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1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド

1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド 化学構造式
56038-13-2
CAS番号.
56038-13-2
化学名:
1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド
别名:
1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド;スクラロース;4,1',6'-トリクロロ-4,1',6'-トリデオキシガラクトスクロース;1',4,6'-トリクロロガラクトスクロース;1-(1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル)-4-クロロ-4-デオキシ-α-D-ガラクトピラノシド;スクラロース標準品
英語化学名:
Sucralose
英語别名:
TGS;E955;SUCRALOSE;SPLENDA [R];Sucralose99%;SUCRALOSE(P);ctopyranoside;loro-4-deoxy-;Sucralose 0.1;Sucralose, NF
CBNumber:
CB9363034
化学式:
C12H19Cl3O8
分子量:
397.63
MOL File:
56038-13-2.mol

1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド 物理性質

融点 :
115-1018°C
沸点 :
104-107 C
比旋光度 :
D +68.2° (c = 1.1 in ethanol)
比重(密度) :
1.375 g/cm
貯蔵温度 :
2-8°C
溶解性:
Do you have solubility information on this product that you would like to share
外見 :
Powder
酸解離定数(Pka):
12.52±0.70(Predicted)
色:
White
PH:
6-8 (100g/l, H2O, 20°C)
光学活性 (optical activity):
[α]/D 86.0±2.0°, c = 1 in H2O
水溶解度 :
Soluble in Water.
Merck :
14,8880
BRN :
3654410
CAS データベース:
56038-13-2(CAS DataBase Reference)
EPAの化学物質情報:
.alpha.-D-Galactopyranoside, 1,6-dichloro-1,6-dideoxy-.beta.-D-fructofuranosyl 4-chloro-4-deoxy- (56038-13-2)

安全性情報

主な危険性  Xi
Rフレーズ  36/37/38
Sフレーズ  26-37/39-24/25
WGK Germany  3
RTECS 番号 LW5440140
HSコード  2932 14 00
有毒物質データの 56038-13-2(Hazardous Substances Data)
毒性 LD50 orally in Rabbit: > 10000 mg/kg

1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド 価格 もっと(22)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01COBQA-6411 スクラロース
Sucralose
56038-13-2 5g ¥3600 2021-03-23 購入
富士フイルム和光純薬株式会社(wako) W01CHDASB-00019383 スクラロース
Sucralose
56038-13-2 100mg ¥34500 2021-03-23 購入
東京化成工業 S0839 スクラロース >98.0%(HPLC)
Sucralose >98.0%(HPLC)
56038-13-2 25g ¥6900 2021-03-23 購入
東京化成工業 S0839 スクラロース >98.0%(HPLC)
Sucralose >98.0%(HPLC)
56038-13-2 5g ¥2100 2021-03-23 購入
関東化学株式会社(KANTO) 49861-01 スクラロース標準品
Sucralose standard
56038-13-2 100mg ¥21000 2021-03-23 購入

1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド 化学特性,用途語,生産方法

外観

白色~うすい灰色, 結晶~粉末

定義

本品は、次の化学式で表される糖の塩化物である。

溶解性

水、エタノール及びアセトンに溶ける。

用途

HPLC用標準品

化粧品の成分用途

香味剤

化学的特性

Off-White Amorphous Solid

化学的特性

Sucralose is a white to off-white colored, free-flowing, crystalline powder.

来歴

Sucralose, 1,6-dichloro-1,6-dideoxy-β-D-fructofuranosyl- 4-chloro-4-deoxy-α-D-galactopyranoside, is a trichloro-galactosucrose sweetener developed by the British sugar company Tate & Lyle during the 1970s (U.S. Pat. 4,343,934 (Aug. 10, 1982), M. R. Jenner and D. Waite (to Talres Development), (U.S. Pat. 4,362,869 (Dec. 7, 1982), M. R. Jenner and co-workers (to Talres Development), and (U.S. Pat. 4,435,440 (Mar. 6, 1984), L. Hough, S. P. Phadnis, and R. A. Khan (to Tate & Lyle). It was licensed to McNeil-PPC, Inc., a Johnson & Johnson subsidiary, in the United States until a new agreement took place in February, 2004. McNeil Nutritionals retained ownership of SPLENDA Brand and the right for its worldwide retail and food service business. Tate & Lyle became the sole manufacturer of SPLENDA Brand sucralose and owned the right for its worldwide ingredient sales.

使用

Sucralose (1,6-dichloro-1,6-dideoxy-p-fructofuranosyl-4-chloro-oc- D-galactopyra- noside) is a nonnutritive sweetener based on sucrose. It is selectively chlorinated and the glycoside link between the two rings is resistant to hydrolysis by acid or enzymes, so it is not metabolized. It has 400 to 800 times the sweetness of sucrose, is very soluble in water, and is stable in heat. It can be used in food products that are baked or fried.
Sucralose is produced by the selective chlorination of the sucrose molecule using a patented process by Tate and LyIe that replaces the three hydroxyl groups (OH) with three chlorine (Cl) atoms.
This modified sugar is minimally absorbed by the body and passes out unchanged. It was approved for use in foods and beverages in 1999 in the United States.

使用

A low-calorie artificial sweetener

使用

antiprotozoal

使用

High intensity sweetener manufactured by replacing three hydroxyl groups on the sucrose molecule with three chlorine atoms. The results are a sweetener of 0 cal that is not digested. It is 600 times as sweet as sugar with a similar flavor profile. It is heat stable, readily soluble, and maintains its stability at elevated temperatures. It has been approved for use in specific categories that include baked products, beverages, confectioneries, and certain desserts and toppings.

