ジチオりん酸O,O-ジメチルS-(α-エトキシカルボニルベンジル)

ジチオりん酸O,O-ジメチルS-(α-エトキシカルボニルベンジル) MSDS

Phenthoate

ジチオりん酸O,O-ジメチルS-(α-エトキシカルボニルベンジル) 化学特性,用途語,生産方法

外観

無色～うすい黄色, 澄明の液体

溶解性

エタノール及びアセトンに溶けやすく、水にほとんど溶けない。

農薬用途

殺虫剤、ダニ駆除剤

説明

Phenthoate is a colorless crystalline substance. Solubility in water is 10 mg/L (25 ?C). It is readily soluble in most organic solvents. Log Kow = 3.69. It is relatively stable in neutral and acidic aqueous media but decomposed under alkaline conditions.

使用

Phenthoate is an organothiophosphate insecticide used against lepidoptera and houseflies.

定義

ChEBI: An organic thiophosphate that is ethyl mandelate in which the hydroxy group has been replaced by a (dimethoxyphosphorothioyl)sulfanediyl group.

代謝経路

Studies which have measured the degradation of phenthoate in buffered aqueous solution have shown that it can be hydrolysed at the carboethoxy group, by cleavage of the P-S and C-S bonds and by demethylation in addition to oxidative desulfuration to the oxon. Reports on the metabolism of phenthoate in plants, insects and mammals have shown that the metabolic products can be largely explained by cleavage of these reactive groups. P-S and C-S bond cleavage is demonstrated by the formation of both O,O-dimethyl phosphorothioate and O,O-dimethyl phosphorodithioate. Metabolism in plants, insects and mammals is similar with many of the possible metabolites being identified in most species. Phenthoate carboxylic acid is a major metabolite except in plants where hydrolysis of the phosphorodithioate moiety predominates. In mammals, little or none of the activated metabolite, phenthoate oxon, can be detected, suggesting that the predominant metabolic route is degradative, wkuch may in part explain the favourable mammalian toxicity of the compound.

代謝

Phenthoate is degraded by hydrolysis of the carboethoxy moiety. Demethylation and the cleavage of P?S?C linkages are also important degradation routes. Oxidative desulfuration to the oxon followed by hydrolysis occurs in animals and plants.The major metabolites excreted in the urine and feces are demethyl phenthoate, demethyl phenthoate acid, demethyl phenthoate oxon, and O,O-dimethyl hydrogen phosphorodithioate and phosphorothioate. It is rapidly degraded in soils; DT₅₀ was less than 1 d in both upland and submerged soil.

ジチオりん酸O,O-ジメチルS-(α-エトキシカルボニルベンジル) 上流と下流の製品情報

原材料

準備製品

2597-03-7(ジチオりん酸O,O-ジメチルS-(α-エトキシカルボニルベンジル))キーワード:

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• 2597-03-7
• pap (jmaf)
• phenthoate (bsi,iso)
• O,O-Dimethyl S-alpha-Ethoxycarbonylbenzyl phosphorodithioate
• O,O-Dimethyl-S-(phenylacetic acid ethyl ester) phosphorodithioate
• OMS 1075
• Papthion
• Phendal
• Phentoate
• Rogodial
• S 2940
• CIDIAL
• CIDIAL(R)
• CHEMPHEN
• KAP(R)
• AIMSAN
• Ethyl 2-dimethoxyphosphinothioylsulfanyl-2-phenylacetate
• Ethyl-a-[dimethoxyphosphinothioyl-thio]benzacetate
• (Dimethyl S-(phenylethoxycarbonylmethyl)phosphorothiolothionate)
• Acetic acid, (O,O-dimethyldithiophosphorylphenyl)-, ethyl ester
• Acetic acid, mercaptophenyl-, ethyl ester, S-ester with O,O-dimethyl phosphorodithioate
• BAY 33051
• Bayer 18,510
• BAYER 18510
• Benzeneacetic acid, alpha-[(dimethoxyphosphinothioyl)thio]-, ethyl ester
• Cidemul
• Cydeal
• Dimefenthoat
• Dimephenthioate
• Dimephenthoate
• Dimethenthoate
• フェントエート
• フェンダル
• パプチオン
• シジアル
• シデムル
• ツィジアール
• 2-[(ジメトキシホスフィノチオイル)チオ]-2-フェニル酢酸エチル
• フェントアート
• ジメフェントアート
• α-[(ジメトキシホスフィノチオイル)チオ]ベンゼン酢酸エチル
• PAP剤
• モンテカチーニL-561
• ジチオりん酸O,O-ジメチルS-(α-エトキシカルボニルベンジル)
• エルサン
• タグソン
• Ｏ，Ｏ－ジメチルジチオホスホリルフェニル酢酸エチル
• フェントエート標準品
• O,O-ジメチルジチオホスホリルフェニルサクサンエチル
• ジメチルジチオホスホリルフェニルサクサンエチル
• Ｏ，Ｏジメチルジチオホスホリルフェニル酢酸エチル
• フェントエート(PAP)
• CS_N-13006-100MG_フェントエートPAP
• フェントエートPAP
• PAP標準物質
• フェントエート STANDARD
• PAP標準品
• フェントエート Standard, 100 µg/mL in MeOH
• エチル 2-{[ジメトキシ(スルファニリデン)-λ5-ホスファニル]スルファニル}-2-フェニルアセタート
• ドハヌサン50
• ジメチルジチオホスホリルフェニル酢酸エチル
• 有機リン系殺虫剤
• 農薬類，殺虫剤および除草剤など
• 生活関係標準物質
• 食料品
• 有機標準物質