α-(p-トルエンスルホニル)ベンジルイソシアニド
α-(p-トルエンスルホニル)ベンジルイソシアニド 物理性質
- 融点 :
- 106 °C(dec.)
- 貯蔵温度 :
- under inert gas (nitrogen or Argon) at 2-8°C
- 外見 :
- powder to crystal
- 色:
- White to Light yellow to Light orange
α-(p-トルエンスルホニル)ベンジルイソシアニド 価格
もっと(17)
| メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01COBOR-6229 |
イソシアン化(1-フェニル-1-トシル)メチル
(1-Phenyl-1-tosyl)methyl isocyanide |
36635-66-2 |
25g |
￥425000 |
2024-03-01 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01APOOR1744 |
Isocyano(phenyl)methyl 4-methylphenyl sulphone |
36635-66-2 |
1g |
￥28800 |
2024-03-01 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01APOOR1744 |
Isocyano(phenyl)methyl 4-methylphenyl sulphone |
36635-66-2 |
5g |
￥117600 |
2024-03-01 |
購入 |
|
東京化成工業
|
T3157 |
α-(p-トルエンスルホニル)ベンジルイソシアニド >98.0%(HPLC)(N)
α-(p-Toluenesulfonyl)benzyl Isocyanide
>98.0%(HPLC)(N) |
36635-66-2 |
1g |
￥19400 |
2024-03-01 |
購入 |
|
東京化成工業
|
T3157 |
α-(p-トルエンスルホニル)ベンジルイソシアニド >98.0%(HPLC)(N)
α-(p-Toluenesulfonyl)benzyl Isocyanide
>98.0%(HPLC)(N) |
36635-66-2 |
5g |
￥75600 |
2024-03-01 |
購入 |
α-(p-トルエンスルホニル)ベンジルイソシアニド 化学特性,用途語,生産方法
外観
白色～ほとんど白色粉末～結晶
製造方法
A 1-L, three-necked, roundbottomed flask fitted with an overhead stirrer, a 100 mL addition funnel, and a temperature probe was charged with THF (200 mL) and 1615 (27.6 g, 94.8 mmol). Phosphoryl chloride (17.7 mL, 190 mmol) was added and the resulting solution was stirred for 5 min at 25 C??. After cooling the solution to 0 C??, triethylamine (79.3 mL, 569 mmol) was added slowly over 30¨C45 min while keeping the internal reaction temperature below 10 C??. After the addition of triethylamine was complete, the reaction mixture was warmed to 5¨C10 C?? and maintained at this temperature for 30¨C45 min. Ethyl acetate (140 mL) and water (140 mL) were added sequentially to the reaction mixture, stirring was continued for 5 min, and then the mixture was transferred to a separatory funnel and the aqueous layer was removed. The organic layer was washed with water (2?á140 mL), saturated sodium hydrogen carbonate solution (140 mL), and brine (70 mL). The organic layer was transferred to a 500-mL, round-bottomed flask and concentrated on a rotary evaporator. The residue was diluted with 1-propanol (140 mL) and this solution was concentrated on a rotary evaporator to half of its original volume. The residue was cooled to 5¨C10 C?? for 30 min and the beige solid that crystallized was collected by filtration through a Buchner funnel. The filter cake was rinsed with 1-propanol (2?á75 mL). The beige solid was dried in vacuo for 3¨C4 h to give 18.1¨C19.7 g (70¨C 76%) of a-tosylbenzyl isocyanide 1616.
Structurally analogous to TosMIC 1600 is PhosMIC 1617, which has a phosphonate residue instead of a sulfonate residue. Some representatives have been described by Bartlett.
α-(p-トルエンスルホニル)ベンジルイソシアニド 上流と下流の製品情報
原材料
準備製品
α-(p-トルエンスルホニル)ベンジルイソシアニド 生産企業
Global( 97)Suppliers
α-(p-トルエンスルホニル)ベンジルイソシアニド スペクトルデータ(FT-IR)
36635-66-2(α-(p-トルエンスルホニル)ベンジルイソシアニド)キーワード:
- 36635-66-2
- A-TOSYLBENZYL ISOCYANIDE
- ALPHA-TOSYLBENZYL ISOCYANIDE
- (1-PHENYL-1-TOSYL)METHYL ISOCYANIDE
- 1-([ISOCYANO(PHENYL)METHYL]SULPHONYL)-4-METHYLBENZENE
- alfa-Tosylbenzylisocyanide
- 1-(isocyano(p-tolyl)methylsulfonyl)-4-methylbenzene
- Isocyano(phenyl)methyl 4-methylphenyl sulphone
- Benzene,1-[(isocyanophenylMethyl)sulfonyl]-4-Methyl-
- alpha-(Toluene-4-sulphonyl)benzyl isocyanide
- a-(4-Tolylsulfonyl)benzylisocyanide
- alpha-(Toluene-4-sulphonyl)benzyl isocyanide, 4-{[Isocyano(phenyl)methyl]sulphonyl}toluene, alpha-Tosylbenzyl isocyanide
- Isocyano(phenyl)methyl 4-methylphenyl sulphone 97%
- 1-(Isocyano-phenyl-Methanesulfonyl)-4-Methyl-benzene
- 1-((Isocyano(phenyl)methyl)sulfonyl)-4-methylbenzene
- Isocyano(phenyl)methyl4-methylphenylsulphone97%
- -(p-Toluenesulfonyl)benzyl Isocyanide
- α-(p-Toluenesulfonyl)benzyl Isocyanide
- alpha-(p-Toluenesulfonyl)benzyl Isocyanide
- 5-(isocyanomethylsulfonyl)-2-methyl-5-phenylcyclohexa-1,3-diene
- Isocyano(phenyl)methyl 4-methylphenyl sulfone
- SKL019
- α-(p-Toluenesulfonyl)benzyl Isocyanide
- α-(p-トルエンスルホニル)ベンジルイソシアニド
- α-トシルベンジルイソシアニド
- イソシアン化(1-フェニル-1-トシル)メチル
- イソシアン化A-トシルベンジル