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4-ホスホノ-3-アザブタン酸

4-ホスホノ-3-アザブタン酸 化学構造式
1071-83-6
CAS番号.
1071-83-6
化学名:
4-ホスホノ-3-アザブタン酸
别名:
(カルボキシメチル)アミノメチルホスホン酸;[(ホスホノメチル)アミノ]酢酸;N-(ホスホノメチル)-グリシン;N-(ホスホノメチル)グリシン;グリホサート;N-ホスホノメチルグリシン;カルボキシメチルアミノメチルホスホン酸;グリホセート;グリホゼート;4-ホスホノ-3-アザブタン酸;グリホサト;グリホサート標準品;グリホサート標準液;N-(ホスホノメチル)グリシン (別名:グリホサート);グリホサートN-(ホスフォノメチル)グリシン;グリホサート STANDARD;グリホサート IN WATER;グリホサート標準物質;グリホサート Standard, 0.1 mg/mL in Water;グリホサート Standard, 1000 µg/mL in H2O
英語化学名:
Glyphosate
英語别名:
AMMO;TOTAL;ASSET;BRAKE;sting;RAUDO;rodeo;sonic;TILLER;Hockey
CBNumber:
CB7680517
化学式:
C3H8NO5P
分子量:
169.07
MOL File:
1071-83-6.mol

4-ホスホノ-3-アザブタン酸 物理性質

融点 :
230 °C (dec.)(lit.)
比重(密度) :
1.74
闪点 :
230°C
貯蔵温度 :
APPROX 4°C
外見 :
solid
水溶解度 :
1.2 g/100 mL
Decomposition :
230 ºC
Merck :
13,4525
BRN :
2045054
安定性::
Stable. Incompatible with metals, strong oxidizing agents, strong bases. May be light sensitive.
CAS データベース:
1071-83-6(CAS DataBase Reference)
EPAの化学物質情報:
Glycine, N-(phosphonomethyl)-(1071-83-6)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  Xi,N,Xn
Rフレーズ  41-51/53-62-37/38-36/37/38-36-22
Sフレーズ  26-39-61-2-37-36
RIDADR  UN 3077 9/PG 3
WGK Germany  2
RTECS 番号 MC1075000
HSコード  29319090
有毒物質データの 1071-83-6(Hazardous Substances Data)
毒性 LD50 in rats, mice (mg/kg): 4873, 1568 orally (Bababunmi)
化審法 一般化学物質
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H318 重篤な眼の損傷 眼に対する重篤な損傷性/眼刺激 性 1 危険 P280, P305+P351+P338, P310
H411 長期的影響により水生生物に毒性 水生環境有害性、慢性毒性 2
注意書き
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P305+P351+P338 眼に入った場合:水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。
P391 漏出物を回収すること。
P501 内容物/容器を...に廃棄すること。

4-ホスホノ-3-アザブタン酸 価格 もっと(18)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-547 グリホサート in Water
Glyphosate in Water, 0.1 mg/mL in Water
1071-83-6 1mL ¥7400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-015NB-250 グリホサート
Glyphosate
1071-83-6 250mg ¥9200 2018-12-26 購入
関東化学株式会社(KANTO) 17575-96 グリホサート標準品 >95.0%(HLC)
Glyphosate standard >95.0%(HLC)
1071-83-6 200mg ¥12000 2018-12-13 購入
関東化学株式会社(KANTO) 49828-19 グリホサート標準液
Glyphosate standard solution
1071-83-6 10mL ¥8500 2018-12-13 購入
Sigma-Aldrich Japan 337757 N-(ホスホノメチル)グリシン 96%
N-(Phosphonomethyl)glycine 96%
1071-83-6 250mg ¥4500 2018-12-25 購入

4-ホスホノ-3-アザブタン酸 MSDS


Bronco

4-ホスホノ-3-アザブタン酸 化学特性,用途語,生産方法

用途

農薬(除草剤) (NITE CHRIP)

化学的特性

Glyphosate is a broad-spectrum, non-selective systemic herbicide. It is a colorless crystal at room temperature and is soluble in acetone, ethanol, xylene, and water. Glyphosate is used for the control of annual and perennial plants, including grasses, sedges, broadleaved weeds, and woody plants. It can be used on non-cropland as well as on many varieties of crops. Glyphosate itself is an acid, but it is commonly used in salt form, most commonly isopropylamine salt. It may also be available in acidic or trimethylsulfonium salt forms. It is generally distributed as water-soluble concentrates and powders. Glyphosate is a GUP.

