トリフェニルすずクロリド 化学特性,用途語,生産方法
外観
白色～ほとんど白色, 結晶性粉末
溶解性
水に不溶, 有機溶媒に可溶。ジクロロメタンに溶け、水にほとんど溶けない。
使用
Chlorotriphenylstannane is used in the synthesis of nanoparticles which bear triamide ligands.
定義
ChEBI: An organotin compound that is triphenylstannane in which the hydrogen attached to tin is replaced by a chloro group. A fungicide used to control blights on potatoes, leaf spot diseases on sugar beet and anthracnose on beans.
一般的な説明
White crystalline solid, insoluble in water; soluble in organic solvents. Used as a rodent repellent, molluscicide, fungicide and insecticide.
空気と水の反応
Hydrolyzes to hydroxide in water.
反応プロフィール
Chlorotriphenyltin is in the family of tin compounds widely used as stabilizers for plastics, additives to paint(as antifouling agents). Some have catalytic properties. Examples include butyl tin, dibutyl tin oxide. Their main hazard is associated with their high toxicity, in skin adsorption or inhalation.
健康ハザード
Toxic and irritating to the skin. Dermal exposure may lead to severe skin burns as well as renal failure and possible death. (Non-Specific -- Tin Compounds, Organic) Target organs affected are central nervous system, eyes, liver, urinary tract, skin and the blood.
火災危険
When heated to decomposition, Chlorotriphenyltin emits toxic fumes of chlorides. Hydrolyzes to hydroxide in water. Stable when stored in dark with dry air.
安全性プロファイル
Poison by ingestion,
intraperitoneal, and intravenous routes.
Experimental reproductive effects. Mutation
data reported. An insect chemosterilant. See
also TIN COMPOUNDS. When heated to
decomposition it emits toxic fumes of Cl-.
純化方法
Purify it by distillation, followed by recrystallisation from MeOH by adding pet ether (b 30-60o), m 105-106o [Kozeschow et al. Chem Ber 67 1348 1934], or by crystallisation from Et2O, or 5 parts of EtOH and a small volume of pet ether. [Krause Chem Ber 51 914 1918.] It sublimes in a vacuum. [Beilstein 16 H 914, 16 I 540, 16 II 625, 16 III 1240, 16 IV 1606.] HIGHLY TOXIC.
トリフェニルすずクロリド 上流と下流の製品情報
原材料
準備製品