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ペルオキシジナトリウム

ペルオキシジナトリウム 化学構造式
1313-60-6
CAS番号.
1313-60-6
化学名:
ペルオキシジナトリウム
别名:
ペルオキシジナトリウム;過酸化ナトリウム;過酸化ソ-ダ;過酸化ナトリウム GRANULAR,+140 MESH PARTICLE SIZE,REAGENT GRADE,97%;過酸化ナトリウム PURISS. P.A.,ACS REAGENT,REAG. ISO,≥95%;過酸化ナトリウム/ 95+%;過酸化ナトリウム, 95%;過酸化ナトリウム, min. 93% (ACS)
英語化学名:
Sodium peroxide
英語别名:
Oxolin;flocool;Solozone;Na2-(O2);Flocool 180;solozone[qr];Oxygen powder;SODIUM DIOXIDE;flocool180[qr];Natriumperoxid
CBNumber:
CB7853032
化学式:
Na2O2
分子量:
77.98
MOL File:
1313-60-6.mol

ペルオキシジナトリウム 物理性質

融点 :
460 °C (dec.)(lit.)
沸点 :
657°C
比重(密度) :
2.8
闪点 :
657°C
貯蔵温度 :
Store at +15°C to +25°C.
溶解性:
Soluble in acid. Insoluble in alkali.
外見 :
beads (small)
色:
Yellow
比重:
2.805
PH:
12.8 (100g/l, H2O, 20℃)
水溶解度 :
Soluble in water, forming NaOH and H{2}O{2}. Soluble in acid. Insoluble in alkali.
Sensitive :
Air Sensitive & Hygroscopic
Merck :
14,8655
安定性::
Reacts violently with water. Contact with combustible materials may cause fire or explosion. Incompatible with strong oxidizing agents, alcohols, organic materials, acids, powdered metals. Absorbs carbon dioxide from the air.
CAS データベース:
1313-60-6(CAS DataBase Reference)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  O,C
Rフレーズ  8-35
Sフレーズ  8-27-39-45
RIDADR  UN 1504 5.1/PG 1
WGK Germany  1
RTECS 番号 WD3450000
3-9-23
TSCA  Yes
HSコード  2815 30 00
国連危険物分類  5.1
容器等級  I
消防法 危-1-PO-1-I
化審法 1-496
毒劇物取締法 III
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H271 火災または爆発のおそれ;強酸化性物質 酸化性液体; 酸化性固体 1 危険 P210, P220, P221, P280, P283,P306+P360, P371+P380+P375,P370+P378, P501
H314 重篤な皮膚の薬傷?眼の損傷 皮膚腐食性/刺激性 1A, B, C 危険 P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
注意書き
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P220 衣類/.../可燃物から遠ざけること。
P221 可燃物と混合を回避するために予防策をとること。
P260 粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P283 防火服/防炎服/耐火服を着用すること。
P303+P361+P353 皮膚(または髪)に付着した場合:直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。
P305+P351+P338 眼に入った場合:水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。
P310 ただちに医師に連絡すること。
P370+P378 火災の場合:消火に...を使用すること。
P371+P380+P375 大火災の場合で大量にある場合:区域より退避さ せ、爆発の危険性に応じ、離れた距離から消火する こと。
P405 施錠して保管すること。

ペルオキシジナトリウム 価格 もっと(24)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01AFAL13306 過酸化ナトリウム, 95%
Sodium peroxide, 95%
1313-60-6 50g ¥10940 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01AFAL13306 過酸化ナトリウム, 95%
Sodium peroxide, 95%
1313-60-6 250g ¥43840 2018-12-26 購入
関東化学株式会社(KANTO) 20770-3A 過酸化ナトリウム
Sodium peroxide
1313-60-6 100g ¥11200 2018-12-13 購入
関東化学株式会社(KANTO) 20770-2A 過酸化ナトリウム
Sodium peroxide
1313-60-6 25g ¥4800 2018-12-13 購入
Sigma-Aldrich Japan 223417 過酸化ナトリウム granular, +140?mesh particle size, reagent grade, 97%
Sodium peroxide granular, +140?mesh particle size, reagent grade, 97%
1313-60-6 100g ¥16500 2018-12-25 購入

