Ruthenium tetroxide

Ruthenium tetroxide 구조식 이미지
카스 번호:
20427-56-9
상품명:
Ruthenium tetroxide
동의어(영문):
RuO4;Ruthenium(Ⅷ) Oxide;rutheniumtetraoxide;RUTHENIUM TETROXIDE;ruthenium(VI) oxide;RUTHENIUM (VIII) OXIDE;Ruthenium oxide (RuO4);0.5%stabilizedaqueoussolution;Ruthenium oxide (RuO4), (T-4)-;ruthenium dioxide hydrate,superfine powder
CBNumber:
CB1121685
분자식:
O4Ru
포뮬러 무게:
165.07
MOL 파일:
20427-56-9.mol

Ruthenium tetroxide 속성

녹는점
25.4°
끓는 점
bp 40°
밀도
3.290
저장 조건
Refrigerator (+4°C)
용해도
slightly soluble in H2O; very soluble in ctc; reacEtOH
물리적 상태
결정성 분말
색상
하얀색
수용성
2.03g/100mL H2O(20°C); 가용성이 높은 CCl4, 기타 염소화 탄화수소 [MER06] [KIR82]
감도
heat sensitive, store cold
안정성
안정적인.
CAS 데이터베이스
20427-56-9
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
안전지침서 16-17-36/37/39
유엔번호(UN No.) 3139
위험 등급 5.1
포장분류 I
HS 번호 28439000
기존화학 물질 KE-30677
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H413 장기적 영향에 의해 수생생물에 유해의 우려가 있음 수생 환경유해성 물질 - 만성 구분 4
예방조치문구:
P273 환경으로 배출하지 마시오.

Ruthenium tetroxide C화학적 특성, 용도, 생산

화학적 성질

Ruthenium tetroxide is a golden-yellow volatile solid with an acrid odor, sparingly soluble in water and freely soluble in CCl4, in which it forms stable solutions. In comparison with the analogous compound OsO4, ruthenium tetroxide is a stronger oxidizing agent that reacts violently-resulting in explosion and/or flames-with most common organic solvents such as ether, alcohols, benzene, and pyridine, 1 and also with filter paper.
Ruthenium tetroxide
Ruthenium tetroxide is a clear orange to gold colored solution, It sublimes very easily at room temperature, possessing a melting point of 25.4℃ and a boiling point of 40℃ . While it is very soluble in CCl4 and other nonflammable organic solvents, a saturated solution in water at 20℃ reaches a concentration of 2% w/v.

용도

Ruthenium tetroxide is an oxidizing agent similar to osmium tetroxide, but more difficult to handle. The solvents normally employed in OsO4 oxidations (ether, benzene, pyridine) cannot be used because of their violent reaction with RuO4. Only CCl4 is recommended.

생산 방법

Ruthenium(VIII) oxide (ruthenium tetraoxide) RuO4 is formed when an alkaline ruthenium solution is treated with a strong oxidant, such as chlorine, or bromate ion when the Ru is in acid solution.

제조 방법

Ruthenium tetroxide can be conveniently handled as a carbon tetrachloride solution that is easily prepared by stirring an aqueous solution of sodium periodate NaIO4 with a suspension of hydrated ruthenium dioxide in CCl4. Ruthenium tetroxide partitions between CCl4 and water, resulting in a 60:1 concentration ratio.

위험도

Fire risk in contact with organic materials.

Ruthenium tetroxide 준비 용품 및 원자재

원자재

준비 용품


Ruthenium tetroxide 공급 업체

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