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(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE

化学構造式
470480-32-1
CAS番号.
470480-32-1
化学名:
别名:
英語名:
(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
英語别名:
(S,S,R,R)-TANGPHOS;(S,S',R,R')-TANGPHOS;(1S,1S',2R,2R')-1,1'-DI-TERT-BUTYL-(2,2')-DIPHOSPHOLANE;(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE;(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE;(2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane;2,2'-Biphospholane, 1,1'-bis(1,1-dimethylethyl)-, (1S,1'S,2R,2'R)-;(1S,1S'',2R,2R'')-(+)-1,1''-DI-T-BUTYL-[2,2'']-DIPHOSPHOLANE (S,S,R,R)-TANGPHOS;(1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane,min.95%(S,S,R,R)-TANGPHOS
CBNumber:
CB9117701
化学式:
C16H32P2
分子量:
286.37
MOL File:
470480-32-1.mol

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE 物理性質

融点 :
60-65 °C
沸点 :
353.6±12.0 °C(Predicted)

安全性情報

Rフレーズ  36/37/38
Sフレーズ  22-24/25
WGK Germany  3

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE 価格

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE 化学特性,用途語,生産方法

使用

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Catalytic ligand used in:
  • Preparation of α-borono-substituted alkylarenes by asymmetric hydroboration of styrenes catalyzed by copper(I)
  • Enantioselective synthesis of spiroindane di-Me acetic acid via hydrogenation of spiroindane di-Me acetic acid catalyzed by Ru(II)
  • Asymmetric γ-addition of thiols to allenoates
  • Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution
  • Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE 上流と下流の製品情報

原材料

準備製品

(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE 生産企業

Global( 11)Suppliers
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470480-32-1()キーワード:

1,2-ビス(ジエチルホスフィノ)エタン
  • 470480-32-1
  • (S,S',R,R')-TANGPHOS
  • (S,S,R,R)-TANGPHOS
  • (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
  • (1S,1S',2R,2R')-1,1'-DI-TERT-BUTYL-(2,2')-DIPHOSPHOLANE
  • (1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane,min.95%(S,S,R,R)-TANGPHOS
  • (1S,1S'',2R,2R'')-(+)-1,1''-DI-T-BUTYL-[2,2'']-DIPHOSPHOLANE (S,S,R,R)-TANGPHOS
  • 2,2'-Biphospholane, 1,1'-bis(1,1-dimethylethyl)-, (1S,1'S,2R,2'R)-
  • (2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane
  • (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
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