ペルオキシジナトリウム 化学特性,用途語,生産方法

溶解性

水に易溶 (分解), エタノールに不溶。水に溶けやすく、その時酸素を発生して発熱する。エタノール又はその他の可燃性物質に触れると発火する。

用途

・酸化剤として動植物繊維、羽毛、骨、象牙、ワックスなどの漂白・過酸化物、過ホウ酸塩などの製造・分析試薬・二酸化炭素吸収剤として潜水艦などの空気浄化用・融解して小立方体に固めたものはオキソンという商品名で酸素発生剤

使用上の注意

強い酸化性があるので、有機物及び還元性物質との接触又は混合を避けて下さい。吸湿しやすいので、使用後は直ちに栓又は封をして下さい。

化学的特性

Sodium peroxide, Na202, is a fire-hazardous white powder that yellows when heated and causes ignition when in contact with water. Sodium peroxide is decomposed by heating, although this is not easily accomplished. It is stable in dry air; however, in moist air,or when acted on by water, it decomposes readily. It can be a powerful oxidizer and a powerful reducing agent, depending on conditions. Sodium peroxide is also used as a bleach, in medicine soap, and in the decomposition of minerals.

使用

Bleaching animal and vegetable fibers, feathers, bones, ivory, wood, wax, sponges, coral; rendering air charged with CO2 respirable as in torpedo boats, submarines, diving bells, etc.; purifying air in sick rooms; dyeing and printing textiles; chemical analysis. General oxidizing agent.

定義

Exists as impurity (about 10%) in sodium peroxide, obtained by heat- ing sodium peroxide in oxygen, reacts with water to yield hydrogen peroxide, oxygen, and sodium hydroxide.

定義

sodium peroxide: A whitish solid(yellow when hot), Na2O2, soluble inice-water and decomposed in warmwater or alcohol; r.d. 2.80; decomposesat 460°C. A crystalline octahydrate(hexagonal) is obtained bycrystallization from ice-water. Thecompound is formed by the combustionof sodium metal in excess oxygen.At normal temperatures itreacts with water to give sodiumhydroxide and hydrogen peroxide.It is a powerful oxidizing agent reactingwith iodine vapour to give theiodate and periodate, with carbon at300°C to give the carbonate, andwith nitrogen(II) oxide to give thenitrate. It is used as a bleachingagent in wool and yarn processing,in the refining of oils and fats, andin the production of wood pulp.

一般的な説明

A yellow-white to yellow granular solid. Mixtures with combustible material are readily ignited by friction, heat, or contact with moisture. May vigorously decompose under prolonged exposure to heat, causing the rupture of the containers.

空気と水の反応

Reacts vigorously with water, large amounts react explosively [Haz. Chem. Data 1969. p. 201].

反応プロフィール

Sodium peroxide reacts violently with reducing agents, combustible materials and light metals. Reacts exothermically and rapidly or even explosively with water to form a strong base (NaOH) and oxygen (O2) [Handling Chemicals Safely 1980 p. 854]. A mixture with ammonium persulfate can explode if subjected to friction (crushing in a mortar), if heated, or if a stream of gaseous carbon dioxide is passed over Sodium peroxide [Mellor 10:464 1946-47]. Reacts very vigorously with gaseous hydrogen sulfide; even in the absence of air, the reaction may be accompanied by flame [Mellor 10:132 1946-47]. An explosion results when gaseous carbon dioxide is passed over a mixture of Sodium peroxide with powdered magnesium [Mellor 2:490 1946-47] . Mixtures with acetic acid or acetic anhydride can explode if not kept cold [Von Schwartz 1918 p. 321]. Spontaneously flammable in contact with aniline, benzene, diethyl ether, or organic materials such as paper and wood. Mixtures with charcoal, glycerine, certain oils, and phosphorus burn or explode [Mellor 2:490 1946-47]. A mixture with calcium carbide (powdered) burst into flame when exposed to damp air and exploded when heated [Mellor 2:490 1946-47]. Decomposes, often violently in the presence of catalytic quantities of manganese dioxide [Mellor 2 Supp. 2:635 1961]. Mixing with sulfur monochloride leads to a violent reaction [Mellor 2 Supp. 2:634 1961]. Can react with and cause the ignition of fuels.

危険性

Dangerous fire and explosion risk in contact with water, alcohols, acids, powdered metals, and organic materials. Strong oxidizing agent. Keep dry. Irritant.

健康ハザード

TOXIC; inhalation or contact with vapor, substance, or decomposition products may cause severe injury or death. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.

