P-아미노아조벤젠
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P-아미노아조벤젠 속성
- 녹는점
- 123-126 °C(lit.)
- 끓는 점
- >360 °C(lit.)
- 밀도
- 1.2828 (rough estimate)
- 굴절률
- 1.6500 (estimate)
- 용해도
- 클로로포름(약간 용해됨), 메탄올(약간 용해됨)
- 산도 계수 (pKa)
- 2.82(at 25℃)
- 색상 색인 번호
- 11000
- 색상
- 결정은 에탄올로부터 분리되었습니다. 파란색 껍질이 있는 노란색 결정 또는 주황색 바늘,
- 수용성
- 29.59mg/L(25℃)
- Merck
- 14,419
- BRN
- 1913042
- 안정성
- 안정적인. 강한 산화제와 호환되지 않습니다.
- CAS 데이터베이스
- 60-09-3(CAS DataBase Reference)
- IARC
- 2B (Vol. 8, Sup 7) 1987
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | T,N,Xi | ||
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위험 카페고리 넘버 | 45-50/53-36/37/38-20/21/22-46 | ||
안전지침서 | 53-45-60-61-36/37/39-26-22 | ||
유엔번호(UN No.) | UN 3077 9/PG 3 | ||
WGK 독일 | 3 | ||
RTECS 번호 | BY8225000 | ||
위험 등급 | IRRITANT | ||
포장분류 | III | ||
HS 번호 | 29270000 | ||
유해 물질 데이터 | 60-09-3(Hazardous Substances Data) | ||
독성 | LD50 intraperitoneal in mouse: 200mg/kg | ||
기존화학 물질 | KE-05-0130 | ||
유해화학물질 필터링 | 97-1-447 | ||
중점관리물질 필터링 | 별표2-9 | ||
암, 돌연변이성물질 필터링 | 38 | ||
함량 및 규제정보 | 물질구분: 유독물질; 혼합물(제품)함량정보: p-아미노아조벤젠 및 이를 0.1% 이상 함유한 혼합물 |
그림문자(GHS): | ||||||||||||||||||||||||||||||||||||
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신호 어: | Danger | |||||||||||||||||||||||||||||||||||
유해·위험 문구: |
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예방조치문구: |
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P-아미노아조벤젠 C화학적 특성, 용도, 생산
개요
This azoic coloring can be reduced in paraphenylenediamine (PPD). It ean be found in some semipermanent hair dyes, and patch tests are frequently positive (about 30%) in hairdressers with hand dermatitis. Because of cross-sensitivity, the detection of sensitization to p-aminoazobenzene may be assumed by a PPD test.화학적 성질
4-Aminoazobenzene forms yellow to tan crystals or orange needles.용도
In form of its salts in dyeing; intermediate in manufacture of Acid Yellow, diazo dyes and indulines.정의
ChEBI: Azobenzene substituted at one of the 4-positions by an amino group.제조 방법
commonly known as Aniline Yellow. (a) aniline?hydrochloride solution added to a aniline?diazonium salt, and slowly, until aniline?diazonium salt salt disappear so far. Then in contain a small amount of aniline?hydrochloride aniline?solution will product (Diazoaminobenzene) 30 ~ 40 ℃ heating 2 ~ 3 hours,??acidified to form 4-(Phenyldiazenyl)benzenamine??hydrochloride and crystalline precipitates. In order to obtain 4-(Phenyldiazenyl)benzenamine?times the company, and then 4-(Phenyldiazenyl)benzenamine hydrochloride dissolved in water and mercerized. (B) aniline?diazotization and coupling anilino-methanesulfonic acid, sodium hydroxide solution and then with boiled together, hydrolyzed mesylate.일반 설명
Odorless brownish-yellow needles with bluish coating, or an orange powder.공기와 물의 반응
Dust may form an explosive mixture in air. Insoluble in water.반응 프로필
4-AMINOAZOBENZENE can detonate, particularly if sensitized by the presence of metal salts or strong acids. May form toxic gases with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. May form flammable gases with alkali metals. May react explosively with strong oxidizing agents, metal salts, peroxides, and sulfides. Emits toxic fumes of oxides of nitrogen when heated to decomposition (over 350°C) [Sax, 2nd ed., 1965, p. 417].위험도
