ChemicalBook >제품 카탈로그 >유기 화학>헤테로시 클릭 화합물>2,2,6-Trimethyl-4H-1,3-dioxin-4-one

2,2,6-Trimethyl-4H-1,3-dioxin-4-one

2,2,6-Trimethyl-4H-1,3-dioxin-4-one 구조식 이미지

카스 번호:: 5394-63-8

상품명:: 2,2,6-Trimethyl-4H-1,3-dioxin-4-one

동의어(영문):: 2,2,6-TRIMETHYL-1,3-DIOXIN-4-ONE;Diketton Acetone Adduct;2,2,6-TRIMETHYL-1,3-DIOXEN-4-ONE;TKD;2,2,6-TrimethyL;-4H-1,3-dioxin-4-one;DIKETE ACETONE ADDUCT;DIKETENE ACETONE ADDUCT;2,2,6-Trimethyl-4H-1,3-dioxin-;Trimethyl-(4H)-1,3-dioxin-4-one

CBNumber:: CB0412977

분자식:: C7H10O3

포뮬러 무게:: 142.15

MOL 파일:: 5394-63-8.mol

MSDS 파일:: SDS

속성

안전

MSDS

용도

공급 업체 256

2,2,6-Trimethyl-4H-1,3-dioxin-4-one 속성

녹는점: 12-13 °C(lit.)

끓는 점: ~275 °C(lit.)

밀도: 1.07 g/mL at 25 °C(lit.)

굴절률: n20/D 1.460(lit.)

인화점: 67 °F

저장 조건: 2-8°C

용해도: 물: 불용성

물리적 상태: 액체

색상: 어두운 갈색

수용성: 실질적으로 불용성

BRN: 2408

노출 한도: ACGIH: TWA 250 ppm; STEL 500 ppm
OSHA: TWA 1000 ppm(2400 mg/m3)
NIOSH: IDLH 2500 ppm; TWA 250 ppm(590 mg/m3)

InChIKey: XFRBXZCBOYNMJP-UHFFFAOYSA-N

CAS 데이터베이스: 5394-63-8(CAS DataBase Reference)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	F,Xi
위험 카페고리 넘버	11-36/37/38-36
안전지침서	16-26-27-36/37/39-9-33
유엔번호(UN No.)	UN 1993 3/PG 2
WGK 독일	3
위험 등급	3
포장분류	II
HS 번호	29329995
기존화학 물질	KE-34501

그림문자(GHS):

신호 어:

Danger

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	그림 문자	P- 코드
H225	고인화성 액체 및 증기	인화성 액체	구분 2	위험		P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H319	눈에 심한 자극을 일으킴	심한 눈 손상 또는 자극성 물질	구분 2A	경고		P264, P280, P305+P351+P338,P337+P313P

예방조치문구:

P210	열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P305+P351+P338	눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

NFPA 704

	3
2		0

2,2,6-Trimethyl-4H-1,3-dioxin-4-one MSDS

2,2,6-Trimethyl-4H-1,3-dioxin-4-one

2,2,6-Trimethyl-4H-1,3-dioxin-4-one C화학적 특성, 용도, 생산

화학적 성질

Dark brown liquid

용도

Diketene-Acetone Adduct can be used in place of diketene in many reactions. As a transportable form of diketene, it is especially important in those countries, where the transportation of diketene is not allowed or at least not desired.

주요 응용

2,2,6-Trimethyl-4H-1,3-dioxin-4-one generates unstable acetylketene together with acetone when heated above 120 ℃. Subsequent condensation with isocyanates, arylcyanates, or substituted cyanamides gives access to a wide range of 1,3-oxazine derivatives. Furthermore, diketene – acetone adduct can also be used for the preparation of a variety of compounds that are not accessible from diketene.

화학 반응

Diketene – acetone adduct (2,2,6-Trimethyl-4H-1,3-dioxin-4-one) can be regarded as a stabilized form of diketene. It can be safely transported and may conveniently be used instead of diketene in many reactions. For example, it reacts with alcohols and amines to yield acetoacetates and acetoacetamides, respectively. Diketene – acetone adduct generates unstable acetylketene together with acetone when heated above 120 ?C. Subsequent condensation with isocyanates, arylcyanates, or substituted cyanamides gives access to a wide range of 1,3-oxazine derivatives. Furthermore, diketene – acetone adduct can also be used for the preparation of a variety of compounds that are not accessible from diketene.

2,2,6-Trimethyl-4H-1,3-dioxin-4-one 준비 용품 및 원자재

원자재

Butanoic acid, 3-oxo-, 1-methylethenyl ester 1-Butene-1,3-dione 1,3-Dioxan-4-one, 2,2,6-trimethyl- 케텐 아세톤 아세틸 케텐 P-톨루엔설폰 산 아세토아세트산터셔리부틸에스테르

준비 용품

2,6-Dimethyl-4H-pyran-4-one 아세토초산아닐리드 4H-Pyran-4-one, 2,3-dihydro-2,2,3,3-tetramethoxy-6-methyl- A-NAPHTHYLACETOACETANILIDE 4-(2,3-Dichlorophenyl)-2,6-diMethyl-1,4-dihydropyridine-3,5-dicarboxylic acid

2,2,6-Trimethyl-4H-1,3-dioxin-4-one 공급 업체

글로벌( 256)공급 업체

공급자	전화	이메일	국가	제품 수	이점
BTC pharm India	+918790379245	banny.janga@btcpharm.com	India	1269	58
Hebei Guanlang Biotechnology Co,.LTD	+8619930503252	daisy@crovellbio.com	China	5964	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7845	58
Ouhuang Engineering Materials (Hubei) Co., Ltd	+8617702722807	admin@hbouhuang.com	China	2259	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Beijing Cooperate Pharmaceutical Co.,Ltd	010-60279497	sales01@cooperate-pharm.com	CHINA	1811	55
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10248	58

2,2,6-Trimethyl-4H-1,3-dioxin-4-one 관련 검색:

붕산트리메틸 메틸이소부틸케톤 N-메틸-2-피롤리디논 아세토시메 시클로옥텐 2,3,7,8-테트라클로로디벤조-P-디옥신 Mesotrione Norandrostenedione Norgestrel METHYL-2-PYRROLIDONE 2,2,5,6-TETRAMETHYL-4H-1,3-DIOXIN-4-ONE 2,2,6-Trimethyl-4H-1,3-dioxin-4-one 2,2-DIMETHYL-6-TRIFLUOROMETHYL-1,3-DIOXIN-4-ONE (6R)-(-)-4,10-DIMETHYL-7-ISOPROPYL-1,5-DIOXASPIRO[5.5]UNDEC-3-EN-2-ON 2,6-Bis(4-methoxyphenyl)-2-methyl-4H-1,3-dioxin-4-one SPIRO[ADAMANTANE-2,2'-(6'-(4'-CHLOROPHENYL)-4H-1',3'-DIOXIN-4'-ONE)] 2-(chloromethyl)-2-methyl-6-phenyl-4H-1,3-dioxin-4-one 2-(BROMOMETHYL)-6-(4-METHYLPHENYL)-2-PHENYL-4H-1,3-DIOXIN-4-ONE