ホスメット

ホスメット 化学構造式
732-11-6
CAS番号.
732-11-6
化学名:
ホスメット
别名:
フタロホス;ジチオりん酸O,O-ジメチルS-(フタルイミジルメチル);プロレート;プロラート;PMP剤;ホスメット;イミダン;ジチオりん酸S-(1,3-ジオキソイソインドリン-2-イル)メチルO,O-ジメチル;ジチオりん酸O,O-ジメチルS-[(1,3-ジヒドロ-1,3-ジオキソ-2H-イソインドール-2-イル)メチル];ホスメット標準品;ジメチルフタリルイミドメチルジチオホスフェイト;S-[(1,3-ジオキソイソインドリン-2-イル)メチル]=O,O-ジメチル=ホスホロジチオアート;CS_N-12207-100MG_ホスメット;PMP標準品;イミダン STANDARD;イミダン (ホスメット);イミダン (ホスメット), 1000 µg/mL in Hexane;イミダン Standard, 100 µg/mL in MeOH;O,O-ジメチル {[(1,3-ジオキソ-2,3-ジヒドロ-1H-イソインドール-2-イル)メチル]スルファニル}ホスホノチオアート
英語名:
Phosmet
英語别名:
PMP;IMIDN;imidan;INOVAT;FOSDAN;Fosmet;R-1504;Smidan;CEKUMET;PHOSMET
CBNumber:
CB6681168
化学式:
C11H12NO4PS2
分子量:
317.32
MOL File:
732-11-6.mol
MSDS File:
SDS

ホスメット 物理性質

融点 :
72.5°C
沸点 :
412.6±47.0 °C(Predicted)
比重(密度) :
1.03 g/cm3
蒸気圧:
6.5×10-5 Pa (25°C)
闪点 :
>100 °C
貯蔵温度 :
0-6°C
溶解性:
Chloroform: Slightly Soluble,Methanol: Slightly Soluble
酸解離定数(Pka):
-2.63±0.20(Predicted)
水溶解度 :
25 mg l-1 (25°C)
外見 :
個体
BRN :
264869
LogP:
2.780
CAS データベース:
732-11-6(CAS DataBase Reference)
NISTの化学物質情報:
Phosmet(732-11-6)
EPAの化学物質情報:
Phosmet (732-11-6)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  Xn;N,N,Xn
Rフレーズ  21/22-50/53
Sフレーズ  22-36/37-60-61
RIDADR  UN 2811
WGK Germany  3
RTECS 番号 TE2275000
国連危険物分類  6.1(b)
容器等級  III
有毒物質データの 732-11-6(Hazardous Substances Data)
毒性 LD50 in male, female rats (mg/kg): 113, 160 orally (Gaines)
毒劇物取締法 III
絵表示(GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
注意喚起語 危険
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H301 飲み込むと有毒 急性毒性、経口 3 危険 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H332 吸入すると有害 急性毒性、吸入 4 警告 GHS hazard pictograms P261, P271, P304+P340, P312
H370 臓器の障害 特定標的臓器有害性、単回暴露 1 危険 GHS hazard pictograms P260, P264, P270, P307+P311, P321,P405, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 GHS hazard pictograms P273, P391, P501
注意書き
P202 全ての安全注意を読み理解するまで取り扱わないこ と。
P260 粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。
P264 取扱い後は皮膚をよく洗うこと。
P264 取扱い後は手や顔をよく洗うこと。
P273 環境への放出を避けること。
P301+P310 飲み込んだ場合:直ちに医師に連絡すること。

ホスメット 価格 もっと(10)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01W0116-0922 PMP標準品 98.0+% (capillary GC)
98.0+% (qNMR)
PMP Standard 98.0+% (capillary GC)
98.0+% (qNMR)
732-11-6 200mg ¥5550 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-055N イミダン
Imidan
732-11-6 10mg ¥5300 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-8141A-1-08 イミダン (ホスメット)
Imidan (Phosmet), 1000 ug/mL in Hexane
732-11-6 1mL ¥8900 2024-03-01 購入
関東化学株式会社(KANTO) 32183-96 ホスメット標準品 >95.0%(GC)
Phosmet standard >95.0%(GC)
732-11-6 200mg ¥5800 2024-03-01 購入
Sigma-Aldrich Japan 36195 ホスメット PESTANAL?, analytical standard
Phosmet PESTANAL?, analytical standard
732-11-6 100mg ¥6660 2024-03-01 購入

