilled under reduced pressure to remove the solvent. The crude product is separated by column chromatography to obtain Tris(4-fluorophenyl)phosphine with a yield of 74%.
トリス(4-フルオロフェニル)ホスフィン 上流と下流の製品情報
原材料
準備製品