化学的特性

Glyphosate, an organophosphate/carboxylic acid (substituted), is a colorless crystalline powder. Often used as a liquid in a carrier solvent which may change physical and toxicological properties.

使用

Nonselective, postemergence, broad spectrum herbicide used to control annual and perennial grasses, sedges, broad-leaved and emerged aquatic weeds. This herbicide is also used to control insects on fruit trees.

使用

Herbicide

一般的な説明

Odorless white powder. Decomposition begins at approximately 419°F (darkens). pH (1% solution in water) 2.5.

反応プロフィール

Glyphosate may react with galvanized steel or unlined steel (except stainless steel) containers to produce hydrogen gas which may form a highly combustible or explosive gas mixture. Glyphosate can react with caustic (basic) materials to liberate heat. Glyphosate is corrosive to iron.

健康ハザード

Glyphosate is practically non-toxic if ingested, with a reported acute oral LD50 of 5600 mg/kg in the rat. The toxicities of the technical acid (glyphosate) and the formulated product (Roundup) are nearly the same. Laboratory animals, such as rats, dogs, mice, and rabbits, exposed to glyphosate for 2 years did not indicate any kind of adverse health effects.

火災危険

Flash point data for Glyphosate are not available; however, Glyphosate is probably combustible.

安全性プロファイル

Poison by intraperitoneal route. Moderately toxic by ingestion. Human systemic effects: arrhythmias, blood pressure lowering, body temperature increase, change in heart rate, convulsions, darrhea, fibrosing alveolitis, fibrosis, hypermoultty, respiratory depression, respiratory stimulation. Used as an herbicide. When heated to decomposition it emits very toxic fumes of NOx and POx.

職業ばく露

A potential danger to those involved in the manufacture, formulation, and application of this nonselective and nonresidual pre-emergence organophos phate herbicide. Has wide residential use in the United States for the control of weeds.

環境運命予測

Soil. Degrades microbially in soil releasing phosphoric acid, N-nitrosoglyphosate (Newton et al., 1984), ammonia (Cremlyn, 1991), N,N-dimethylphosphinic acid, N-methylphosphinic acid, aminoacetic acid (glycine), N-methylaminoacetic acid (sarcosine), hydroxymethylphosphonic acid (Duke et al., 1991), aminomethylphosphonic acid (Normura and Hilton, 1977; Rueppel et al., 1977; Hoagland, 1980; Duke et al., 1991; Muir, 1991) and carbon dioxide (Sprankle et al., 1975; Cremlyn, 1991). N-Nitrosoglyphosate also formed from the nitrosation of glyphosate in soil solutions containing nitrite ions (Young and Kahn, 1978).
The reported half-life of glyphosate in soil is <60 days (Hartley and Kidd, 1987). In the laboratory, experimentally determined dissipation rates of glyphosate in a Lintonia sandy loam, Drummer silty clay, Norfolk sandy loam and Raye silty loam were 0.028
Plant. In a forest brush field ecosystem, the half-life of glyphosate in foliage and litter ranged from 10.4 to 26.6 days, respectively (Newton et al., 1984).
Photolytic. When an aqueous solution of glyphosate (1 ppm) was exposed to outdoor sunlight for 9 weeks (from August 12 through October 15, 1983), aminomethylphosphonic acid and ammonia formed as major and minor photoproducts, respectively (Lund-H?ie and Friestad, 1986). More than 90% degradation was observed after only 4 weeks of exposure. Photodegradation was also observed when an aqueous solution was exposedindoors to UV light (λ = 254 nm). The reported half-lives of this reaction at starting concentrations of 1.0 and 2,000 ppm were 4 days and 3–4 weeks, respectively. When aqueous solutions were exposed indoors to sodium light (λ = 550–650 nm) and mercury light (λ = 400–600 nm), no photo-degradation occurred (Lund-H?ie and Friestad, 1986).
Chemical/Physical. Under laboratory conditions, the half-life of glyphosate in natural waters was 7–10 weeks (Muir, 1991). A 1% aqueous solution has a pH of 2.5 (Keith and Walters, 1992). This suggests glyphosate will react with alkalies and amin

