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(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド

(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド 化学構造式
959-98-8
CAS番号.
959-98-8
化学名:
(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド
别名:
(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド;6α,7,8,9α,10,10-ヘキサクロロ-1,5,5aβ,6,9,9aβ-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド;エンドスルファンA;(5aR)-6α,7,8,9α,10,10-ヘキサクロロ-1,5,5aβ,6,9,9aβ-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド;エンドスルファンI;α-ベンゾエピン;6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド;α-エンドスルファン;Α-エンドスルファン標準品;ヘキサクロロヘキサヒドロメタノベンゾジオキサチエピンオキサイド(α);Α‐エンドスルファン標準品;CS_N-10979-100MG_Α-エンドスルファン;Α-エンドスルファン 100ΜG/ML;エンドスルファン I (1000 UG/ML メタノール溶液);Α-エンドスルファン STANDARD;エンドスルファンI STANDARD;エンドスルファン-I (13C9, 100±10ΜG/ML ノナン溶液);Α-エンドスルファン 溶液;エンドスルファン I;α-エンドスルファン Standard, 1000 µg/mL in p-Dioxane
英語化学名:
Endosulfan I
英語别名:
β-osulfan;β-Thiodane;endosulfana;endosulfan1;ENDOSULFAN I;'LGC' (1119);A-ENDOSULFAN;beta-thionex;alpha-Thiodan;ALPHA-BENZOEPIN
CBNumber:
CB8477426
化学式:
C9H6Cl6O3S
分子量:
406.93
MOL File:
959-98-8.mol

(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド 物理性質

融点 :
109°C
比重(密度) :
1.94
蒸気圧:
4.58 x 10-5 mmHg at 25 °C (subcooled liquid vapor pressure calculated from GC retention time data,Hinckley et al., 1990)
闪点 :
-26 °C
貯蔵温度 :
APPROX 4°C
外見 :
neat
水溶解度 :
(mg/L):
0.51 at 20 °C (shake flask-GC, Bowman and Sans, 1983)
0.53 at 25 °C (extraction-GLC, Weil et al., 1974)
BRN :
2950316
Henry's Law Constant:
0.266 at 5 °C, 0.464 at 15 °C, 0.711 at 20 °C, 0.809 at 25 °C, 1.09 at 35 °C; in 3% NaCl solution:1.07 at 5 °C, 2.08 at 15 °C, 4.71 at 25 °C, 6.71 at 35 °C (gas stripping-GC, Cetin et al., 2006)
暴露限界値:
ACGIH TLV: TWA 0.1 mg/m3.
NISTの化学物質情報:
Endosulfan i(959-98-8)
EPAの化学物質情報:
6,9-Methano-2,4, 3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1, 5,5a,6,9,9a-hexahydro-, 3-oxide, (3.alpha.,5a.beta.,6.alpha., 9.alpha.,9a.beta.)-(959-98-8)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T,N,Xn,F
Rフレーズ  24/25-36-50/53-25-67-65-62-51/53-48/20-38-11
Sフレーズ  36/37-45-60-61-62-33-29-16-9
RIDADR  2761
WGK Germany  3
RTECS 番号 RB9275100
国連危険物分類  6.1(a)
容器等級  II
毒性 LC50 (96-hour) for golden orfe 2 mg/L (Hartley and Kidd, 1987), rainbow trout 0.3 mg/L and white sucker 3.0 mg/L (Verschueren, 1983).
化審法 第1種特定化学物質 &_& 化審法施行令第7条 &_& 化審法施行令第8条
安衛法 57-2
PRTR法 1-388
毒劇物取締法 II
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H225 引火性の高い液体および蒸気 引火性液体 2 危険 P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H304 飲み込んで気道に侵入すると生命に危険のおそ れ 吸引性呼吸器有害性 1 危険
H312 皮膚に接触すると有害 急性毒性、経皮 4 警告 P280,P302+P352, P312, P322, P363,P501
H315 皮膚刺激 皮膚腐食性/刺激性 2 警告 P264, P280, P302+P352, P321,P332+P313, P362
H336 眠気やめまいのおそれ 特定標的臓器毒性、単回暴露; 麻酔作用 3 警告 P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 長期にわたる、または反復暴露により臓器の障 害のおそれ 特定標的臓器有害性、単回暴露 2 警告 P260, P314, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
H411 長期的影響により水生生物に毒性 水生環境有害性、慢性毒性 2
注意書き
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P260 粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P301+P310 飲み込んだ場合:直ちに医師に連絡すること。
P370+P378 火災の場合:消火に...を使用すること。
P403+P233 換気の良い場所で保管すること。容器を密閉 しておくこと。
P403+P235 換気の良い場所で保管すること。涼しいところに 置くこと。

