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플루오로트리클로로메탄

플루오로트리클로로메탄
플루오로트리클로로메탄 구조식 이미지
카스 번호:
75-69-4
한글명:
플루오로트리클로로메탄
동의어(한글):
트라이클로로플루오로메테인;트리클로로플루오로메탄;플루오로트리클로로메탄
상품명:
Trichlorofluoromethane
동의어(영문):
f11;f11b;F 11;f-11;fc11;CFCl3;CCl3F;FC 11;F 11B;fc-11
CBNumber:
CB1127379
분자식:
CCl3F
포뮬러 무게:
137.37
MOL 파일:
75-69-4.mol

플루오로트리클로로메탄 속성

녹는점
-111°C
끓는 점
23.8°C
밀도
1.494
증기 밀도
5.04 (vs air)
증기압
12.85 psi ( 20 °C) &_& 39.17 psi ( 55 °C)
굴절률
1.382
인화점
2 °C
저장 조건
2-8°C
용해도
water: soluble1g/L
물리적 상태
neat
색상
Colorless, odorless liquid
냄새
Odorless; weak chlorinated solvent.
수용성
insoluble. 0.124 g/100 mL
Merck
13,9714
BRN
1732469
Henry's Law Constant
At 25 °C: 88.2 and 123 in distilled water and seawater, respectively (Hunter-Smith et al., 1983)
노출 한도
NIOSH REL: ceiling 1,000 ppm (5,600 mg/m3), IDLH 2,000 ppm; OSHA PEL: TWA 1,000 ppm; ACGIH TLV: ceiling 1,000 ppm (adopted).
안정성
Stable. Incompatible with bronze, silver, copper, beryllium, alkali and alkaline earth metals.
InChIKey
CYRMSUTZVYGINF-UHFFFAOYSA-N
CAS 데이터베이스
75-69-4(CAS DataBase Reference)
NIST
Trichloromonofluoromethane(75-69-4)
EPA
Methane, trichlorofluoro-(75-69-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn;N,Xi,N,Xn,T,F
위험 카페고리 넘버 20-59-23-21/22-36/37/38-20/22-11-23/25-39/23/24/25-23/24/25-21-67-66-36
안전지침서 23-24/25-59-61-45-36/37-36-26-16-24-7
유엔번호(UN No.) 3082
WGK 독일 3
RTECS 번호 PB6125000
위험 참고 사항 Irritant
유해 물질 데이터 75-69-4(Hazardous Substances Data)
독성 Drinking water standard: No MCLGs or MCLs have been proposed although trichlorofluoromethane has been listed for regulation (U.S. EPA, 1996). A DWEL of 100 μg/L was recommended (U.S. EPA, 2000).
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H312 피부와 접촉하면 유해함 급성 독성 물질 - 경피 구분 4 경고 P280,P302+P352, P312, P322, P363,P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
H331 흡입하면 유독함 급성 독성 물질 흡입 구분 3 위험 P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H336 졸음 또는 현기증을 일으킬 수 있음 특정표적장기 독성 물질(1회 노출);마취작용 구분 3 경고 P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H370 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킴(노출되어도 특정 표적장기 독성을 일으키지 않는다는 결정적인 노출경로가 있다면 노출경로를 기재) 특정 표적장기 독성 - 1회 노출 구분 1 위험 P260, P264, P270, P307+P311, P321,P405, P501
H372 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킴 특정 표적장기 독성 - 반복 노출 구분 1 위험 P260, P264, P270, P314, P501
H420 대기 상층부의 오존층을 파괴하여 공공의 건강 및 환경에 유해함 오존층에 유해 함 구분 1 경고 P502
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P311 의료기관(의사)의 진찰을 받으시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P403+P233 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
P502 정보의 재사용의 회복 / 제조 / 공급 업체를 참조하십시오

플루오로트리클로로메탄 MSDS


Fluorocarbon 11

플루오로트리클로로메탄 C화학적 특성, 용도, 생산

화학적 성질

colourless liquid

화학적 성질

Fluorotrichloromethane is a colorless liquid or gas. Chlorinated solvent odor. The Odor Threshold is 5.0 ppm.

용도

In refrigeration machinery requiring a refrigerant effective at negative pressures. As aerosol propellant.

정의

ChEBI: A one-carbon compound that is methane in which the hydrogens have been replaced by three chlorine and one fluorine atom.

일반 설명

A clear light colored liquid. Nearly odorless. Denser than water. Poses low acute health hazard to humans. Primary hazard is to the environment. Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminate groundwater and nearby waterways.

공기와 물의 반응

Water soluble. Hydrolyzed slowly.

반응 프로필

Trichlorofluoromethane is incompatible with alkali or alkaline earth metals, powdered aluminum, zinc and beryllium. Trichlorofluoromethane reacts violently with barium and lithium.

건강위험

Breathing concentrations approaching 10% in air will cause dizziness and drowsiness. Contact with tissues may cause frostbite.

화재위험

Special Hazards of Combustion Products: Produces irritating and toxic products when heated to decomposition temperatures.

화학 반응

Reactivity with Water: No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

High concentrations cause narcosis and anesthesia in humans. Human systemic effects by inhalation: conjunctiva irritation, fibrosing alveolitis, and liver changes. Experimental poison by inhalation. Moderately toxic by intraDeritoneal route. Reacts violentlv with I aluminum, barium, or lithium. When heated to decomposition it emits highly toxic fumes of Fand Cl-. Used as an aerosol propellant, refrigerant, and blowing agent for polymeric foams. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.

잠재적 노출

This material is used as a refrigerant; aerosol propellant; and foaming agent; as blowing agent in production of polyurethane foams.

환경귀착

Biological. In a static-culture-flask screening test, trichlorofluoromethane was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum. No significant degradation was observed after 28 d of incubation. At substrate concentrations of 5 and 10 mg/L, percent losses due to volatilization were 58 and 37% after 10 d (Tabak et al., 1981).
Chemical/Physical. When trichlorofluoromethane (50 μg/L) in an ultrasonicator was exposed to 20-kHz ultrasound at 5 °C, nearly 100% degradation was achieved after 6 min. During sonication, the pH of the aqueous solution decreased, which is consistent with the formation of HCl, hydrofluoric acid, and acidic species from fluorine and chlorine. In this experiment <5% of trichlorofluoroethane was lost to volatilization (Cheung and Kurup, 1994).

운송 방법

Hazard Class: 2.2; Labels: 2.2-Nonflammable compressed gas, Technical Name Required.

비 호환성

Chemically active and powdered metals: aluminum, barium, sodium, potassium, calcium, powdered aluminum; zinc, magnesium.

폐기물 처리

Incineration, preferably after mixing with another combustible fuel. Care must be exer cised to assure complete combustion to prevent the forma tion of phosgene. An acid scrubber is necessary to remove the halo acids produced. Consult with environmental regu latory agencies for guidance on acceptable disposal prac tices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations govern ing storage, transportation, treatment, and waste disposal.

플루오로트리클로로메탄 준비 용품 및 원자재

원자재

준비 용품


플루오로트리클로로메탄 공급 업체

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Mainchem Co., Ltd.
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AoboRui (Tianjin) Co., Ltd. 86 022 65675308 18310521067
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SHANG FLUORO 021-65170832 13331983812 18019716620
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J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
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Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40269 62
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030
86-021-50426522,50426273 sales@jingyan-chemical.com China 10011 60
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202,021-54308259
+86-21-64545202 info@hanhonggroup.com China 43261 64

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