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テトラメチルチウラムジスルフィド

テトラメチルチウラムジスルフィド 化学構造式
137-26-8
CAS番号.
137-26-8
化学名:
テトラメチルチウラムジスルフィド
别名:
テトラメチルチウラムジスルフィド;チウラッド;1,1'-ジチオビス(N,N-ジメチルチオホルムアミド);チラート;N,N,N',N'-テトラメチルチウラムジスルフィド;スポトレート;ビス(N,N-ジメチルチオカルバモイル)ペルスルフィド;ツアズ;ノメルサン;ツリサン;チウラミル;TMTD剤;ジチオビス(N,N-ジメチルチオホルムアミド);チオサン;フェルナサン;テルサン;デルサン;チラム【殺菌薬】;ポマルソル;レジフィルム
英語化学名:
Tetramethylthiuram Disulfide
英語别名:
TMTD;tmtc;TNTD;Tuex;anles;aules;Heryl;tigam;tm-95;TMTDS
CBNumber:
CB9218792
化学式:
C6H12N2S4
分子量:
240.43
MOL File:
137-26-8.mol

テトラメチルチウラムジスルフィド 物理性質

融点 :
156-158 °C(lit.)
沸点 :
129 °C (20 mmHg)
比重(密度) :
1.43
屈折率 :
1.5500 (estimate)
闪点 :
89°C
貯蔵温度 :
0-6°C
溶解性:
0.0184g/l
外見 :
solid
水溶解度 :
16.5 mg/L (20 ºC)
Merck :
14,9371
BRN :
1725821
暴露限界値:
NIOSH REL: TWA 0.5 mg/m3, IDLH 100 mg/m3; OSHA PEL: 0.5 mg/m3; ACGIH TLV: TWA 5 mg/m3.
InChIKey:
KUAZQDVKQLNFPE-UHFFFAOYSA-N
CAS データベース:
137-26-8(CAS DataBase Reference)
NISTの化学物質情報:
Thiram(137-26-8)
EPAの化学物質情報:
Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-(137-26-8)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  Xn,N
Rフレーズ  20/22-36/38-43-48/22-50/53
Sフレーズ  26-36/37-60-61
RIDADR  UN 2771/2811
WGK Germany  3
RTECS 番号 JO1400000
自然発火温度 316 °F
TSCA  Yes
国連危険物分類  9
容器等級  III
HSコード  29303000
有毒物質データの 137-26-8(Hazardous Substances Data)
毒性 LD50 orally in rats: 640 mg/kg (Gaines)
消防法 危-4-1-II
化審法 (2)-1820 優先評価化学物質
安衛法 変異原性物質
PRTR法 第一種指定化学物質
絵表示(GHS)
注意喚起語 Warning
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H302 飲み込むと有害 急性毒性、経口 4 警告 P264, P270, P301+P312, P330, P501
H315 皮膚刺激 皮膚腐食性/刺激性 2 警告 P264, P280, P302+P352, P321,P332+P313, P362
H317 アレルギー性皮膚反応を起こすおそれ 感作性、皮膚 1 警告 P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 強い眼刺激 眼に対する重篤な損傷性/眼刺激 性 2A 警告 P264, P280, P305+P351+P338,P337+P313P
H332 吸入すると有害 急性毒性、吸入 4 警告 P261, P271, P304+P340, P312
H373 長期にわたる、または反復暴露により臓器の障 害のおそれ 特定標的臓器有害性、単回暴露 2 警告 P260, P314, P501
H400 水生生物に強い毒性 水生環境有害性、急性毒性 1 警告 P273, P391, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P260 粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。
P261 粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P304+P340 吸入した場合:空気の新鮮な場所に移し、呼吸しやすい 姿勢で休息させること。
P305+P351+P338 眼に入った場合:水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。
P501 内容物/容器を...に廃棄すること。

テトラメチルチウラムジスルフィド 価格 もっと(18)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-118N チラム
Thiram
137-26-8 10mg ¥4400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSP-118NB-250 チラム
Thiram
137-26-8 250mg ¥16600 2018-12-26 購入
東京化成工業 B0486 テトラメチルチウラムジスルフィド >98.0%(N)
Tetramethylthiuram Disulfide >98.0%(N)
137-26-8 500g ¥5400 2018-12-04 購入
東京化成工業 B0486 テトラメチルチウラムジスルフィド >98.0%(N)
Tetramethylthiuram Disulfide >98.0%(N)
137-26-8 25g ¥1800 2018-12-04 購入
関東化学株式会社(KANTO) 40088-31 二硫化ビス(ジメチルチオカルバモイル)
Bis(dimethylthiocarbamoyl)disulfide
137-26-8 25g ¥2100 2018-12-13 購入