ホスメット 化学特性,用途語,生産方法

外観

白色, 結晶~粉末

溶解性

水に不溶。脂肪族炭化水素以外の殆どの有機溶媒に可溶。水25mg/l(25℃)。アセトン650, ベンゼン600,トルエン, メチルイソブチルケトン300, キシレン250, メタノール50,ケロシン5(全てg/l 25℃)。アセトンに溶け、水にほとんど溶けない。

効能

殺虫薬, アセチルコリンエステラーゼ阻害薬

農薬用途

殺虫剤

説明

Phosmet is an organophosphate insecticide and acaricide. It reduces apple damage by a large variety of insects, including apple maggots, codling moths, and obliquebanded leafrollers when used as either a border or cover spray at a concentration of 1.9 kg AI/hectare. Phosmet is effective in controlling S. scabiei in pigs when applied as a 20% pour-on solution. It is toxic to rats via oral administration (LC50 = 230 mg/kg). Formulations containing phosmet have been used in the control of insects and mites in agriculture.

化学的特性

Phosmet is a white crystalline solid

使用

Phosmet is used as a pesticide to protect crops and vegetation. Insecticide.

一般的な説明

Off-white crystalline solid with an offensive odor. Used as an insecticide and acaricide.

反応プロフィール

Organophosphates, such as Phosmet, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Storage above 113 F, may lead to decomposition. [EPA, 1998].

健康ハザード

Phosmet is an organophosphorus pesticide. Phosmet is very toxic; the probable oral lethal dose for humans is 50-500 mg/kg, or between 1 teaspoon and 1 oz. for a 150 lb. person. It is a cholinesterase inhibitor and has central nervous system effects. Oral lethal doses in humans have been reported at 50 mg/kg.

火災危険

(Non-Specific -- Organophosphorus Pesticide, n.o.s.). Container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases. Storage above 113F, may lead to decomposition.

农业用途

Insecticide, Acaricide: Phosmet is a non-systemic insecticide used on both plants and animals. It is mainly used on apple trees for control of coddling moth, though it is also used on a wide range of crops including alfalfa, nuts, grapes, blueberries, peas, potatoes, fruit crops, ornamentals, and vines for the control of aphids, suckers, mites, fire ants and fruit flies. The compound is also an active ingredient in some dog collars. It is used as an insecticide on swine and cattle. U.S. Maximum Allowable Residue Levels for Phosmet [40 CFR 180.261 (a)]: Alfalfa 40 ppm; almond, hulls 10 ppm; apple 10 ppm; apricot 5 ppm; blueberry 10 ppm; cattle, fat 0.2 ppm; cattle, meat 0.2 ppm; cattle, meat byproducts 0.2 ppm; cherry 10 ppm; cotton, undelinted seed 0.1 ppm; crabapple 20 ppm; cranberry 10 ppm; fruit, stone, group 12 5 ppm; goat, fat 0.2 ppm; goat, meat0.2 ppm; goat, meat byproducts 0.2 ppm; grape 10 ppm; hog, fat 0.2 ppm; hog, meat 0.2 ppm; hog, meat byproducts 0.2 ppm; horse, fat 0.2 ppm; horse, meat 0.2 ppm; horse, meat byproducts 0.2 ppm; kiwifruit 25 ppm; nectarine 5 ppm; nuts 0.1 ppm; pea 0.5 ppm; pea, field, hay 10 ppm; pea, field, vines 10 ppm; peach 10 ppm; pear 10 ppm; pistachio 0.1 ppm; plum, prune, fresh 5 ppm; potato 0.1 ppm; sheep, fat 0.2 ppm; sheep, meat 0.2 ppm; sheep, meat byproducts 0.2 ppm; sweet potato, roots 10 ppm. Regional registration, as defined in section 180.1(n) [40 CFR 180.261 (c)]: Crabapple 20 ppm; pistachio 0.1 ppm.

