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N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ

N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ 化学構造式
23135-22-0
CAS番号.
23135-22-0
化学名:
N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ
别名:
ビダート;2-ジメチルアミノ-N-(メチルカルバモイルオキシ)-2-オキソアセトイミドチオ酸S-メチル;N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ;メチル-N',N'-ジメチル-N-[(メチルカルバモイル)オキシ]-1-チオオキサムイミデート;オキサミル;チオキサミル;オキサミル標準品;メチル-N'-N'-ジメチル-N-[(メチルカルバモイル)オキシ]-1-チオオキサムイミデート;メチル-N',N'-ジメチル-N-[(メチルカルバモイル)オキシ]-1-チオオキサムイミデート (別名 オキサミル);オキサミル STANDARD;オキサミル Standard, 100 µg/mL in MeOH;オキサミル, 0.1 mg/mL in Acetonitrile
英語化学名:
Oxamyl
英語别名:
Blade;d-1410;d 1410;oxamil;OXAMYL;VYDATE;vydateg;vydatek;vydatel;dpx1410
CBNumber:
CB7311293
化学式:
C7H13N3O3S
分子量:
219.26
MOL File:
23135-22-0.mol

N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ 物理性質

融点 :
100°C
比重(密度) :
0.9700
蒸気圧:
5.1×10-5Pa (25 °C)
屈折率 :
1.6630 (estimate)
貯蔵温度 :
0-6°C
外見 :
neat
水溶解度 :
28 g/100 mL
BRN :
2212753
CAS データベース:
23135-22-0(CAS DataBase Reference)
NISTの化学物質情報:
Oxamyl(23135-22-0)
EPAの化学物質情報:
Ethanimidothioic acid, 2-(dimethylamino)-N-[[(methylamino) carbonyl]oxy]-2-oxo-, methyl ester(23135-22-0)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T+;N,N,T+
Rフレーズ  21-26/28-51/53
Sフレーズ  36/37-45-61
RIDADR  UN 2811
WGK Germany  3
RTECS 番号 RP2300000
国連危険物分類  6.1(a)
容器等級  I
有毒物質データの 23135-22-0(Hazardous Substances Data)
毒性 LD50 orally in rats: 5 mg/kg (Fahmy)
PRTR法 第1種指定化学物質
毒劇物取締法 II
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H300 飲み込むと生命に危険 急性毒性、経口 1, 2 危険 P264, P270, P301+P310, P321, P330,P405, P501
H312 皮膚に接触すると有害 急性毒性、経皮 4 警告 P280,P302+P352, P312, P322, P363,P501
H330 吸入すると生命に危険 急性毒性、吸入 1, 2 危険 P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H411 長期的影響により水生生物に毒性 水生環境有害性、慢性毒性 2
注意書き
P260 粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。
P264 取扱い後は皮膚をよく洗うこと。
P264 取扱い後は手や顔をよく洗うこと。
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P284 呼吸用保護具を着用すること。
P301+P310 飲み込んだ場合:直ちに医師に連絡すること。

N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ 価格 もっと(10)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-531-03 オキサミル
Oxamyl, 0.1 mg/mL in Acetonitrile
23135-22-0 1mL ¥4400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-632-17 オキサミル
Oxamyl, 0.1 mg/mL in Acetonitrile
23135-22-0 1mL ¥4400 2018-12-26 購入
関東化学株式会社(KANTO) 49801-51 オキサミル標準品
Oxamyl standard
23135-22-0 100mg ¥14000 2018-12-13 購入
Sigma-Aldrich Japan 36184 オキサミル PESTANAL?, analytical standard
Oxamyl PESTANAL?, analytical standard
23135-22-0 100mg ¥17500 2018-12-25 購入
Sigma-Aldrich Japan 442730 オキサミル analytical standard
Oxamyl analytical standard
23135-22-0 442730 ¥10300 2018-12-25 購入

N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ 化学特性,用途語,生産方法

外観

白色, 結晶~結晶性粉末

溶解性

水280g/l (25℃) メタノール1440, エタノール330, アセトン670, トルエン10 (全g/kg25℃)。水280g/l(25℃)。メタノール1,440, エタノール330, アセトン670, トルエン10(全てg/kg 25℃)。水、エタノール及びアセトンに溶ける。

農薬用途

殺虫剤、ダニ駆除剤、線虫駆除剤

使用

Oxamyl is a pesticide used in the treatment and protection of crops from parasites and insects.

使用

Insecticide, nematocide, acaricide.