テトラメチルチウラムジスルフィド MSDS


TMTD

テトラメチルチウラムジスルフィド 化学特性,用途語,生産方法

用途

殺菌剤, 天然ゴム、合成ゴム用加硫促進剤。

効能

殺真菌薬

化学的特性

Thiram is a colorless to yellow, crystalline solid. Characteristic odor. Commercial pesticide products may be dyed blue.

化学的特性

white to almost white powder

使用

antianginal

使用

Thiram is an ectoparasiticide. Thiram is used in agriculture to prevent fungal diseases in seed and crops. Thiram has other applications ranging from use as a topical bactericide to animal repellent.

使用

Rubber accelerator; vulcanizer; seed disinfectant; fungicide; bacteriostat in soap; animal repellent.

使用

Seed disinfectant

定義

ChEBI: An organic disulfide that results from the formal oxidative dimerisation of N,N-dimethyldithiocarbamic acid. It is widely used as a fungicidal seed treatment.

一般的な説明

A liquid solution of a white crystalline solid. Primary hazard is to the environment. Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminates groundwater and waterways.

空気と水の反応

Insoluble in water. Decomposes in acidic media to give toxic products. Decomposes to an extent on prolonged exposure to heat, air or moisture.

反応プロフィール

TMTD is incompatible with oxidizing materials and strong acids. Also incompatible with strong alkalis and nitrating agents .

危険性

Toxic by ingestion and inhalation, irritant to skin and eyes. Body weight and hematologic effects. Questionable carcinogen.

健康ハザード

Inhalation of dust may cause respiratory irritation. Liquid irritates eyes and skin and may cause allergic eczema in sensitive individuals. Ingestion causes nausea, vomiting, and diarrhea, all of which may be persistent; paralysis may develop.

火災危険

Special Hazards of Combustion Products: Toxic and irritating oxides of sulfur are formed. Carbon disulfide may be formed from unburned material.

农业用途

Fungicide, Rodenticide: Thiram is used as a fungicide to prevent crop damage in the field and to prevent crops from deterioration in storage or transport. Thiram is also used as a seed, nut, fruit, and mushroom disinfectant from a variety of fungal diseases. In addition, it is used as an animal repellent to protect fruit trees and ornamentals from damage by rabbits, rodents, and deer. Thiram has been used in the treatment of human scabies, as a sun screen, and as a bactericide applied directly to the skin or incorporated into soap. Thiram is used as a rubber accelerator and vulcanizer and as a bacteriostat for edible oils and fats. It is also used as a rodent repellent, wood preservative, and may be used in the blending of lubricant oils. Registered for use in EU countries. Registered for use in the U.S.

製品名

AAPIROL®; AATACK®; AATIRAM®; ACCELERATOR T®; ACCELERATOR THIURAM®; ACCEL TMT®; AGROSOL POUR-ON®; ANLES®; ARASAN®[C]; ATIRAM®; ATTACK®; AULES®; CHIPCO THIRAM 75®; CRYLCOAT®; CUNITEX®; CYURAM DS®; DELSAN®; EBECRYL®; EKAGOM TB®; EVERSHIELD T SEED PROTECTORANT®; FALITIRAM®; FERMIDE®; FERNACOL®; FERNASAN®; FERNIDE®; FLO PRO T SEED PROTECTANT®; FMC 2070®[C]; FORMALSOL®; HERMAL®; HERYL®; HEXATHIR®; HY-VIC®; KODIAK T®; KREGASAN®; LIQUID MOLY-CO-THI®; MERCURAM®; METIURAC®; MOLY-T®; NA2771®; NOBECUTAN®; NOMERSAN®; NORMERSAN®; OPTIMA®; PANORAM 75®; POLYRAM ULTRA®; POMARSOL®; POMARSOL FORTE®; POMASOL®; PRO-GRO®; PURALIN®; RAXIL®; REZIFILM®; ROOTONE®; ROYAL TMTD®; RTUBAYTAN- THIRAM®; RTU FLOWABLE SOYBEAN FUNGICIDE®; SADOPLON®; SOLUCRYL®; SPOTRETE®; SPOTRETE-F®; SQ 1489®; SRANANSF- X®; TERSAN 75®[C]; TERSANTETRAMETHYL DIURANE SULFIDE®; TETRAPOM®; TETRASIPTON®; THIANOSAN®; THILLATE®; THIMAR®; THIMER®; THIOKNOCK®; THIOSAN®; THIOSCABIN®; THIOTEX®; THIOTOX®; THIRAM 75®; THIRAM 80®; THIRAMAD®; THIRAM B®; THIRAMPA®; THIRASAN®; THIULIN®; THIULIX®; THIURAD®; THIURAMIN®; THIURAMYL®; THYLATE®; TIRAMPA®; TITAN FL®; TRAMETAN®; TRIDIPAM®; TRIPOMOL®; TUADS®; TUEX®; TULISAN®; UCECOAT®; UCECRYL®; UVECRYL®; VANCIDA TM-95®; VANCIDE TM®; VITAFLO 280®; VITAVAX® Thiram; VITAVAX-T®; VUAGT-1-4®; VULCAFOR TMTD®; VULKACIT MTIC®; VULKACIT THIURAM®; VULKACIT THIURAM/C®

