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テルブホス

テルブホス 化学構造式
13071-79-9
CAS番号.
13071-79-9
化学名:
テルブホス
别名:
テルブホス標準品;テルブホス;テルブホス‐D10;CS_N-13510-250MG_テルブホス;テルブホス STANDARD;テルブホス Standard, 100 µg/mL in Methanol;テルブホス Standard, 1000 µg/mL in Hexane
英語化学名:
Terbufos
英語别名:
st-100;HUNTER;TERTIN;Plydax;Counter;Aragran;ac92100;ent27920;CYANATER;TERBUFOS
CBNumber:
CB6348870
化学式:
C9H21O2PS3
分子量:
288.43
MOL File:
13071-79-9.mol

テルブホス 物理性質

融点 :
-29°C
沸点 :
69°C (0.01 mmHg)
比重(密度) :
1.105
蒸気圧:
3.46×10-2 Pa (25 °C)
闪点 :
88°C
貯蔵温度 :
APPROX 4°C
外見 :
Liquid
色:
Colorless, pale
水溶解度 :
Insoluble
Merck :
13,9233
BRN :
1710115
CAS データベース:
13071-79-9(CAS DataBase Reference)
NISTの化学物質情報:
Phosphorodithioic acid, s-[(tert-butylthio)methyl] o,o-diethyl ester(13071-79-9)
EPAの化学物質情報:
Phosphorodithioic acid, S-[[(1,1-dimethylethyl)thio] methyl] O,O-diethyl ester(13071-79-9)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T+;N,N,T+
Rフレーズ  27/28-50/53
Sフレーズ  36/37-45-60-61
RIDADR  UN 2810
WGK Germany  3
RTECS 番号 TD7200000
国連危険物分類  6.1(a)
容器等級  I
HSコード  29309090
有毒物質データの 13071-79-9(Hazardous Substances Data)
毒性 LD50 orally in quail: 15 mg/kg (Hill, Camardese)
消防法 危-4-3-III
安衛法 57,57-2
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P391 漏出物を回収すること。
P501 内容物/容器を...に廃棄すること。

テルブホス 価格 もっと(9)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-208N テルブホス
Terbufos
13071-79-9 10mg ¥4400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-8141A-1-10 テルブホス Standard
Terbufos Standard, 1000 ug/mL in Hexane
13071-79-9 1mL ¥19900 2018-12-26 購入
関東化学株式会社(KANTO) 49801-72 テルブホス標準品
Terbufos standard
13071-79-9 100mg ¥15000 2018-12-13 購入
Sigma-Aldrich Japan 45313 テルブホス PESTANAL?, analytical standard
Terbufos PESTANAL?, analytical standard
13071-79-9 100mg ¥16600 2018-12-25 購入
林純薬工業株式会社 99045313 テルブホス
Terbufos
13071-79-9 100mg ¥16600 2018-12-15 購入

テルブホス MSDS


Terbufos

テルブホス 化学特性,用途語,生産方法

外観

無色~うすい黄色, 澄明の液体

溶解性

水4.5mg/l(27℃)。芳香族炭化水素, アルコール,アセトンなど多くの有機溶媒に容易に溶ける。アセトンに溶け、水にほとんど溶けない。

用途

殺虫剤、殺線虫剤 (NITE調査)プラスチック架橋剤?充てん剤、ゴム添加剤、電子材料原料、ICパッケージ?特殊光学ガラス原料、食品添加物、医薬、セラミックス原料、触媒、試薬、炉床材?塩基性耐火レンガ?電融マグネシア原料 (化学工業日報社)

農薬用途

殺虫剤、線虫駆除剤

化学的特性

Yellowish liquid. Soluble in alcohol, acetone.

化学的特性

Terbufos is a colorless to pale yellow liquid.

使用

Terbufos is used to control soil pests in maize, sugar beet and vegetables and also nematodes in sugar beet and bananas.

使用

Soil insecticide.

一般的な説明

Technical product is a clear, colorless to pale yellow liquid. Used as a soil insecticide.

空気と水の反応

Hydrolyzes under alkaline conditions [EPA, 1998]. Insoluble in water.

反応プロフィール

Organothiophosphates, such as Terbufos, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Terbufos decomposes in the presence of acids or bases .

危険性

Moderate fire risk. Toxic by ingestion. Cholinesterase inhibitor. Questionable carcinogen.

健康ハザード

Terbufos may be fatal if swallowed, inhaled, or absorbed through the skin. Repeated inhalation or skin contact may progressively increase susceptibility to poisoning.

火災危険

This is a liquid organophosphorus pesticide. Fire may produce irritating or poisonous gases. Hydrolyzes under alkaline conditions.

农业用途

Insecticide, Nematicide: This insecticide and nematicide is applied at planting time to corn, sugar beets, sorghum, maize, cotton, bananas and cabbage. It controls corn rootworms, wireworms, white grubs, maggots, billbugs and nematodes. Some above-ground pests can be controlled when soil has been treated with terbufos. Terbufos has no residential use. Not approved for use in EU countries. A U.S. EPA restricted use Pesticide (RUP).