使用

Oxamyl is a broad spectrum systemic insecticide/nematicide. It exhibits both oral and contact toxicity to control both sucking and chewing insects and mites in a wide variety of row crops, fruits, vegetables and ornamentals.

农业用途

Insecticide, Nematicide, Acaricide: A systemic and contact insecticide/acaricide and nematicide, oxamyl is a restricted use pesticide used on apples, bananas, carrots, celery, citrus, cotton, cucumbers, eggplants, garlic, ginger, muskmelon (including cantaloupe and honeydew melon), onion (dry bulb), peanuts, pears, peppers, peppermint, pineapples, plantains, potatoes, pumpkins, soybeans, spearmint, squash, sweet potatoes, tobacco, tomatoes, watermelons, yams. Oxamyl is also used on non-bearing apple, cherry, citrus, peach, pear, and tobacco. It is applied directly onto plants or the soilsurface. It is available in both liquid and granular form, but the granular form is banned in the U.S. It has no residential use. Registered for use in EU countries[115

製品名

BLADE®; D-1410®; DPX 1410®; INSECTICIDE-NEMACIDE 1410®; OXAMYL CARBAMATE INSECTICIDE®; THIOXAMYL®; VYDATE®; VYDATE® 10G; VYDATE L®; VYDATE INSECTICIDE/NEMATICIDE®; VYDATE OXAMYL INSECTICIDE/NEMATOCIDE®[C]

安全性プロファイル

Poison by ingestion, skin contact, and inhalation. Experimental reproductive effects. Moderately toxic by skin contact. When heated to decomposition it emits very toxic fumes of NOx and SOx

職業ばく露

Oxamyl is a white crystalline solid. Sulfur or garlic-like odor. Molecular weight=219.3

環境運命予測

Soil. Oxamyl rapidly degraded in a loamy sand and fine sand soil at 25°C to carbon dioxide and the intermediate methyl N-hydroxy-N,N-dimethyl-1-thiooxaminidate (Rajagopol et al., 1984). The reported half-life in soil is approximately one week (Worthing and Hance, 1991). Ou and Rao (1986) reported a half-life in soil of 8–50 days. The reported half-lives of oxamyl in Pitstone, Devizes, Sutton Veany and Mepal soils at 15°C were reported to be 10.2–13.1, 6.2, 7.1 and 17.8 days, respectively (Bromilow et al., 1980). Smelt et al. (1987) reported that oxamyl degraded at a higher rate in field plots after repeated applications of this nematocide than in soils that received no treatment. The repeated applications of oxamyl to soils probably induced microbial activity, which resulted in the accelerated disappearance of this compound.
Harvey and Han (1978) reported a half-life of 8 days for oxamyl in soil.
Groundwater. According to the U.S. EPA (1986) oxamyl has a high potential to leach to groundwater.
Plant. Dislodgable residues of oxamyl on cotton leaf 0, 24, 48, 72 and 96 hours after application (0.41 kg/ha) were 1.5, 1.1, 1.2, 0.85 and 0.76 mg/m2, respectively (Buck et al., 1980).
Chemical/Physical. The hydrolysis half-lives of oxamyl in a sterile 1% ethanol/water solution at 25°C and pH values of 4.5, 6.0, 7.0 and 8.0, were 300, 17, 1.6 and 0.20 weeks, respectively (Chapman and Cole, 1982). Under alkaline conditions, oxam

代謝経路

Oxamyl degrades in soils, plants and animals following common metabolic pathways. Primary degradation reactions include the hydrolysis of the carbamate ester to yield the corresponding oxyimidothioate and nitrile. Other major metabolic reactions include N-demethylation and the hydration/oxidation of the nitriles to the corresponding amides and acids. The majority of the oxamyl metabolites are recovered as conjugates in plants and animals. No metabolites containing the oxidised thiomethyl group were observed. The primary degradation/metabolic pathways of oxamyl are presented in Scheme 1.

輸送方法

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2991 Carbamate pesticides, liquid, toxic, flammable, flash point <23°C, Hazard Class: 6.1; Labels: 6.1-Poisonous material, 3-Flammable liquid.