定義

ChEBI: A disaccharide derivative consisting of 4-chloro-4-deoxy-alpha-D-galactopyranose and 1,6-dichloro-1,6-dideoxy-beta-D-fructofuranose units linked by a glycosidic bond.

調製方法

Sucralose may be prepared by a variety of methods that involve the selective substitution of three sucrose hydroxyl groups by chlorine. Sucralose can also be synthesized by the reaction of sucrose (or an acetate) with thionyl chloride.

応用例(製薬)

Sucralose is used as a sweetening agent in beverages, foods, and pharmaceutical applications. It has a sweetening power approximately 300–1000 times that of sucrose and has no aftertaste. It has no nutritional value, is noncariogenic, does not promote dental caries, and produces no glycemic response.

安全性

Sucralose is generally regarded as a nontoxic and nonirritant material and is approved, in a number of countries, for use in food products. Following oral consumption, sucralose is mainly unabsorbed and is excreted in the feces.
The WHO has set an acceptable daily intake for sucralose of up to 15 mg/kg body-weight.
LD50 (mouse, oral): > 16 g/kg
LD50 (rat, oral): > 10 g/kg

貯蔵

Sucralose is a relatively stable material. In aqueous solution, at highly acidic conditions (pH < 3), and at high temperatures (≤35℃), it is hydrolyzed to a limited extent, producing 4-chloro-4- deoxygalactose and 1,6-dichloro-1,6-dideoxyfructose. In food products, sucralose remains stable throughout extended storage periods, even at low pH. However, it is most stable at pH 5–6.
Sucralose should be stored in a well-closed container in a cool, dry place, at a temperature not exceeding 21℃. Sucralose, when heated at elevated temperatures, may break down with the release of carbon dioxide, carbon monoxide, and minor amounts of hydrogen chloride.

規制状況(Regulatory Status)

The FDA, in April 1998, approved sucralose for use as a tabletop sweetener and as an additive in a variety of food products. In the UK, sucralose was fully authorized for use in food products in 2005. It is also accepted for use in many other countries worldwide. Included in the Canadian List of Acceptable Nonmedicinal Ingredients.

1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド 上流と下流の製品情報

原材料

準備製品


1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド 生産企業

Global( 501)Suppliers
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56038-13-2(1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド)キーワード:


  • 56038-13-2
  • 1,6-dichloro-1,6-dideoxy-beta-d-fructofuranosyl4-chloro-4-deoxy-alpha-d-gala
  • 4,1’,6’-trichloro-4,1’,6’-trideoxy-galacto-sucrose
  • alpha-d-galactopyranoside,1,6-dichloro-1,6-dideoxy-beta-d-fructofuranosyl4-ch
  • ctopyranoside
  • Sucralose in stock GMP Factory
  • 1,6-dichloro-1
  • 4,1',6'-trichlorogalactosucrose
  • loro-4-deoxy-
  • 1,6-DICHLORO-1,6-DIDEOXY-BETA-D-FRUCTOFURANOSYL-4-CHLORO-4-DEOXY-ALPHA-D-GALACOTOPYRANOSIDE
  • 1,6-Dichloro-1,6-dideoxy-beta-D-fructofuranosyl 4-chloro-4-deoxy-alpha-D-galactose
  • SUCRALOSE
  • TRICHLOROSUCROSE
  • 1,6-Dichloro-1,6-dideoxy-beta-D-fructofuranosyl-4-chloro-4-deoxy-alpha-D-galactopyranoside
  • SUCRALOSE FCC (TRICHLOROGALACTOSUCROSE)
  • SucraloseC12H19Cl3O8
  • Sucralose98%Min.
  • Sucralose99%
  • Steviosides90%
  • Sucralose&Int.
  • SPLENDA [R]
  • .alpha.-D-Galactopyranoside, 1,6-dichloro-1,6-dideoxy-.beta.-D-fructofuranosyl 4-chloro-4-deoxy-
  • trichlorogalactosucrose
  • 4,16trichloro-4,16trideoxy pentagalactosucrose
  • SUCRALOSE /4,1'',6'',-TRICHLORO-4,1'',6''TRIDEOXY-PENTAGALACTOSUCROSE
  • SUCRALOSE(TRICHLOROSUCROSE)
  • Sucralose 98.0-102.0%
  • 4,1,6-TRICHLOROGALACTOSUCROSE (SUCRALOSE)
  • 1,6-Dichloro-1,6-dideoxy-β-D-fructofuranosyl-4-chloro-4-deoxy-α-D-galacotopyranoside
  • 1,6-Dichloro-1,6-Dideoxy-B-D-Fructofuranosyl-4-Chloro-4-Deoxy-A-D-Galacotopyranoside
  • (2R,3R,4R,5R,6R)-2-{[(2S,3R,4R,5R)-2,5-Bis(chloromethyl)-3,4-dihydroxytetrahydro furan-2-yl]oxy}-
  • 1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル4-クロロ-4-デオキシ-α-D-ガラクトピラノシド
  • スクラロース
  • 4,1',6'-トリクロロ-4,1',6'-トリデオキシガラクトスクロース
  • 1',4,6'-トリクロロガラクトスクロース
  • 1-(1,6-ジクロロ-1,6-ジデオキシ-β-D-フルクトフラノシル)-4-クロロ-4-デオキシ-α-D-ガラクトピラノシド
  • スクラロース標準品
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