製品名

AC 921000®; ARAGRAN®; CONTRAVEN®; COUNTER®; COUNTER 15G SYSTEMIC INSECTICIDE®; PLYDOX®; TERBUROX®

職業ばく露

A potential danger to those involved in the manufacture, formulation or application of this organophosphate soil insecticide.

環境運命予測

Soil. Oxidized in soil to its primary and secondary oxidation products, terbufos sul- foxide and terbufos sulfone, respectively (Bowman and Sans, 1982; Chapman et al., 1982; Wei, 1990). Both metabolites were formed due to micobial activity and chemical oxidation (Chapman et al., 1982). Incubation of terbufos (5 μg/g) in a loamy sand containing Nitrosomonas sp. and Nitrobacter sp. gave terbufos sulfoxide and terbufos sulfone as the primary products. After 2 weeks, the sulfoxide increased the bacterial population >55% and the sulfone increased the fungal population at least 66% (Tu, 1980). The half-life in soil is 9–27 days (Worthing and Hance, 1991).
Chemical/Physical. Terbufos and its degradation products terbufos sulfoxide and ter- bufos sulfone followed first-order disappearance in natural, sterilized natural and distilled water at 20°C. In natural and distilled water, the sulfoxide and su

代謝経路

Terbufos is the S-tertiary butyl homologue of phorate (the S-ethyl homolope). Consequently, the compound is more strongly sorbed to soils; however, the metabolism is essentially the same, with activation via thiooxidation and to a lesser degree oxidative desulfuration being the principal mechanisms. The metabolic routes for terbufos biotransformation have mainly been studied in soils where oxidation to the sulfoxide is rapid and further metabolism to the sulfone quite slow. In common with other phosphorodithioate insecticides, the phosphorodithioate moiety is excreted in mammalian urine as diethyl phosphate, O,O-diethyl phosphorothioate and O,O-diethyl phosphorodithioate and in humans the concentrations of these metabolites have been found useful as indicators of exposure to the insecticide.

輸送方法

UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1Poisonous materials, Technical Name Required.

Degradation

Terbufos is hydrolysed in strong alkalis (pH>9) and acids (pH﹤2) (PM). Terbufos disappeared rapidly when incubated in distilled water (pH 5.9), natural water (pH 8.7) and sterilised natural water (pH 8.75) with DT50 values of 3.3, 3.2 and 3.5 days, respectively. Terbufos was not converted into the sulfoxide (2) or the sulfone (3) under these conditions. The actual products of hydrolysis were not identified. Terbufos sulfoxide (2) and sulfone (3) were ten to one hundred times more stable than terbufos under the same conditions and there was evidence that, in contrast to terbufos, the hydrolysis was pH dependent (Bowman and Sans, 1982).

不和合性

Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the presence of strong reducing agents, such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials.

廃棄物の処理

In accordance with 40CFR165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

テルブホス 上流と下流の製品情報

原材料

準備製品


テルブホス 生産企業

Global( 0)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度

13071-79-9(テルブホス)キーワード:


  • 13071-79-9
  • ai3-27920
  • Aragran
  • caswellno131a
  • Counter
  • Counter 15 G
  • Counter 15G soil insecticide
  • Counter 15G soil insecticide-nematicide
  • counter15gsoilinsecticide
  • counter15gsoilinsecticide-nematicide
  • ENT 27920
  • ent27920
  • epapesticidechemicalcode105001
  • Methanethiol, (tert-butylthio)-, S-ester with O,O-diethyl phosphorodithioate
  • O,O-Diethyl S-(Tert-butylthio)methyl phosphorodithioate
  • O,O-Diethyl S-[[(1,1-dimethylethyl)thio]methyl] phosphorodithioate
  • Phosphorodithioic acid, O,O-diethyl S-(((1,1-dimethylethyl)thio)methyl) ester
  • Phosphorodithioic acid, S-[[(1,1-dimethylethyl)thio]methyl] O,O-diethyl ester
  • st-100
  • S-t-Butylthio-methyl-O,O-diethyl phosphorodithioate
  • HUNTER
  • COUNTER(R)
  • CONTRAVEN
  • CYANATER
  • S-[(1,1-DIMETHYLETHYLTHIO)METHYL]-O,O-DIETHYL PHOSPHORODITHIOATE
  • S-TERT-BUTYLTHIOMETHYL O,O-DIETHYL DITHIOPHOSPHATE
  • S-tert-Butylthiomethyl O,O-diethyl phosphorodithioate
  • TERTIN
  • TERBUFOS
  • Terbufos granules
  • TERBOROX
  • テルブホス標準品
  • テルブホス
  • テルブホス‐D10
  • CS_N-13510-250MG_テルブホス
  • テルブホス STANDARD
  • テルブホス Standard, 100 µg/mL in Methanol
  • テルブホス Standard, 1000 µg/mL in Hexane
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