メチルシクロペンタジエニルマンガントリカルボニル 化学特性,用途語,生産方法
用途
ガソリンのアンチノック剤、有機マンガン錯体の合成原料
化学的特性
An orange liquid with a pleasant odor. Slightly soluble in water and denser than water. May be toxic by inhalation, ingestion and/or skin absorption. Faintly pleasant, herb-like odor.
使用
Methylcyclopentadienyl manganese tricarbonyl is used for doping of ZnSe nanocrystals
It can also be used as a reactant for:
Aldol addition reactions
Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units
Molecular fragmentation using shaped femtosecond laser pulses
Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE)
一般的な説明
Methylcyclopentadienyl manganese tricarbonyl (hereinafter "MMT") is an antiknock agent for gasoline discovered in the fifties and sold commercially by Ethyl Corporation. It can be made by the reaction of carbon monoxide with bis(methylcyclopentadienyl) manganese referred to as "carbonylation".
空気と水の反応
Slightly soluble in water.
反応プロフィール
METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL decomposes when exposed to light. METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is stable in water.
危険性
Toxic by ingestion, inhalation, and skinabsorption. Central nervous system impairment;lung, liver and kidney damage.
健康ハザード
In concentrated form METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is highly toxic by all routes of exposure. Approximately 5-15 ml, when spilled on the hand and wrist of a worker, produced toxic effects within 3-5 minutes.
火災危険
When heated to decomposition, METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL emits toxic fumes of carbon monoxide. Hazardous polymerization may not occur.
安全性プロファイル
Poison by ingestion,
inhalation, skin contact, intravenous, and
intraperitoneal routes. A slimn irritant. When
heated to decomposition it emits toxic
fumes of CO. See also MANGANESE
COMPOUNDS and CARBONYLS.
職業ばく露
MMT is used as an octane improver
in unleaded gasoline, other distillate fuels, and fuel oils;
as a smoke abater in fuels.
輸送方法
UN3281 Metal carbonyls, liquid n.o.s. Hazard
class 6.1. Technical name required, Potential Inhalation
Hazard (Special Provision 5).
不和合性
Light causes decomposition. May be
air-reactive. A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause
fires or explosions. Keep away from alkaline materials,
strong bases, strong acids, oxoacids, epoxides, halogens.
廃棄物の処理
Generators of waste (equal
to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number N450, must conform
to USEPA regulations for storage, transportation, treatment, and disposal of waste. Dispose of waste material
as hazardous waste using a licensed disposal contractor
to an approved landfill. Dispose of contents and container to an approved waste disposal plant. Containers
must be disposed of properly by following package label
directions or by contacting your local or federal environmental control agency, or by contacting your regional
EPA office. All federal, state, and local environmental
regulations must be observed. Do not discharge into
drains or sewers.
メチルシクロペンタジエニルマンガントリカルボニル 上流と下流の製品情報
原材料
準備製品