에토프로포스
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에토프로포스 속성
- 녹는점
- -13 °C
- 끓는 점
- 86-91°C
- 밀도
- d420 1.094
- 증기압
- 4.65 x 10-2 Pa (26 °C)
- 인화점
- 100 °C
- 저장 조건
- APPROX 4°C
- 용해도
- DMF: 5mg/mL; DMSO: 5mg/mL; Ethanol: 1.6mg/mL
- 수용성
- 700mg l-1(20°C)
- Merck
- 13,3782
- BRN
- 8139788
- 안정성
- 흡습성
- CAS 데이터베이스
- 13194-48-4(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | T+;N,N,T+ | ||
---|---|---|---|
위험 카페고리 넘버 | 25-26/27-43-50/53 | ||
안전지침서 | 27-28-36/37/39-45-60-61-27/28 | ||
유엔번호(UN No.) | UN 2810 | ||
WGK 독일 | 3 | ||
RTECS 번호 | TE4025000 | ||
위험 등급 | 6.1(a) | ||
포장분류 | II | ||
HS 번호 | 29309090 | ||
유해 물질 데이터 | 13194-48-4(Hazardous Substances Data) | ||
독성 | LC50 (96-hour) for rainbow trout 13.8 mg/L, bluegill sunfish 2.1 mg/L and goldfish 13.6 mg/L (Hartley and Kidd, 1987); acute oral LD50 for rats 262 mg/kg (Hartley and Kidd, 1987), 34 mg/kg (RTECS, 1985). | ||
기존화학 물질 | KE-28678 | ||
유해화학물질 필터링 | 97-1-189 | ||
함량 및 규제정보 | 물질구분: 유독물질; 혼합물(제품)함량정보: 에토프로포스 및 이를 1% 이상 함유한 혼합물 |
에토프로포스 C화학적 특성, 용도, 생산
개요
Introduced in the 1960s, ethoprop is a nonsystemic insecticide/nematicide. The mobility of ethoprop in soil and its half-life are strongly dependent on soil organic matter (21). It is not known to be carcinogenic and is available as granules or emulsifiable concentrates.화학적 성질
Ethoprophos is a pale yellow liquid.용도
Ethoprophos is an organophosphate non-systemic nematicide and soil insecticide. Ethoprophos is an acetylcholinesterase (AChE) inhibitor.일반 설명
Ethorop is one of a family of organophosphorus pesticides. Mocap is combustible though Mocap may require some effort to ignite. Mocap is very toxic by skin absorption and inhalation. Mocap may or may not be water soluble.공기와 물의 반응
Hydrolyzed in alkali.반응 프로필
Organothiophosphates, such as Mocap, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.건강위험
Mocap is extremely toxic; the probable oral lethal dose for humans is 5-50 mg/kg, or between 7 drops and 1 teaspoonful for a 150 lb. person. It is a cholinesterase inhibitor which affects the nervous system.화재위험
(Non-Specific -- Organophosphorus Pesticide, Liquid, n.o.s.) Container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases. Stable in water. Hydrolyzed in alkali.농업용
Nematicide, Insecticide: Ethoprop is used as a pre-plant soil application to control wireworms and nematodes in potatoes, sugar cane, sweet potatoes, and tobacco, with lesser usage on corn (field and sweet), beans (lima and snap), cucumbers, and cabbage. In addition, it is used to treat pineapples, bananas, and plantains, as well as fieldgrown ornamentals and non-bearing citrus trees, and commercial turf. Roughly 60% of ethoprop is applied to potatoes.상품명
AI3-27318®; CASWELL No. 434C®; JOLT®[C]; MENAP®; MOBIL V-C 9-104®; MOCAP®[C]; MOCAP 10G®[C]; PHOSETHOPROP®; ROVOKIL®; V-C 9-104®[C]; V-C CHEMICAL V-C 9-104®[C]; VIRGINIA-CAROLINA VC 9-104®Safety Profile
Poison by ingestion and skin contact. A cholinesterase inhibitor type of insecticide. When heated to decomposition it emits very toxic fumes of POx and SOx. See also PARATHION.잠재적 노출
A potential danger to those involved in the manufacture, formulation and application of this nematocide and soil insecticideCarcinogenicity
In a combined chronic feeding/ carcinogenicity study, when rats were fed diets with 0, 1, 10, or 100 ppm ethoprop in the diet for 24 months (equivalent to 0, 0.041, 0.40, or 4.19 mg/kg/day (males); 0, 0.052, 0.51, or 5.12 mg/kg/day (females)), adrenal gland malignant pheochromocytomas were increased in males and thyroid C-cell carcinomas were increased slightly in males . When ethoprop was administered in the diet to mice for 104 weeks at 0, 0.2, 2.0, or 30 ppm (males: 0, 0.026, 0.254, or 3.96 mg/ kg/day; females: 0, 0.032, 0.318, or 4.9 mg/kg/day), survival was unaffected at any dose level and no statistically significant dose-related incidence of tumors were seen in males or females.환경귀착
Soil. The reported half-life in humus-containing soil (pH 4.5) and a sandy loam (pH 7.2–7.3) are 87 and 14–28 days, respectively (Hartley and Kidd, 1987). The rate of degradation increased in soils that had been treated annually four times (Smelt et al., 1987).Chemical/Physical. Emits toxic fumes of phosphorus and sulfur oxides when heated to decomposition (Sax and Lewis, 1987).
신진 대사 경로
Ethoprophos is a soil-acting insecticide and nematicide which is generally incorporated into the soil in the form of a granular formulation. Volatilisation is a factor involved in the loss and movement of the compound in the environment. The major route of degradation of ethoprophos in both plants and mammals is via hydrolysis to give O-ethyl S-propyl phosphorothioate through loss of propanethiol. Propanethiol has been shown to react as a nucleophile to yield ethyl propyl sulfide through attack on the phosphorus atom and dipropyl disulfide through attack on the sulfur atom of ethoprophos. The sulfide metabolites are further metabolised via oxidation to sulfoxides and sulfones. In mammals, an additional important route of detoxification is through de-ethylation via glutathione- S-alkyl transferase, a route common to many organophosphorus insecticides.운송 방법
UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required비 호환성
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the presence of strong reducing agents such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials폐기물 처리
In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office에토프로포스 준비 용품 및 원자재
원자재
potassium O-ethyl-S-propyldithiophosphate
POTASSIUM HYDROGENSULFIDE,
에틸알코올
Ethyl dichlorophosphate
포스포러스옥시클로라이드
삼황화사인
프로필메르캅탄
weak
O,O-디에틸 수소 포스포로디씨오에이트
1-브로모프로판
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts
SULPHOSUCCINIC ACID ESTER
준비 용품
에토프로포스 공급 업체
글로벌( 126)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 |
sales@chemdad.com | China | 39916 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49390 | 58 |
ANHUI WITOP BIOTECH CO., LTD | +8615255079626 |
eric@witopchemical.com | China | 23556 | 58 |
Hebei Duling International Trade Co. LTD | +8618032673083 |
sales05@hbduling.cn | China | 15745 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 |
cherry@crovellbio.com | China | 18456 | 58 |