製品名

Trade Names: APPA®; DECEMTHION®; DELPHOS ®; FESDAN®; FIREBAN®; FTALOPHOS®; IMIDAN®; KEMOLATE®; PERCOLATE®; PMC®; PROLATE®[C]; R 1504®; SAFIDON®; SMIDAN®; STARBAR CATTLE DUST®[C]; STAUFFER R 1504®; VET-KEM®; ZEOCON®

安全性プロファイル

A human poison by ingestion. Poison experimentally by inhalation and ingestion routes. Moderately toxic by skin contact. Human systemic effects by inhalation: lachqmation, somnolence, and olfaction effects. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, POx, and SOx. See also ESTERS.

職業ばく露

An organophosphorus insecticide and acaricide.

発がん性

No treatment-related increases in tumor incidence occurred in rats given a diet with 0, 20, 40,200, or 400 ppm (400 ppm terminated at 12 months) (equivalent to 0, 1.1, 1.8, 9.4, and 23 mg/kg/day in males and 0, 1.1, 2.1, 10.9, and 27 mg/kg/day in females) for 2 years .
When mice were given diets with 0, 5, 25, or 100 ppm phosmet (approximately 0.75, 3.75, or 15.0 mg/kg/day) for 2 years, there was an increased incidence of hepatocellular tumors in males and mammary gland tumors in females .

環境運命予測

Soil. In soils, phosmet is rapidly hydrolyzed to phthalimide (Camazano and Martin, 1980; Sánchez Camazano and Sánchez Martin, 1983). The rate of hydrolysis is greater in the presence of various montmorillonite clays and chloride salts. The calculated hydrolysis half-lives of phosmet in the presence of calcium, barium, copper, magnesium and nickel montmorillonite clays were 0.084, 0.665, 10.025, 16.926 and 28.738 days, respectively. Similarly, the half-lives of phosmet in the presence of copper, calcium, magnesium and barium chlorides were <0.020, 5.731, 10.680 and 12.242 days, respectively. In comparison, the hydrolysis of phosmet in a neutral water solution was 46.210 days (Sánchez Camazano and Sánchez Martin, 1983)
Plant. In plants, phosmet is degraded to nontoxic compounds (Hartley and Kidd, 1987). Dorough et al. (1966) reported the half-life in Bermuda grass was 6.5 days. Half-life values ranged from 1.2 to 6.5 days (Dorough et al., 1966; Leuck and Bowman
Chemical/Physical. Emits toxic fumes of phosphorus, nitrogen and sulfur oxides when heated to decomposition (Sax and Lewis, 1987). Though no products were identified, the
hydrolysis half-lives at 20°C were 7.0 days and 7.1 hours at pH 6.1 and pH 7.4, respectively. At 37.5°C and pH 7.4, the hydrolysis is 1.1 hours (Freed et al., 1979)

代謝経路

The main degradative route of phosmet metabolism in plants and animals is similar with the compound being hydrolysed via attack on the carbonyl group of the phthaloyl moiety, yielding phthalamic acid which is further hydrolysed and decarboxylated to benzoic acid. It should be noted, however, that the studies on which the evidence for these metabolites is based are old and used paper chromatography for the main analytical evidence. A rather later study in rats identified N-hydroxymethylphthalimide and phthalimide as metabolites, implying a degradative hydrolytic route via attack on the N-methylene carbon atom. Oxidative desulfuration to the active acetylcholinesterase inhibitor phosmet oxon predominates over hydrolysis in insects and is responsible for the selectivity of the compound.

代謝

Orally administered phosmet in mammals is rapidly degraded to phthalamic acid, phthalic acid, and phthalic acid derivatives, and the metabolites are excreted in the urine. Oxidative desulfuration to the oxon predominates over hydrolysis in insects. It is rapidly degraded in plants and soils.

輸送方法

UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1Poisonous materials, Technical Name Required.