代謝経路

The photolytic degradation of glyphosate results in the formation of glycine, (aminomethyl)phosphonic acid (AMPA), and NH3. Glyphosate undergoes nitrogen ? carbon cleavage on reaction with m- chloroperoxybenzoic acid, leading ultimately to many of the same products formed on their metabolism and environmental degradation. It is suggested that insoluble complexes of glyphosate with iron(III), copper(II), calcium, and magnesium ions are formed at near-neutral pH, a mechanism of which is the inactivation of glyphosate in contaminated groundwater.268 The bacterium degrades high levels of glyphosate, primarily by converting to AMPA. Appreciable uptake of glyphosate is observed with seedlings and leaves and to a lesser extent with culture cells in the form of non-metabolized glyphosate, with AMPA as the only detectable metabolite.

輸送方法

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz ardous material, Technical Name Required.

不和合性

Organophosphates are susceptible to for mation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water, and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithio carbamates, isocyanates, mercaptans, nitrides, sulfides (releasing heat, toxic, and possibly flammable gases), thio sulfates, and dithionites (releasing hydrogen sulfate and oxides of sulfur). Solutions are corrosive to iron, unlined steel, and galvanized steel, forming a highly combustible or explosive gas mixture. Do not store glyphosate in contain ers made from these materials.

4-ホスホノ-3-アザブタン酸 上流と下流の製品情報

原材料

準備製品


4-ホスホノ-3-アザブタン酸 生産企業

Global( 315)Suppliers
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1071-83-6(4-ホスホノ-3-アザブタン酸)キーワード:


  • 1071-83-6
  • KERNEL(R)
  • landmaster
  • ENVISION(R)
  • tumbleweed
  • TOTAL
  • TILLER
  • GLYPHOSATE 62 % IPA SALT
  • Rounduuuuup(Monsanto)
  • Paraquat tech
  • roundup(monsanto)
  • N-(PHOSPHONOMETHYL)-GLYCINE PLANT CELL*C ULTURE TEST
  • GLYPHOSATE, 1GM, NEAT
  • GLYPHOSATE PESTANAL (N-(PHOSPHONO- METHY
  • GLYPHOSATE 1X1ML DI WATER 1000UG/ML
  • Glyphosate, 95% Technical
  • Glyphosate95%(Ida)
  • glyphosate (iso,ansi,wssa,jmaf)
  • GLYPHOSATE98%
  • GLIPHOZAT
  • GLIPHOSATE
  • GLYPHOSPHATE
  • glyphosate acid
  • Glyphosate isopropyl amine salt aqueous solution(41%)
  • N-PHOSPHANO METHYL GLYCINE
  • GlyphoMax
  • Glyphosate CT
  • Herbatop
  • Hockey
  • Kickdown
  • Klinik
  • (カルボキシメチル)アミノメチルホスホン酸
  • [(ホスホノメチル)アミノ]酢酸
  • N-(ホスホノメチル)-グリシン
  • N-(ホスホノメチル)グリシン
  • グリホサート
  • N-ホスホノメチルグリシン
  • カルボキシメチルアミノメチルホスホン酸
  • グリホセート
  • グリホゼート
  • 4-ホスホノ-3-アザブタン酸
  • グリホサト
  • グリホサート標準品
  • グリホサート標準液
  • N-(ホスホノメチル)グリシン (別名:グリホサート)
  • グリホサートN-(ホスフォノメチル)グリシン
  • グリホサート STANDARD
  • グリホサート IN WATER
  • グリホサート標準物質
  • グリホサート Standard, 0.1 mg/mL in Water
  • グリホサート Standard, 1000 µg/mL in H2O
  • グリホサート Standard, 5.0 mg/mL in H2O
  • グリホサート, 0.1 mg/mL in Water
  • グリフォセート
  • 除草剤
  • 代謝産物
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