염화질소

염화질소
염화질소 구조식 이미지
카스 번호:
10025-85-1
한글명:
염화질소
동의어(한글):
염화질소
상품명:
Trichlorine nitride
동의어(영문):
TRICHLORAMINE;Nitrogen chloride;Trichlorine nitride;nitrogen trichloride;Trichloramine: (Nitrogen chloride);Nitrogen chloride(NCl3) (6CI,7CI,8CI,9CI);(1R,4S)-4-Aminocyclopent-7-enyl]methanol&hydrochloride
CBNumber:
CB0852223
분자식:
Cl3N
포뮬러 무게:
120.37
MOL 파일:
10025-85-1.mol

염화질소 속성

녹는점
-27°C
끓는 점
71°C (estimate)
밀도
1.653
용해도
insoluble in H2O; soluble in CS2, benzene, ctc 2
물리적 상태
노란색 유성 액체
산도 계수 (pKa)
-22.67±0.70(Predicted)
색상
yellow oily liquid; explodes, explosive
수용성
불용성 H2O, 24시간 후에 H2O로 분해됨; 가용성 CS2, 삼염화인, 벤젠, CCl4, CHCl3 [MER06]
CAS 데이터베이스
10025-85-1
EPA
Nitrogen trichloride (10025-85-1)

안전

유엔번호(UN No.) 3099
위험 등급 5.1
포장분류 II
유해 물질 데이터 10025-85-1(Hazardous Substances Data)

염화질소 C화학적 특성, 용도, 생산

화학적 성질

Yellow oil or rhombic crystals.Insoluble in cold water; decomposes in hot water; soluble in chloroform, phosphorus trichloride, and carbon disulfide.

물리적 성질

Yellow, oily, heavy liquid; pungent odor; density 1.653 g/mL; freezes to rhombohedral crystalline solid below -40°C; evaporates in air rapidly; vaporpressure 150 torr at 20°C; explodes when heated at 93°C; highly unstable, decomposes explosively in light; insoluble in water, decomposes slowly in cold water after several hours; decomposes in hot water; soluble in benzene, chloroform, carbon tetrachloride, carbon disulfide and phosphorus trichloride.

용도

Bleaching of flour; wastage control of citrus fruit.

제조 방법

Nitrogen trichloride is prepared by passing chlorine gas into slightly acid solution of ammonium chloride. The product is continuously extracted with carbon tetrachloride:
NH4Cl + 3Cl2 → NCl3 + 4HCl
Hypochlorous acid, HOCl, also may be used instead of chlorine in such preparation.
Nitrogen trichloride can be prepared by the action of anhydrous chlorine with anhydrous ammonia:
3Cl2 + NH3 → NCl3 + 3HCl
Nitrogen trichloride is made commercially by electrolyzing an acidified solution of ammonium chloride.

위험도

Explodes when heated to approximately 200F (93C) or when exposed to direct sunlight. Toxic by ingestion and inhalation, strong irritant.

Safety Profile

Moderately toxic by inhalation. An irritant to the eyes, skin, mucous membranes, and a systemic central nervous system irritant. An explosive sensitive to impact, light, and ultrasound. The solid explodes on melting. The liquid explodes above 60°C. Concentrated solutions are also explosive. Explosive decomposition is initiated by contact with: concentrated ammonia, arsenic, dinitrogen tetraoxide, hydrogen sulfide, hydrogen trisulfide, nitrogen oxide, organic matter, ozone, phosphine, phosphorus, potassium cyanide, potassium hydroxide solutions, selenium, hydrogen chloride, hydrogen fluoride, hydrogen bromide, hydrogen iodide. mxtures with chlorine + hydrogen are potentially explosive. Upon decomposition it emits toxic fumes of Cl- and NOx. See also CHLORIDES.

염화질소 준비 용품 및 원자재

원자재

준비 용품


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