不和合性

Organothiophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur). Not compatible with other pesticides under alkaline conditions. Contact with water, steam or moisture forms phthalic acids. Slightly corrosive to metals in the presence of moisture.

廃棄物の処理

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Small amounts may be decomposed with hypochlorite. For large amounts, incineration with effective gas scrubbing is recommended.

ホスメット 上流と下流の製品情報

原材料

準備製品


ホスメット 生産企業

Global( 82)Suppliers
名前 電話番号 電子メール 国籍 製品カタログ 優位度
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873
sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674;
factory@coreychem.com China 29826 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-87569266 15319487004
1015@dideu.com China 2263 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503259 +86-19930503259
cherry@crovellbio.com China 18459 58
GIHI CHEMICALS CO.,LIMITED
+8618058761490
info@gihichemicals.com China 50001 58
Aladdin Scientific
+1-833-552-7181
sales@aladdinsci.com United States 35748 58
Mainchem Co., Ltd. +86-0592-6210733
sale@mainchem.com China 32360 55

ホスメット  スペクトルデータ(1HNMR、13CNMR、IR1、IR2、MS)


732-11-6(ホスメット)キーワード:


  • 732-11-6
  • Phosphorodithioic acid O,O-dimethyl S-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]
  • 2-(dimethoxyphosphinothioylsulfanylmethyl)isoindole-1,3-dione
  • 2-[(dimethoxythiophosphorylthio)methyl]isoindoline-1,3-quinone
  • IMidan solution
  • Phosmet solution
  • Phosmet Solution, 100ppm
  • CEKUMET
  • INOVAT
  • IMIDITHION
  • IMIDN
  • imidan
  • IMIDAN (TM)
  • FOSDAN
  • N-[MERCAPTOMETHYL]-PHTHALIMIDE-S-[O,O-DIMETHYL PHOSPHORODITHIOATE]
  • Phthalimidomethyl-0,0-dimethyl phosphorodithioate
  • PHTHALOPHOS
  • PMP
  • Phosphorodithioic acid S-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl] O,O-dimethyl ester
  • PHOSMET
  • PROLATE
  • O,O-DIMETHYL S-PHTHALIMIDOMETHYL DITHIOPHOSPHATE
  • O,O-DIMETHYL-S-PHTHALIMIDO METHYL-PHOSPHORODITHIOATE
  • O,O-DIMETHYL PHTHALIMIDO-METHYL-PHOSPHOROTHIOLOTHIONATE
  • O,O-dimethyl phthalimidomethyl phosphorodithioate
  • IMIDAN, 1GM, NEAT
  • (O,O-Dimethyl-phthalimidiomethyl-dithiophosphate)
  • Decemthion
  • Decemthion P-6
  • decemthionp-6
  • decemtionp-6
  • フタロホス
  • ジチオりん酸O,O-ジメチルS-(フタルイミジルメチル)
  • プロレート
  • プロラート
  • PMP剤
  • ホスメット
  • イミダン
  • ジチオりん酸S-(1,3-ジオキソイソインドリン-2-イル)メチルO,O-ジメチル
  • ジチオりん酸O,O-ジメチルS-[(1,3-ジヒドロ-1,3-ジオキソ-2H-イソインドール-2-イル)メチル]
  • ホスメット標準品
  • ジメチルフタリルイミドメチルジチオホスフェイト
  • S-[(1,3-ジオキソイソインドリン-2-イル)メチル]=O,O-ジメチル=ホスホロジチオアート
  • CS_N-12207-100MG_ホスメット
  • PMP標準品
  • イミダン STANDARD
  • イミダン (ホスメット)
  • イミダン (ホスメット), 1000 µg/mL in Hexane
  • イミダン Standard, 100 µg/mL in MeOH
  • O,O-ジメチル {[(1,3-ジオキソ-2,3-ジヒドロ-1H-イソインドール-2-イル)メチル]スルファニル}ホスホノチオアート
  • 有機リン系殺虫剤
  • 農薬類,殺虫剤および除草剤など
  • 生活関係標準物質
  • 食料品
  • 有機標準物質
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