Lithium tri-tert-butoxyaluminum hydride
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Lithium tri-tert-butoxyaluminum hydride 속성
- 녹는점
- 300-319 °C (dec.) (lit.)
- 끓는 점
- 66°C (THF)
- 밀도
- 0.942 g/mL at 25 °C
- 인화점
- 95 °F
- 저장 조건
- 2-8°C
- 용해도
- 저온에서 유기용매에 용해됩니다.
- 물리적 상태
- 액체
- 색상
- 투명하거나 약간 탁한 무색
- 수용성
- 물과 반응합니다.
- 감도
- Air & Moisture Sensitive
- BRN
- 5796791
- 노출 한도
- ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
- 안정성
- 안정적인. 알코올과 호환되지 않습니다. 물과 격렬하게 반응함. 가연성이 높습니다.
- InChIKey
- BYBIDFZFKATBFH-UHFFFAOYSA-N
- CAS 데이터베이스
- 17476-04-9(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | F,C,T | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 60-61-10-14/15-19-34-14-11-15-35-40-37 | ||
| 안전지침서 | 53-26-36/37/39-43-45-16-43B-6A | ||
| 유엔번호(UN No.) | UN 3399 4.3/PG 1 | ||
| WGK 독일 | 1 | ||
| RTECS 번호 | OJ5585000 | ||
| F 고인화성물질 | 10-21 | ||
| TSCA | Yes | ||
| 위험 등급 | 4.3 | ||
| 포장분류 | II | ||
| HS 번호 | 29055900 | ||
| 기존화학 물질 | 2015-3-6423 |
Lithium tri-tert-butoxyaluminum hydride C화학적 특성, 용도, 생산
화학적 성질
Lithium tri-tert-butoxyaluminum hydride is a white powder with a melting point of 319°C, which is sublimated under vacuum at 280°C. It is soluble in ethylene glycol dimethyl ether, diglyme and tetrahydrofuran, and slightly soluble in ether. Stable in dry air, hydrolyzed slowly in moist air. Lithium tri-tert-butoxyaluminum hydride is a mild and highly selective reducing agent. Ketones, aldehydes and acid chlorides can be reduced in diethyl ether or diglyme at 0°C, fatty acid esters and nitriles are not reduced, but phenyl esters of fatty acids and alicyclic acids can be reduced.용도
Lithium tri-tert-butoxyaluminum hydride is less reactive than lithium aluminum hydride (LAH) and is very useful in selective reductions of acyl halides, aldehydes, ketones, and esters. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff. LAH, is a reducing agent commonly employed in modern organic synthesis.제조 방법
Lithium aluminum hydride reacts with tert-butanol in ether to prepare Lithium tri-tert-butoxyaluminum hydride.LiAlH4+3 (CH3)3COH→LiAlH[OC(CH3)3] 3+3 H2
일반 설명
Lithium tri-tert-butoxyaluminum hydride is a mild reducing agent mainly used for the selective reduction of ketones. It is very suitable for selective reductions on account of its mild reducing power, the most important of these being the reduction of steroid ketones. In addition to chemical selectivity, a certain stereoselectivity is shown in the reduction of cyclic ketones.Lithium tri-tert-butoxyaluminum hydride 준비 용품 및 원자재
원자재
준비 용품
Lithium tri-tert-butoxyaluminum hydride 공급 업체
글로벌( 231)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Cangzhou Lingang Xingchen Chemical Co.,Ltd. | +8613820956817 |
sales1@daofuchem.com | China | 6 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12456 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 |
peter@yan-xi.com | China | 5993 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 |
sales@myuchem.com | China | 6710 | 58 |
| Hangzhou ICH Biofarm Co., Ltd | +undefined8613073685410 |
sales@ichemie.com | China | 985 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 |
info@spring-chem.com | China | 2068 | 57 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Shanghai Arbor Chemical Co., Ltd. | 021-60451682 |
act@arborchemical.com | CHINA | 906 | 58 |
Lithium tri-tert-butoxyaluminum hydride 관련 검색:
tert-부틸알코올 수소화 리튬알미늄 터트-부틸 퍼옥시아세테이트 수소화 알루미늄 염화 리튬 수소화알루미늄 나트륨 수소화나트륨 수소화리튬 알루미늄에틸레이트 알루미늄 이소프로폭사이드 알루미늄 삼차-뷰톡사이드 수산화알루미늄분말 리튬
LITHIUM TRIS[(3-ETHYL-3-PENTYL)OXY]ALUMINOHYDRIDE
LITHIUM-ALUMINUM ALLOY
LITHIUM TRI-TERT-BUTOXYALUMINODEUTERIDE
LITHIUM TETRA(PERFLUORO-T-BUTOXY)ALUMINATE
Lithium tri-tert-butoxyaluminum hydride