스크라단

스크라단
스크라단 구조식 이미지
카스 번호:
152-16-9
한글명:
스크라단
동의어(한글):
쉬라단;스크라단;N,N,N',N',N'',N'',N''',N'''-옥타메틸다이포스포르아마이드;비스(다이메틸아미노)아포스폰산 무수물;비스(다이메틸아미노)인산 무수물;비스(비스다이메틸아미노포스포노러스) 안하이드라이드;비스-N,N,N',N'-테트라메틸포스포로다이아미드산 무수물;옥타메틸 피로포스포르아마이드;옥타메틸다이포스포르아마이드;옥타메틸디포스포르아미드;옥타메틸피로인산 아마이드;옥타메틸피로포스포르아마이드
상품명:
SCHRADAN
동의어(영문):
OMPA;ompax;sytam;pestox;systam;ompatox;pestox3;SCHRADEN;SCHADRAN;SCHRADAN
CBNumber:
CB1238792
분자식:
C8H24N4O3P2
포뮬러 무게:
286.25
MOL 파일:
152-16-9.mol
MSDS 파일:
SDS

스크라단 속성

녹는점
17℃
끓는 점
bp0.5 120-125°; bp2.0 154°
밀도
1.24 g/cm3 (25 ºC)
굴절률
1.4698 (589.3 nm 20℃)
물리적 상태
액체
산도 계수 (pKa)
0.85±0.70(Predicted)
색상
점성 액체
CAS 데이터베이스
152-16-9
EPA
Schradan (152-16-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T+
위험 카페고리 넘버 27/28
안전지침서 36/37-38-45
유엔번호(UN No.) 3018
위험 등급 6.1(a)
포장분류 I
HS 번호 29299090
유해 물질 데이터 152-16-9(Hazardous Substances Data)
독성 LD50 in male, female rats (mg/kg): 9.1, 42 orally; 15, 44 dermally (Gaines)
기존화학 물질 KE-05-1145
유해화학물질 필터링 97-1-143
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 쉬라단 및 이를 1% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H300 삼키면 치명적임 급성 독성 물질 - 경구 구분 1,2 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H310 피부와 접촉하면 치명적임 급성 독성 물질 - 경피 구분 1,2 위험 GHS hazard pictograms P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
예방조치문구:
P262 눈, 피부, 의복에 묻지 않도록 하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P302+P350 피부에 묻은 경우,비눗물로 부드럽게 씻기
P310 즉시 의료기관(의사)의 진찰을 받으시오. 삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.
P321 (…) 처치를 하시오.
P322 특정 조치(라벨의 … 참조)
P330 입을 씻어내시오.
P361 즉시 오염된 의복을 모두 벗을 것
P363 다시 사용전 오염된 의류는 세척하시오.
P405 밀봉하여 저장하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.

스크라단 C화학적 특성, 용도, 생산

화학적 성질

OMPA is a colorless liquid in crude form; otherwise, it is a dark brown viscous liquid.

용도

Insecticide.

일반 설명

Schradan, octamethyl pyrophosphoramide(OMPA), bis[bisdimethylaminophosphonous] anhydride(Pestox III), is a viscous liquid that is miscible with waterand soluble in most organic solvents. It is not hydrolyzed byalkalies or water but is hydrolyzed by acids. Schradan isused as a systemic insecticide for plants, being absorbed bythe plants without appreciable injury. Insects feeding on theplant are incapacitated.
Schradan is a weak inhibitor of cholinesterases in vitro.In vivo, it is metabolized to the very strong inhibitor hydroxymethylOMPA. Hydroxymethyl OMPA is not stable andis metabolized further to the N-methoxide, which is a weakinhibitor of cholinesterase.

반응 프로필

Organophosphates, such as SCHRADAN, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

건강위험

Extremely toxic; probable oral lethal dose in humans is 5-50 mg/kg, between 7 drops and 1 teaspoonful for a 150 lb. person. It is highly toxic when inhaled. Material is a cholinesterase inhibitor. It is similar in action to other organophosphorous pesticides in its toxicity. It is slightly less toxic than parathion. Gastrointestinal, neurologic and respiratory symptoms may accompany poisoning with SCHRADAN. High doses may cause a toxic psychosis similar to acute alcoholism. Persons taking phenobarbital and phenaglycodol together, glutethimide, chlorpromazine hydrochloride, or meprobamate may be at greater risk. These drugs appear to enhance the toxicity of the material markedly.

화재위험

When heated to decomposition, SCHRADAN can emit highly toxic fumes of oxides of phosphorus. Decomposes when mixed with acid. Hydrolyzed under acid conditions to dimethylamine and orthophosphoric acid.

Safety Profile

Poison by ingestion, inhalation,skin contact, intraperitoneal, intravenous, subcutaneous,and ocular routes. Human systemic effects by ingestion: acholinesterase inhibitor. Has been found to inhibitperipheral cholinesterase without pronounced effects o

잠재적 노출

Material is used as a systemic insecticide for plants and as an acaricide. Not registered as a pesticide in the United States.

운송 방법

UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

비 호환성

Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Acids.

폐기물 처리

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

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