火災危険

May ignite combustibles (wood, paper, oil, clothing, etc.). React vigorously and/or explosively with water. Produce toxic and/or corrosive substances on contact with water. Flammable/toxic gases may accumulate in tanks and hopper cars. Some may produce flammable hydrogen gas upon contact with metals. Containers may explode when heated. Runoff may create fire or explosion hazard.

安全性プロファイル

A severe irritant to shin, eyes, and mucous membranes. Dangerous fire hazard by chemical reaction; a powerfuloxidizing agent. Reacts explosively or violently under the appropriate conditions with water, acids, powdered metals, acetic acid, acetic anhydride, Al, (Al + CO2), aluminum + aluminum chloride, almond oil, (NH4)2S208, aniline, Sb, As, benzene, boron nitride, calcium aceqlide, charcoal, Cu, cotton wool, (KNO3 + dextrose), diethyl ether, fibrous materials + water, glucose + potassium nitrate, hexamethylene-tetramine, hydrogen sulfide, hydroxy compounds (e.g., ethanol, ethylene glycol, glycerol, sugar), magnesium, (Mg + CO2), MnO2, metals, metals + carbon dioxide + water, nonmetals (e.g., carbon, phosphorus, antimony, arsenic, boron, sulfur, selenium), nonmetal halides (e.g., diselenium dichloride, disulfur dichloride, phosphorus trichloride), organic matter, paraffin, K, silver chloride + charcoal, soap, Na, sodium dioxide, SCl, Sn, Zn, wood, peroxyformic acid, reducing materials. Will react with water or steam to produce heat and toxic fumes. To fight fire, use carbon dioxide or dry chemical. Combustible materials ignited by contact with sodium peroxide should be smothered with soda ash, salt or dolomite mixtures. Chemical fire extinguishers should not be used. If the fire cannot be smothered, it should be flooded with large quantities of water from a hose. When heated to decomposition it emits toxic fumes of Na2O. See also SODIUM HYDROXIDE and PEROXIDES, INORGANIC.

ペルオキシジナトリウム 上流と下流の製品情報

原材料

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ペルオキシジナトリウム 生産企業

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1313-60-6(ペルオキシジナトリウム)キーワード:


  • 1313-60-6
  • Reaxys ID: 16439142
  • SODIUM PEROXIDE GRAN
  • SodiuM peroxide, ACS reagent
  • SODIUM PEROXIDE GRANULAR GR FOR ANALYSIS
  • SODIUM PEROXIDE FOR SYNTHESIS
  • SodiuM Peroxide, Granular, GR ACS
  • Sodium peroxide granular, +140 mesh particle size, reagent grade, 97%
  • Sodium peroxide puriss. p.a., ACS reagent, reag. ISO, >=95%
  • SODIUM PEROXIDE GRANULES
  • Sodium Peroxide, Reag. ISO
  • Sodium Peroxide, For Analysis
  • Sodium peroxide, For analysis ACS
  • Sodium peroxide, p.a.
  • sodiumperoxide[na2(o2)]
  • Sodium peroxide, ACS, 93% min
  • DI-SODIUM PEROXIDE
  • SODIUM DIOXIDE
  • SODIUM PEROXIDE
  • Disodium dioxide
  • Solozone
  • solozone[qr]
  • flocool
  • Sodium binoxide
  • SODIUM PEROXIDE R. G., REAG. ACS, REAG. ISO
  • SODIUM PEROXIDE 93+% A.C.S. REAGENT
  • SODIUM PEROXIDE REAGENT GRADE 97% GR&
  • Sodium peroxide, reagent grade, 97%, granular, particle size +140 mesh
  • SODIUM PEROXIDE, ACS, BAEDS, FOR WURZ-SC HMITT-DECOMPOSIT.
  • SODIUM PEROXIDE, POWDER
  • SodiumPeroxideGr(Granular)
  • ペルオキシジナトリウム
  • 過酸化ナトリウム
  • 過酸化ソ-ダ
  • 過酸化ナトリウム GRANULAR,+140 MESH PARTICLE SIZE,REAGENT GRADE,97%
  • 過酸化ナトリウム PURISS. P.A.,ACS REAGENT,REAG. ISO,≥95%
  • 過酸化ナトリウム/ 95+%
  • 過酸化ナトリウム, 95%
  • 過酸化ナトリウム, min. 93% (ACS)
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