2-아미노-2-메틸-1-프로판올

2-아미노-2-메틸-1-프로판올
2-아미노-2-메틸-1-프로판올 구조식 이미지
카스 번호:
124-68-5
한글명:
2-아미노-2-메틸-1-프로판올
동의어(한글):
2-아미노-2-메틸-1-프로판올;2-아미노-2-메틸프로판올;아미노메틸프로판올;2.2-다이메틸에탄올아민;2-아미노 아이소뷰틸 알코올;2-아미노-2-메틸프로파놀;2-아미노-2-메틸프로판-1-올;2-아미노다이메틸에탄올;2-아미노아이소부탄올;베타-아미노아이소부탄올;아이소부탄올-2-아민;아이소부탄올아민
상품명:
2-Amino-2-methyl-1-propanol
동의어(영문):
2-AMINO-2-METHYLPROPAN-1-OL;AMP-95;2-Amino-2-methylpropanol;1,1-Dimethyl-2-hydroxyethylamine;Aminomethylpropanol;2-methyl-2-amino-1-propanol;Karl Fischer;2,2-Diethyl-ethanolamine;Isobutanolamine;2-Aminoisobutanol
CBNumber:
CB0320043
분자식:
C4H11NO
포뮬러 무게:
89.14
MOL 파일:
124-68-5.mol
MSDS 파일:
SDS

2-아미노-2-메틸-1-프로판올 속성

녹는점
24-28 °C (lit.)
끓는 점
165 °C (lit.)
밀도
0.934 g/mL at 25 °C (lit.)
증기 밀도
3 (vs air)
증기압
<1 mm Hg ( 25 °C)
굴절률
n20/D 1.4455(lit.)
인화점
153 °F
저장 조건
Store below +30°C.
용해도
H2O: 0.1 M at 20 °C, 투명, 무색
물리적 상태
저융점 고체
Specific Gravity
0.934
색상
무색의
pH 범위
9.0 - 10.5
수소이온지수(pH)
11.0-12.0 (25℃, 0.1M in H2O)
산도 계수 (pKa)
9.7(at 25℃)
냄새
100.00?%. 약한 암모니아
수용성
혼용 가능
최대 파장(λmax)
λ: 260 nm Amax: 0.01
λ: 280 nm Amax: 0.01
Merck
14,449
BRN
505979
안정성
안정적인. 타기 쉬운. 강한 산화제와 호환되지 않습니다. 가열되면 폭발 위험이 있을 수 있습니다.
InChIKey
CBTVGIZVANVGBH-UHFFFAOYSA-N
LogP
-0.63 at 20℃
CAS 데이터베이스
124-68-5(CAS DataBase Reference)
NIST
1-Propanol, 2-amino-2-methyl-(124-68-5)
EPA
2-Amino-2-methyl-1-propanol (124-68-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,F
위험 카페고리 넘버 36/38-52/53
안전지침서 61-26
유엔번호(UN No.) 2735
WGK 독일 1
RTECS 번호 UA5950000
자연 발화 온도 438 °C
위험 참고 사항 Harmful/Flammable
TSCA Yes
포장분류 III
HS 번호 29221990
유해 물질 데이터 124-68-5(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 2900 mg/kg LD50 dermal Rabbit > 2000 mg/kg
기존화학 물질 KE-01473
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P332+P313 피부 자극이 생기면 의학적인 조치· 조언을 구하시오.
NFPA 704
2
2 0

2-아미노-2-메틸-1-프로판올 C화학적 특성, 용도, 생산

안전성

위험물안전관리법 :제4류 .인화성액체 물질상태: 액체.

포장, 보관 및 운송

열, 스파크, 화염을 피할 것. 서늘하고 건조한 곳. 환기가 잘 되는 곳에 인화점 이하로 보관할 것. 용기는 밀봉하여 누출을 방지할 것. 혼합 금지 물질과 분리할 것.

공업 용도

Because 2-Amino-2-methyl-1-propanol has the advantages of excellent absorption and desorption capacity, high loading capacity, and low replenishment cost. AMP is one of the promising amines considered for usage in the industrial scale post-combustion CO2 capture technology[1]. At present, there are a large number of studies on the performance of 2-Amino-2-methyl-1-propanol for CO2 adsorption. Using 2-amino-2-methyl-1-propanol (AMP) as the core adsorbent and silica as the shell, the AMP microcapsules prepared are expected to replace conventional adsorbents to achieve carbon dioxide capture in cold environments[2].