接触アレルゲン

TITD is a rubber vulcanization accelerator

接触アレルゲン

This rubber chemical, accelerator of vulcanization, represents the most commonly positive allergen contained in “thiuram mix.” The most frequent occupational categories are the metal industry, homemakers, health services and laboratories, the building industry, and shoemakers. It is also widely used as a fungicide, belonging to the dithiocarbamate group of carrots, bulbs, and woods, and as an insecticide. Thiram is the agricultural name for thiuram.

安全性プロファイル

Poison by ingestion and intraperitoneal routes. Questionable carcinogen with experimental tumorigenic and teratogenic data. Other experimental reproductive effects. Mutation data reported, Affects human pulmonary system. A rmld allergen and irritant. Acute poisoning in experimental animals produced liver, hdney, and brain damage. Dangerous in a fire; see NITROGEN MONOXIDE and SULFUR DIOXIDE.

職業ばく露

Thiram is a dithiocarbamate. Some thiurams have been used as rubber components: thiram is used as a rubber accelerator and vulcanizer; a seed, nut, fruit, and mushroom disinfectant; a bacteriostat for edible oils and fats; and as an ingredient in suntan and antiseptic sprays and soaps. It is also used as a fungicide, rodent repellent; wood preservative; and may be used in the blending of lubricant oils.

応急処置

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

環境運命予測

Biological. In both soils and water, chemical and biological mediated reactions can transform thiram to compounds containing the mercaptan group (Alexander, 1981). Odeyemi and Alexander (1977) isolated three strains of Rhizobium sp. that degraded thiram. One of these strains, Rhizobium meliloti, metabolized thiram to yield dimethy- lamine (DMA) and carbon disul?de which formed spontaneously from dimethyldithiocar- bamate (DMDT). The conversion of DMDT to DMA and carbon disul?de occurred via enzymatic and nonenzymatic mechanisms (Odeyemi and Alexander, 1977).
When thiram (100 ppm) was inoculated with activated sludge (30 ppm) at 25°C and pH 7.0 for two weeks, 30% degraded. Metabolites included methionine, elemental sulfur, formaldehyde, dimethyldithiocarbamate-α-aminobutyric acid and the corresponding keto aci
To a non-autoclaved alluvial sandy loam (pH 7.3) fortified and inoculated with the bacterium Pseudomonas aeruginosa, 40 and 86% degradation were observed after 4 and 24 days, respectively. In autoclaved soil, thiram degradation was not affected. Degradat
Soil. Decomposes in soils to carbon disul?de and dimethylamine (Sisler and Cox, 1954; Kaars Sijpesteijn et al., 1977). When a spodosol (pH 3.8) pretreated with thiram was incubated for 24 days at 30°C and relative humidity of 60–90%, dimethylamine formed as the major product. Minor degradative products included nitrite ions (nitration reduction) and dimethylnitrosamine (Ayanaba et al., 1973).
Plant. Major plant metabolites are ethylene thiourea, thiram monosul?de, ethylene thiram disul?de and sulfur (Hartley and Kidd, 1987).

