프로필벤젠

프로필벤젠
프로필벤젠 구조식 이미지
카스 번호:
103-65-1
한글명:
프로필벤젠
동의어(한글):
N-프로필벤젠;프로필벤젠
상품명:
N-PROPYLBENZENE
동의어(영문):
PROPYLBENZENE;Isocomene;Phenylpropane;1-PHENYLPROPANE;Isocumene;Propylbenzol;1-Propylbenzene;propyl-benzen;n-Propylbenzen;n-Popyl benzene
CBNumber:
CB1128336
분자식:
C9H12
포뮬러 무게:
120.19
MOL 파일:
103-65-1.mol
MSDS 파일:
SDS

프로필벤젠 속성

녹는점
-99 °C (lit.)
끓는 점
159 °C (lit.)
밀도
0.862 g/mL at 25 °C (lit.)
증기 밀도
4.14 (vs air)
증기압
2 mm Hg ( 20 °C)
굴절률
n20/D 1.491(lit.)
인화점
118 °F
저장 조건
2-8°C
용해도
0.06g/L
물리적 상태
액체
산도 계수 (pKa)
>14 (Schwarzenbach et al., 1993)
색상
약간 노란색으로 맑음
폭발한계
0.8-6%(V)
Odor Threshold
0.0038ppm
수용성
알코올, 에테르, 아세톤, 벤젠, 석유 에테르와 섞입니다. 물과 약간 섞임.
Merck
14,7844
BRN
1903006
Henry's Law Constant
4.35, 6.21, 8.37, 11.6, and 15.3 at 10, 15, 20, 25, and 30 °C, respectively (headspace-GC, Perlinger et al., 1993)
Dielectric constant
2.4(20℃)
안정성
안정적인. 가연성. 강한 산화제와 호환되지 않습니다.
InChIKey
ODLMAHJVESYWTB-UHFFFAOYSA-N
LogP
3.690
CAS 데이터베이스
103-65-1(CAS DataBase Reference)
NIST
Benzene, propyl-(103-65-1)
EPA
n-Propylbenzene (103-65-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,N,Xn,T,F
위험 카페고리 넘버 10-37-51/53-65-39/23/24/25-23/24/25-11
안전지침서 24-37-61-62-45-36/37-16
유엔번호(UN No.) UN 2364 3/PG 3
WGK 독일 2
RTECS 번호 DA8750000
자연 발화 온도 842 °F
TSCA Yes
위험 등급 3
포장분류 III
HS 번호 29029090
유해 물질 데이터 103-65-1(Hazardous Substances Data)
독성 LD50 orally in rats: 6040 mg/kg (Jenner)
기존화학 물질 KE-29781
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험 GHS hazard pictograms
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P273 환경으로 배출하지 마시오.
NFPA 704
3
1 0

프로필벤젠 C화학적 특성, 용도, 생산

화학적 성질

colourless or light yellow liquid

물리적 성질

Clear, colorless, mobile liquid with an odor similar to ethylbenzene or toluene. An odor threshold concentration of 3.8 ppbv was determined by a triangular odor bag method (Nagata and Takeuchi, 1990). Cometto-Mu?iz and Cain (1994) reported an average nasal pungency threshold concentration of 1,487 ppmv.

용도

n-Propylbenzene is used to prepare benzoic acid. It is employed as a solvent for gas chromatography. It is also used as a solvent and an intermediate in organic synthesis. Further, it is used in fuels and fuel additives.

정의

ChEBI: An alkylbenzene that is benzene having one of its aromatic hydrogens substituted by a propyl group.

일반 설명

A clear colorless liquid. Insoluble in water and less dense than water. Flash point 86°F. Mildly toxic by ingestion and inhalation. Used to make other chemicals.

공기와 물의 반응

Highly flammable. Insoluble in water.

반응 프로필

Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as PROPYL BENZENE, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.

위험도

Flammable, moderate fire risk.

건강위험

May be harmful by inhalation, ingestion, or skin absorption. May cause eye and skin irritation.

화재위험

Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flashback.

환경귀착

Biological. A Nocardia sp., growing on n-octadecane, biodegraded propylbenzene to phenylacetic acid (Davis and Raymond, 1981). Propylbenzene was cometabolized by a strain of Micrococcus cerificans to cinnamic acid (Pitter and Chudoba, 1990).
Estimated half-lives of propylbenzene (0.8 μg/L) from an experimental marine mesocosm during the spring (8–16 °C), summer (20–22 °C), and winter (3–7 °C) were 19, 1.3, and 11 d, respectively (Wakeham et al., 1983).
Photolytic. A rate constant of 3.7 x 10-9 L/molecule?sec was reported for the reaction of propylbenzene with OH radicals in the gas phase (Darnall et al., 1976). Similarly, a room temperature rate constant of 5.7 x 10-12 cm3/molecule?sec was reported for the vapor-phase reaction of propylbenzene with OH radicals (Atkinson, 1985). At 25 °C, a rate constant of 6.58 x 10-12 cm3/molecule?sec was reported for the same reaction (Ohta and Ohyama, 1985).
Chemical/Physical. Propylbenzene will not hydrolyze because it does not contain a hydrolyzable functional group (Kollig, 1993).

프로필벤젠 준비 용품 및 원자재

원자재

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