네오펜탄

네오펜탄
네오펜탄 구조식 이미지
카스 번호:
463-82-1
한글명:
네오펜탄
동의어(한글):
네오펜탄;2,2-디메틸프로판
상품명:
2,2-DIMETHYLPROPANE
동의어(영문):
Neopentane;dimethylpropane;Neopentan;Neo-C5H12;New pentane;tert-Pentane;Dimethylpropanol;Tetramethylmethan;Tetramethylcarbon;2,2-Dimethylpropan
CBNumber:
CB0703130
분자식:
C5H12
포뮬러 무게:
72.15
MOL 파일:
463-82-1.mol
MSDS 파일:
SDS

네오펜탄 속성

녹는점
-19.8°
끓는 점
bp 9.5°
밀도
d00 0.613 (liq)
증기압
1,074.43 at 19.492 °C, 1,267.75 at 24.560 °C (ebulliometry, Osborn and Douslin, 1974)
굴절률
1.3390
용해도
알코올과 에테르에 용해됩니다(Weast, 1986).
산도 계수 (pKa)
>14 (Schwarzenbach et al., 1993)
수용성
25°C에서 33.2 mg/kg(진탕 플라스크-GC, McAuliffe, 1966)
Henry's Law Constant
3.70(atm?m3/mol) at 25 °C (Mackay and Shiu, 1981)
노출 한도
ACGIH TLV: TWA 600 ppm (adopted).
Dielectric constant
1.9099999999999999
CAS 데이터베이스
463-82-1(CAS DataBase Reference)
EPA
2,2-Dimethylpropane (463-82-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F+,N
위험 카페고리 넘버 12-51/53
안전지침서 9-16-33-61
유엔번호(UN No.) 2044
위험 등급 2.1
HS 번호 2901100000
유해 물질 데이터 463-82-1(Hazardous Substances Data)
독성 Acute oral LD50 (intraperitoneal) for mice 100 mg/kg (quoted, RTECS, 1985).
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H220 극인화성 가스 인화성 가스 구분 1 위험 GHS hazard pictograms P210, P377, P381, P403
H280 고압가스; 가열시 폭발할 수 있음 고압가스 압축가스
액화가스
용존 가스
경고 GHS hazard pictograms P410+P403
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
NFPA 704
4
0 0

네오펜탄 C화학적 특성, 용도, 생산

화학적 성질

2,2-Dimethylpropane, C5H12, is a flammable liquid and is physically similar to butane. It is an important component of petroleum fuel mixtures.

물리적 성질

Colorless, extremely flammable gas which may have a faint, pleasant odor similar to butane. Usually present as a compressed gas or liquid.

용도

2,2-Dimethylpropane is manufactured by petroleum refining operations. It is used as a chemical intermediate for agricultural chemicals, and as a component of high-octane motor and aviation fuels.

일반 설명

Boiling point 40°F. May liquefy in cool or cold weather. Less dense than water. Flash point -85°F. Autoignition temperature 842°F. Insoluble in water but soluble in alcohol. Under prolonged exposure to fire or heat, the containers may rupture violently and rocket.

공기와 물의 반응

Highly flammable. Insoluble in water.

반응 프로필

2,2-DIMETHYLPROPANE may be incompatible with strong oxidizing agents like nitric acid. Charring may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, mostly unreactive. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. Burns exothermically if heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents to produce carbon dioxide and water.

위험도

Highly flammable, dangerous fire risk, explosive limits in air 1.4–7.5%

건강위험

Vapors may cause dizziness or asphyxiation without warning. Some may be irritating if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases.

화재위험

EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Vapors from liquefied gas are initially heavier than air and spread along ground. CAUTION: Hydrogen (UN1049), Deuterium (UN1957), Hydrogen, refrigerated liquid (UN1966) and Methane (UN1971) are lighter than air and will rise. Hydrogen and Deuterium fires are difficult to detect since they burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.) Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.

Safety Profile

Poison by intraperitoneal route. An inhalation hazard. Both the gas and the liquid are flammable when exposed to heat or flame; can react vigorously with oxidlzing materials. When heated to decomposition it emits acrid smoke and irritating fumes.

잠재적 노출

Neopentane is used as a gasoline blending component; for making butyl rubber. A research chemical. Reacts with strong oxidizers, causing fire and explosion hazard. Attacks some plastics, rubbers, and coatings.

환경귀착

Photolytic. A rate constant of 6.50 x 10-11 cm3/molecule?sec was reported for the reaction of 2,2- dimethylpropane with OH radicals in air at 298 (Greiner, 1970). Rate constants of 9.0 x 10-13 and 8.49 x 10-13 cm3/molecule?sec were reported for the reaction of 2,2-dimethylpropane with OH in air (Atkinson et al., 1979; Winer et al., 1979).
Chemical/Physical. Complete combustion in air yields carbon dioxide and water vapor. 2,2- Dimethylpropane will not hydrolyze because it has no hydrolyzable functional group.

운송 방법

UN2044 2,2-Dimethylpropane, Hazard Class: 2.1; Labels: 2.1-Flammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

Purification Methods

It is freed from isobutene by passage over conc H2SO4 or P2O5, and through silica gel. [Beilstein 1 H 141, 1 I 50, 1 II 104, 1 369, 1 IV 333.] Nerolidol (3,7,11-trimethyl-1,6,10-dodecatrien-3-ol) M 222.4 [cis/trans 7212-44-4] b

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

폐기물 처리

Return refillable compressed gas cylinders to supplier. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

네오펜탄 준비 용품 및 원자재

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