(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド 価格 もっと(15)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSAPP-9-099 エンドスルファンI Standard
Endosulfan I Standard, 100 ug/mL in Methanol
959-98-8 1mL ¥8100 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSAS-E0093 α-エンドスルファン Standard
alpha-Endosulfan Standard, 1000 ug/mL in p-Dioxane
959-98-8 1mL ¥14700 2018-12-26 購入
関東化学株式会社(KANTO) 49802-74 α‐エンドスルファン標準品
α‐Endosulfan standard
959-98-8 100mg ¥16000 2018-12-13 購入
Sigma-Aldrich Japan 36659 α-エンドスルファン 溶液 100?μg/mL in hexane, PESTANAL?, analytical standard
α-Endosulfan solution 100?μg/mL in hexane, PESTANAL?, analytical standard
959-98-8 2ml-r ¥14500 2018-12-25 購入
Sigma-Aldrich Japan 45468 α-エンドスルファン PESTANAL?, analytical standard
α-Endosulfan PESTANAL?, analytical standard
959-98-8 100mg ¥19100 2018-12-25 購入

(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド MSDS


endo-1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dimethanol cyclic sulfite

(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド 化学特性,用途語,生産方法

化学的特性

Endosulfan is a chlorinated cyclodiene insecticide. The pure product is a colorless crystalline solid. The technical product is a light to dark brown waxy solid. It has a rotten egg or sulfur odor.

物理的性質

Colorless to brown crystals or flakes with a mild odor similar to terpene or sulfur dioxide.

使用

Insecticide for vegetable crops.

一般的な説明

Brown crystals.

空気と水の反応

Insoluble in water. Slowly hydrolyzes to form sulfur dioxide and diol; hydrolyzes more rapidly under basic or acidic conditions.

反応プロフィール

Endosulfan I is an organochlorine, cyclodiene derivative. Also a sulfite ester. Incompatible with strong oxidizing and reducing agents. Also incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. As an ester Endosulfan I will hydrolyze to form sulfur dioxide and a diol; reaction is more rapid under basic conditions.

健康ハザード

ACUTE/CHRONIC HAZARDS: Highly toxic by ingestion, inhalation, and skin absorption.

火災危険

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.

職業ばく露

Those engaged in the manufacture, formulation, and application of this material

環境運命予測

Soil. Metabolites of endosulfan identified in soils were endosulfandiol (1,4,5,6,7,7- hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dimethanol), endosulfan ether, endosulfan lactone (4,5,6,7,8,8-hexachloro-1,3,3a,4,7,7a-hexahydro-4,7-methane-isobenzofuran-1-one) and endosulfan sulfate (6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,3,4- benzodioxathiepin-3,3-dioxide) (Martens, 1977; Dreher and Podratzki, 1988). These compounds, including endosulfan ether, were also reported as metabolites identified in aquatic systems (Day, 1991). Endosulfan sulfate was the major biodegradation product in soils under aerobic, anaerobic and flooded conditions (Martens, 1977). In flooded soils, endolactone was detected only once whereas endodiol and endohydroxy ether were identified in all soils under these conditions. Under anaerobic conditions, endodiol formed in low amounts in two soils (Martens, 1977).
Indigenous microorganisms obtained from a sandy loam degraded a-endosulfan to endosulfandiol. This diol was converted to endosulfan a-hydroxy ether and trace amounts of endosulfan ether and both were degraded to endosulfan lactone (Miles and Moy, 1979). Using settled domestic wastewater inoculum, a-endosulfan (5 and 10 mg/L) did not degrade after 28 days of incubation at 25°C (Tabak et al., 1981).
Plant. Endosulfan sulfate was formed when endosulfan was translocated from the leaves to roots in both bean and sugar beet plants (Beard and Ware, 1969). In tobacco leaves, a-endosulfan is hydrolyzed to endosulfandiol (Chopra and Mahfouz, 1977). Stewart and Cairns (1974) reported the metabolite endosulfan sulfate was identified in potato peels and pulp at concentrations of 0.3 and 0.03 ppm, respectively. They also reported that the half-life for the conversion of a-endosulfan to b-endosulfan was 60 days. On apple leaves, direct photolysis of endosulfan by sunlight yielded endosulfan sulfate (Harrison et al., 1967).
In carnation plants, the half-lives of a-endosulfan stored under four different conditions, non-washed and exposed to open air, washed and exposed to open air, non-washed and placed in an enclosed container and under greenhouse conditions were 6.79, 6.38, 10.45 and 4.22 days, respectively (Céron et al., 1995).
Surface Water. Endosulfan sulfate was also identified as a metabolite in a survey of 11 agricultural watersheds located in southern Ontario, Canada (Frank et al., 1982). When endosulfan (a- and b- isomers, 10 mg/L) was added to Little Miami River water, sealed and exposed to sunlight and UV light for 1 week, a degradation yield of 70% was observed. After 2 and 4 weeks, 95% and 100% of the applied amount degraded. The major degradation product was identified as endosulfan alcohol by IR spectrometry (Eichelberger and Lichtenberg, 1971).
Photolytic. Thin films of endosulfan on glass and irradiated by UV light (l >300 nm) produced endosulfandiol with minor amounts of endosulfan ether, a lactone, an a-hydroxyether and other unidentified compounds (Archer et al., 1972). When an aqueous solution containing endosulfan was photooxidized by UV light at 90–95°C, 25, 50 and 75% degraded to carbon dioxide after 5.0, 9.5 and 31.0 hours, respectively (Knoevenagel and Himmelreich, 1976).
Chemical/Physical. Endosulfan slowly hydrolyzes forming endosulfandiol and endosulfan sulfate (Kollig, 1993; Martens, 1976; Worthing and Hance, 1991). The hydrolysis rate constant for a-endosulfan at pH 7 and 25°C was determined to be 3.2 ′ 10–3/hour, resulting in a half-life of 9.0 days (Ellington et al., 1988). The hydrolysis half-lives are reduced significantly at varying pHs and temperature. At temperatures (pH) of 87.0 (3.12), 68.0 (6.89) and 38.0°C (8.69), the half-lives were 4.3, 0.10 and 0.08 days, respectively (Ellington et al., 1986). Greve and Wit (1971) reported the hydrolysis half-lives of a- endosulfan at 20°C and pH values of 7 and 5.5 were 36 and 151 days, respectively.
Emits toxic fumes of chlorides and sulfur oxides when heated to decomposition (Lewis, 1990).