Degradation

Oxamyl (1) was stable under acidic conditions but hydrolysed rapidly under basic conditions at 25 °C with DT50 values of >30 days at pH 5, 8 days at pH 7, and 3 hours at pH 9 (McNally and Wheeler, 1988). Cleavage of the methylcarbamoyl bond yielded methyl 2-( dimethylamino)- N-hydroxy-2-oxoethanimidothioate (2) as the primary hydrolysis product.
Exposure to artificial sunlight enhanced the degradation of oxamyl in pH 5 solution (DT50 7 vs. >30 days) to yield compound 2 (McNally, 1988). Rapid degradation of oxamyl was also observed in natural water exposed to natural sunlight (DT50 <1 day, Harvey and Han, 1978a). Compound 2 and its geometrical isomer (3) were major products observed in natural and distilled water exposed to artificial and natural sunlight. Further hydrolysis yielded (dimethy1amino)oxoacetica cid (4) as a minor photodegradation product in natural water exposed to natural sunlight.

不和合性

Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur).

廃棄物の処理

Consult with environmental regulatory agencies for guidance on acceptable disposal 2264 Oxamyl practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Small quantities may be treated with alkali and buried in a landfill. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ 上流と下流の製品情報

原材料

準備製品


N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ 生産企業

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23135-22-0(N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ)キーワード:


  • 23135-22-0
  • 1-(dimethylcarbamoyl)-n-((methylcarbamoyl)oxy)thio-formidicacimethyles
  • 2-(dimethylamino)-n-(((methylamino)carbonyl)oxy)-2-oxoethanimidothioicacidm
  • 2-(dimethylamino)-n-(((methylamino)carbonyl)oxy)-ethanimidothioicacimethy
  • 2-(dimethylamino)-n-[[(methylamino)-carbonyl]oxy]-2-oxoethanimidothioicacidme
  • 2-Dimethylamino-1-(methylthio)glyoxal O-methylcarbamoylmonoxime
  • 2-dimethylamino-1-(methylthio)glyoxalo-methylcarbamoylmonoxime
  • Blade
  • caswellno561a
  • d 1410
  • d-1410
  • dioxamyl
  • Dpx 1410
  • Dpx 1410 l
  • Methyl (1Z)-2-(dimethylamino)-N-([(methylamino)carbonyl]oxy)-2-oxoethanimidothioate
  • Methyl 1-(dimethylcarbamoyl)-N-(methylcarbamoyloxy)thioformimidate
  • Methyl 2-(dimethylamino)-N-(((methylamino)carbonyl)oxy)-2-oxoethanimidothioate
  • methyl1-(dimethylcarbamoyl)-n-(methylcarbamoyloxy)thioformimidate
  • methyl2-(dimethylamino)-n-(((methylamino)carbonyl)oxy)-2-oxoethanimidothioat
  • methyl2-(dimethylamino)-n-(((methylamino)carbonyl)oxy)-2-oxoethanimidothioate
  • N,N-Dimethyl-alpha-methylcarbamoyloxyimino-alpha-(methylthio)acetamide
  • N',N'-Dimethyl-N-((methylcarbamoyl)oxy)-1-thiooxamimidic acid methyl ester
  • n’,n’-dimethyl-n-((methylcarbamoyl)oxy)-1-methylthio-oxamimidicaci
  • n’,n’-dimethyl-n-((methylcarbamoyl)oxy)-1-thiooxamimidicacidmethylester
  • n’,n’-dimethyl-n-[(methylcarbamoyl)oxy]-1-thiooxamimidicacidmethylester
  • n’n’-dimethyl-n-((methylcarbamoyl)oxy-1-thio-oxamimidicacimethylester
  • Nematicide 1410
  • oxamil
  • Oxamimidic acid, N',N'-dimethyl-N-((methylcarbamoyl)oxy)-1-methylthio-
  • Oxamimidic acid, N',N'-dimethyl-N-[(methylcarbamoyl)oxy]-1-thio-, methyl ester
  • Oxamyl (pesticide)
  • ビダート
  • 2-ジメチルアミノ-N-(メチルカルバモイルオキシ)-2-オキソアセトイミドチオ酸S-メチル
  • N-メチルカルバミド酸[(ジメチルカルバモイル)(メチルチオ)メチレン]アミノ
  • メチル-N',N'-ジメチル-N-[(メチルカルバモイル)オキシ]-1-チオオキサムイミデート
  • オキサミル
  • チオキサミル
  • オキサミル標準品
  • メチル-N'-N'-ジメチル-N-[(メチルカルバモイル)オキシ]-1-チオオキサムイミデート
  • メチル-N',N'-ジメチル-N-[(メチルカルバモイル)オキシ]-1-チオオキサムイミデート (別名 オキサミル)
  • オキサミル STANDARD
  • オキサミル Standard, 100 µg/mL in MeOH
  • オキサミル, 0.1 mg/mL in Acetonitrile
  • カーバメート系殺虫剤
  • 殺線虫剤
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