용도

2-Amino-2-methyl-1-propanol is also used in ATR-FTIR spectroscopic investigation of the carbon monoxide absorption characteristics of a series of heterocyclic diamines.

일반 설명

A clear light colored liquid. Insoluble in water and about the same density as water. Flash point 172°F. Used to make other chemicals.

공기와 물의 반응

Insoluble in water.

반응 프로필

2-Amino-2-methyl-1-propanol is an aminoalcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

위험도

Toxic by ingestion.

건강위험

Causes severe irritation. Inhalation may be fatal as a result of spasm, inflammation, and edema of laryns and bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.

화재위험

Special Hazards of Combustion Products: Emits toxic fumes during fire conditions.

Safety Profile

On March 21, 2014, the Environmental Protection Agency (EPA) issued a direct final rule with a parallel proposal identifying 2-Amino-2-methyl-1-propanol (also known as AMP) as a chemical compound that it will no longer be regulated as a volatile organic compound (VOC) under the Clean Air Act. This will remove AMP from regulatory requirements related to controlling VOC emissions in order to meet the national ambient air quality standards (NAAQS) for ozone. EPA will add AMP to the list of negligibly reactive compounds in EPA’s regulatory definition of VOC.
AMP is used for pigment dispersion in water-based coatings such as house paints. Excluding this compound from the regulatory definition of VOC, facilitates access to AMP for manufacturers of water-based coatings in order to meet VOCs limits without impairing the performance of their products or using other more toxic chemicals.

Synthesis

The synthesis of 2-Amino-2-methyl-1-propanol is as follows:

In a 1L three-neck flask with mechanical stirring, first add 200ml of water, add a few drops of dilute sulfuric acid to make it slightly acidic (pH=3.5-4), then heat to 40-50, and start adding 99.0 at the same time. 2,2-Dimethylaziridine and 400ml dilute sulfuric acid aqueous solution, keep the temperature and slightly acidic condition, drop 2,2-dimethylaziridine, then continue to react at this temperature 1h, then under reduced pressure distillation to remove 80% of the water, add 500ml ethanol to the obtained system, neutralize with 30% sodium hydroxide to pH=9.5-10, filter and remove the salt, the obtained filtrate is distilled out of ethanol under normal pressure , And then distilled under reduced pressure to obtain crude 2-amino-2-methyl-1-propanol. This crude product is then rectified to obtain 112.9g 2-amino-2-methyl-1-propanol refined product with a yield of about 91.0%, chromatographic purity is about 99.4%.
synthesis of 2-Amino-2-methyl-1-propanol

Purification Methods

Purify it by distilling and fractional freezing. The hydrochloride has m 204o-206o. [Beilstein 4 III 783, 4 IV 1740.]

2-아미노-2-메틸-1-프로판올 준비 용품 및 원자재

원자재

준비 용품


2-아미노-2-메틸-1-프로판올 공급 업체

글로벌( 600)공급 업체
공급자 전화 이메일 국가 제품 수 이점
Beijing Risun Science and Technology Limited
+8619801193650
xykj@risun.com China 13 58
Coresyn Pharmatech Co., Ltd.
+86-571-86626709 +86-18157142896
cbc@coresyn.com China 9991 58
Henan Alfa Chemical Co., Ltd
+8618339805032
alfa4@alfachem.cn China 12755 58
Suzhou Genemill Biotechnology Co.,Ltd
+86-0512-65917170; +8615862502491
aimeegao@genemill.com China 39 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651
admin@zlchemi.com China 401 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578
sales@hbmojin.com China 12456 58
Hangzhou ICH Biofarm Co., Ltd
+undefined8613073685410
sales@ichemie.com China 985 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806
sales@capotchem.com China 29797 60
Shanghai Bojing Chemical Co.,Ltd.
+86-86-02137122233 +8613795318958
bj1@bj-chem.com China 298 55
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21691 55

2-아미노-2-메틸-1-프로판올 관련 검색:

Copyright 2019 © ChemicalBook. All rights reserved