輸送方法

UN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

不和合性

Those engaged in the manufacture, formulation, and application of this material

廃棄物の処理

A recommended method for disposal is burial 18 in deep in noncropland, away from water supplies, but bags can be burned. Large quantities should be incinerated at high temperature in a unit with effluent gas scrubbing. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/ mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド 上流と下流の製品情報

原材料

準備製品


(5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド 生産企業

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959-98-8((5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド)キーワード:


  • 959-98-8
  • 1,4,5,6,7,7-hexachloro-,cyclicsulfite,endo-5-norbornene-3-dimethanol
  • 5-Norbornene-2,3-dimethanol, 1,4,5,6,7,7-hexachloro-, cyclic sulfite, endo-
  • 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide, (3alpha,5aalpha,6alpha,9alpha,9aalpha)-
  • 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide, (3alpha,5abeta,6alpha,9alpha,9abeta)-
  • 6,9-methano-2,4,3-benzodioxathiepin,6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-,3-oxide,(3α,5aβ,6α)
  • a-endosulfan-alpha
  • alpha-Thiodan
  • endo-1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dimethanol cyclic sulfite
  • endosulfan1
  • endosulfana
  • endosulfani(alpha)
  • ENDOSULFAN (ALPHA ISOMER)
  • ENDOSULFAN I
  • ENDOSULFAN I (ALPHA ISOMER)
  • 'LGC' (1119)
  • ALPHA-BENZOEPIN
  • ALPHA-1,4,5,6,7,7-HEXACHLOROBICYCLO[2.2.1]-5-HEPTENE-2,3-BIS-(METHYLENE)-SULFITE
  • ALPHA-ENDOSULFAN
  • A-ENDOSULFAN
  • 6,7,8,9,10,10-HEXACHLORO-1,5,5A,6,9,9A-HEXAHYDRO-6,9-METHANO-2,4,3-BENZODIOXATHIEPIN-3-OXIDE, ALPHA ISOMER
  • ENDOSULFAN 1 (ALPHA), 25MG, NEAT
  • ALPHA-ENDOSULFAN PESTANAL, 100 MG
  • ENDOSULFAN (ALPHA ISOMER), 100MG, NEAT
  • endosulfan (alpha isomer) (bsi,iso,ansi,esa)
  • ALPHA-ENDOSULPHAN
  • ENDOSULPHANALPHA
  • 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide, (3.alpha.,5a.beta.,6.alpha.,9.alpha.,9a.beta.)-
  • a-Endosulfan 100mg [959-98-8]
  • Endosulfan (alpha isomer) 100mg [959-98-8]
  • β-osulfan
  • (5aS)-6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド
  • 6α,7,8,9α,10,10-ヘキサクロロ-1,5,5aβ,6,9,9aβ-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド
  • エンドスルファンA
  • (5aR)-6α,7,8,9α,10,10-ヘキサクロロ-1,5,5aβ,6,9,9aβ-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド
  • エンドスルファンI
  • α-ベンゾエピン
  • 6β,7,8,9β,10,10-ヘキサクロロ-1,5,5aα,6,9,9aα-ヘキサヒドロ-6,9-メタノ-2,4,3-ベンゾジオキサチエピン3-オキシド
  • α-エンドスルファン
  • Α-エンドスルファン標準品
  • ヘキサクロロヘキサヒドロメタノベンゾジオキサチエピンオキサイド(α)
  • Α‐エンドスルファン標準品
  • CS_N-10979-100MG_Α-エンドスルファン
  • Α-エンドスルファン 100ΜG/ML
  • エンドスルファン I (1000 UG/ML メタノール溶液)
  • Α-エンドスルファン STANDARD
  • エンドスルファンI STANDARD
  • エンドスルファン-I (13C9, 100±10ΜG/ML ノナン溶液)
  • Α-エンドスルファン 溶液
  • エンドスルファン I
  • α-エンドスルファン Standard, 1000 µg/mL in p-Dioxane
  • エンドスルファンI Standard, 100 µg/mL in Methanol
  • 有機塩素系殺虫剤
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