N6-ベンジルアデニン 化学特性,用途語,生産方法
外観
白色〜わずかにうすい黄色, 結晶性粉末〜粉末
定義
本品は、次の化学式で表される複素環式化合物である。
溶解性
エタノールに溶けにくく、水にほとんど溶けない。
用途
植物生長調節剤、サイトカイニン活性を有する。メロンの着果、肥大促進.ジベレリンとの混合処理でリンゴの肥大促進効果もある。花井類では側枝の発生、花芽促進のために使用される。
用途
植物細胞培養培地添加剤。
化粧品の成分用途
ヘアコンディショニング剤、忌避剤.殺虫剤
化学的特性
Colorless to off-white or yellow powder. Corrosive. Insoluble in water, slightly soluble in ethanol, stable in acid and alkali.
使用
6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture.
6-Benzylaminopurine has been used:
to induce sprouting in plant materials.
in seed germination medium for culturing of seeds.
to modify Murashige and Skoog (MS) media for shoot initiation.
inhibitor of respiratory kinase in plants.
6-Benzylaminopurine, benzyl adenine (BAP) is a synthetic cytokinin which together with auxins elicits plant growth and development responses. BAP is a widely use cytokinin supplement to plant growth media such as Murashige and Skoog medium, Gamborg’s medium, and Chu’s N6 medium.
製造方法
synthesis of 6-benzylaminopurine: To 5g hypoxanthine, add 20mL SOCl2, 0.25g DMAP, 10gBTC dissolved in 20mL SOCl2. Heat and add BTC/SOCl2 dropwise. Reflux (refrigerant cooling) to complete dissolution, steam out SOCl2 (containing phosgene, which is used for recovery), evaporated (drained), cooled to room temperature to obtain a milky yellow solid (6-chloropurine and DMAP.Hcl). Directly add 4g benzylamine and 25g triethylamine to it, heat to 70～80 ℃, or microwave heating, until the 6-chloropurine reaction is complete (TLC monitoring), add ethanol, the solid filtered out is washed with ethanol, and dried to obtain 7 g of product 6-benzylaminopurine with a brown color.
Preparation and biological activity of 6-benzylaminopurine derivatives in plants and human cancer cells
定義
ChEBI: 6-Benzylaminopurine is a member of the class of 6-aminopurines that is adenine in which one of the hydrogens of the amino group is replaced by a benzyl group. It has a role as a plant metabolite and a cytokinin. It derives from an adenine.
主な応用
6-Benzylaminopurine solution has been used as a component in the Murashige & Skoog medium (MS) for culturing mandarin explants and plantlets of Dendrocalamus asper (Schultes f.). It has also been used as a supplement in Nitsch and Nitsch medium (NN) of grapevine explants.
一般的な説明
6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture commodities.
健康ハザード
6-benzylaminopurine (6-BA) is widely used in agriculture and horticulture as plant growth regulator. Its excessive use may pose a potential risk to both environment and human health, which is causing great concern. Vapor is irritating when breathed at high concentrations. Contact with liquid causes irritation of skin and burning of eyes; Vapors cause a slight smarting of the eyes or respiratory system if present in high concentrations; If spilled on clothing and allowed to remain, may cause smarting and reddening of the skin.
农业用途
6-Benzylaminopurine is a plant growth promoter, is the first applied synthetic cytokinin, mainlyused as a broad- spectrum plant growth regulator. It can be used inagriculture, horticulture, for plants at different stages, from germination to harvest. It enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in EU countries. Registered for use in the U.S.
製品名
ABG® 3034; ACCEL®; AGTROL®;
6-BA®; BA® (growth stimulant); CHRYSAL BVB®;
EXILIS®; PERLAN®; PROMALIN®; SD® 4901; SQ®
4609
安全性プロファイル
Moderately toxic by ingestion andskin contact. Human mutation data reported. Whenheated to decomposition it emits toxic vapors of NOx.
職業ばく露
A polyamine plant growth regulator
used to lengthen and enhance the shape of apples and to
increase the fruit set in pears. It increases the yield of pistachios
and tomatoes. Not listed for use in the EU countries.
輸送方法
UN3259 Amines, solid, corrosive, n.o.s, or
Polyamines, solid, corrosive, n.o.s., Hazard class: 8;
Labels: 8—Corrosive material, Technical Name Required.
純化方法
It is purified by recrystallisation from aqueous EtOH. It has at 207 and 270nm (H2O), 268 nm max (pH 6), 274nm (0.1 N HCl) and 275nm (0.1 N NaOH). [Daly J Org Chem 21 1553 1956, Bullock et al. J Am Chem Soc 78 3693 1956, Beilstein 26 III/IV 3575.]
不和合性
May react with strong oxidizers such as
chlorates, peroxides, nitrates, etc. May release heat on contact
with water. Solid and corrosive amines are chemical
bases. Neutralize acids to form salts plus water in exothermic
reactions. May be incompatible with isocyanates, halogenated
organics, peroxides, phenols (acidic), epoxides,
anhydrides, and acid halides. May generate flammable gaseous
hydrogen in combination with strong reducing agents,
such as hydrides.
廃棄物の処理
Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator
equipped with an afterburner and scrubber. All federal,
state, and local environmental regulations must be
observed.
N6-ベンジルアデニン 上流と下流の製品情報
原材料
準備製品