Possible carcinogen.화재위험
Flash point data for 4-AMINOAZOBENZENE are not available; however, 4-AMINOAZOBENZENE is probably combustible.색상 색인 번호
This azoic coloring can be reduced in para-phenylenediamine (PPD). It can be found in some semi-permanent hair dyes and patch tests are frequently positive (about 30%) in hairdressers with hand dermatitis. Because of hydrolysis of the azo bond, the detection of sensitization to p-aminoazobenzene may be assumed by a PPD test.Safety Profile
Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Poison by intraperitoneal route. An experimental teratogen. Mutation data reported. Used as a dye for lacquer, varnish, wax products, oil stains, and styrene resins. When heated to decomposition it emits toxic fumes of NOx. See also AMINES잠재적 노출
An azo compound used in form of salts in dyeing; used as intermediate in manufacture of acid yellow and diazo dyes; in insecticides, waxes, lacquers, varnishes, stains, styrene resins운송 방법
UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name RequiredPurification Methods
Crystallise this dye from EtOH, CCl4, pet ether/*C6H6, or a MeOH/H2O mixture. [Beilstein 16 IV 445.]비 호환성
Dust may form explosive mixture with air. Azo compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. This chemicalis sensitive to prolonged exposure to heat. This chemical is incompatible with strong oxidizing agentsP-아미노아조벤젠 준비 용품 및 원자재
원자재
준비 용품
DIAMINE GREEN B
Sumilight Supra Orangl 2GL
disperse Yellow RGFL
photochromic azobenzene polymer
이나트륨 7-하이드록시-8-((4-(페닐아조)페닐)아조)-1,3-나프탈렌- 디설폰산
C.I. 부식성 오렌지 6
5-CHLORO-2-NITRODIPHENYLAMINE
수단 레드 7B
수단 레드 7B
P-아미노아조벤젠
4-[4-(PHENYLAZO)PHENYLAZO]-O-CRESOL
4-Amino-5-hydroxy-3-[(4-nitrophenyl)azo]-6-[[4-(phenylazo)phenyl]azo]naphthalene-2,7-disulfonic acid disodium salt
솔벤트레드110
SOLVENT RED 30
DISPERSE YELLOW 56
Benzenamine, 4-(phenylazo)-, reaction products with aniline and aniline hydrochloride, (Z)-9-octadecenoate
솔벤트오렌지14
이나트륨 7-하이드록시-8-((4-(페닐아조)페닐)아조)-1,3-나프탈렌- 디설폰산
수단 III 용액
Disperse Red 151
P-아미노아조벤젠 공급 업체
글로벌( 241)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
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Hebei Mojin Biotechnology Co.,Ltd | +86-15028179902 |
angelia@hbmojin.com | China | 1069 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 18628 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21667 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32836 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29888 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 |
sales@sdzschem.com | China | 2931 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 |
sales@chemdad.com | China | 39916 | 58 |
Shenyang Simchoice Chemical Co.,Ltd | +86-024-23769576 +86-15040101888 |
sales@simchoicechem.com | China | 255 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49392 | 58 |
P-아미노아조벤젠 관련 검색:
N,N-디메틸아닐린 4-(페닐아조)디페닐아민 수단 레드 7B 메틸 레드 수단 III 용액 디스페르스 엘로 3 수단 IV 파라 레드 메틸 레드, 나트륨 염 3-하이드록시-4-((2-설포-4-((4-설포페닐)아조)페닐)아조N-2,7-나프탈렌디술폰산 테트라나트륨 기름 레드 "O" 이나트륨 7-하이드록시-8-((4-(페닐아조)페닐)아조)-1,3-나프탈렌- 디설폰산
Epi-Lacosamide-d3 (1.0 mg/mL in Acetonitrile)
Dibutyl phosphate
6-HYDROXYWARFARIN
CBPNZQVSJQDFBE-VUWIKSLBSA-N
LUMIRACOXIB
Tolclofos-methyl