輸送方法

UN2771 Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

純化方法

Crystallise thiram (three times) from boiling CHCl3, then recrystallise it from boiling CHCl3 by adding EtOH dropwise to initiate crystallisation, and allow it to cool. Finally it is precipitated from cold CHCl3 by adding EtOH (which retains the monosulfide in solution). [Ferington & Tobolsky J Am Chem Soc 77 4510 1955, Beilstein 4 IV 242.]

不和合性

Dust may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine,fluorine, etc.); contact may cause fires or explosions. Keep away from strong alkaline materials, strong acids, strong bases and nitrating agents.

廃棄物の処理

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Thiram can be dissolved in alcohol or other flammable solvent and burned in an incinerator with an afterburner and scrubber.

テトラメチルチウラムジスルフィド 上流と下流の製品情報

原材料

準備製品


テトラメチルチウラムジスルフィド 生産企業

Global( 284)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
Chemson Industrial (Shanghai) Co., Ltd.
86-21-65208861-ext8007
86-21-65180813 sales1@chemson.com.cn CHINA 117 58
Shenzhen Sendi Biotechnology Co.Ltd.
0755-23311925 18102838259
0755-23311925 Abel@chembj.com CHINA 3203 55
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21924 58
Dalian Richfortune Chemicals Co., Ltd
86-411-84820922, 84821539
86-411-84821380 sales@richfortunechem.com China 360 57
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20680 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
Hefei TNJ Chemical Industry Co.,Ltd.
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86-0551-65418684 info@tnjchem.com China 1750 55
career henan chemical co
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Chemwill Asia Co.,Ltd.
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Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20094 58

137-26-8(テトラメチルチウラムジスルフィド)キーワード:


  • 137-26-8
  • 1,1’-dithiobis(n,n-dimethylthio-formamid
  • 1,1’-dithiobis(n,n-dimethylthioformamide)
  • Aapirol
  • Accel TMT
  • Accelerator T
  • Accelerator Thiuram
  • acceleratort
  • acceleratorthiuram
  • AcceleratorTMTD
  • Aceto TETD
  • acetotetd
  • radothiram
  • rcrawastenumberu244
  • Rezifilm
  • Royal TMTD
  • royaltmtd
  • Sadoplon
  • Sadoplon 75
  • Spotrete
  • spotrete-f
  • SQ 1489
  • sq1489
  • sranan-sf-x
  • Teramethylthiuram disulfide
  • Tersan
  • Tersan 75
  • RHODIASON
  • REZIFILM(R)
  • PURALIN(R)
  • TERSAN(R)
  • テトラメチルチウラムジスルフィド
  • チウラッド
  • 1,1'-ジチオビス(N,N-ジメチルチオホルムアミド)
  • チラート
  • N,N,N',N'-テトラメチルチウラムジスルフィド
  • スポトレート
  • ビス(N,N-ジメチルチオカルバモイル)ペルスルフィド
  • ツアズ
  • ノメルサン
  • ツリサン
  • チウラミル
  • TMTD剤
  • ジチオビス(N,N-ジメチルチオホルムアミド)
  • チオサン
  • フェルナサン
  • テルサン
  • デルサン
  • チラム【殺菌薬】
  • ポマルソル
  • レジフィルム
  • ビス(ジメチルアミノカルボノチオイル)ペルスルフィド
  • チウラム
  • チウラミン
  • チオノック
  • プラリン
  • ビス(ジメチルチオカルバモイル)ペルスルフィド
  • アラサン
  • チウラム標準品
  • チウラム標準液
  • チラム
  • 二硫化ビス(ジメチルチオカルバモイル)
  • 二硫化ビス(ジメチルチオカルバモイル)標準品
  • チラウム
  • テトラメチルチウラムジスルフィド (別名 チラウム又はチラム)
  • ビス(ジメチルチオカルバモイル)ジスルフィド
  • N,N,N’,N’-テトラメチル-2,3-ジチアジチオスクシンアミド
  • テトラメチルチウラムジスルフィド(別名チウラム)
  • チラム チウラム
  • チウラム標準物質
  • チラム STANDARD
  • チラム Standard, 1000 µg/mL in MeOH
  • 光重合開始剤
  • 機能性材料
  • 硫黄化合物 (合成用)
  • 有機合成化学
  • チオカルボニル化合物
  • ジチオカーバメート系殺菌剤
  • 忌避剤
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