플루오알루민산나트륨

플루오알루민산나트륨
플루오알루민산나트륨 구조식 이미지
카스 번호:
15096-52-3
한글명:
플루오알루민산나트륨
동의어(한글):
크리올라이트;플루오린화알루미늄산나트륨(불화알루미늄산나트륨);플루오알루민산나트륨;크리올라이트;헥사플루오로알루민산나트륨;빙정석(합성);나트륨플루오;알루미늄 소듐 플루오라이드
상품명:
cryolite
동의어(영문):
SYNTHETIC CRYOLITE;ALUMINUM SODIUM FLUORIDE;Sodium aluminium fluoride;icespar;icetone;kriolit;CRYOLITE;KRYOLITH;koyoside;kryocide
CBNumber:
CB1300372
분자식:
AlF6Na3
포뮬러 무게:
209.94
MOL 파일:
15096-52-3.mol
MSDS 파일:
SDS

플루오알루민산나트륨 속성

녹는점
1012
끓는 점
decomp
밀도
2.9 g/mL at 25 °C(lit.)
굴절률
1.338
저장 조건
2-8°C
Merck
13,2634
CAS 데이터베이스
15096-52-3(CAS DataBase Reference)
EPA
Cryolite (15096-52-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N
위험 카페고리 넘버 20/22-48/23/25-51/53-20
안전지침서 22-37-45-61
유엔번호(UN No.) UN 3077 9/PG 3
WGK 독일 1
RTECS 번호 BD0075000
TSCA Yes
위험 등급 9
HS 번호 2826300000
유해 물질 데이터 15096-52-3(Hazardous Substances Data)
기존화학 물질 KE-34897
유해화학물질 필터링 97-1-273
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 크리올라이트[Cryolite; 15096-52-3, 13775-53-6] 및 이를 1% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 GHS hazard pictograms P261, P271, P304+P340, P312
H372 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킴 특정 표적장기 독성 - 반복 노출 구분 1 위험 GHS hazard pictograms P260, P264, P270, P314, P501
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P273 환경으로 배출하지 마시오.
P314 불편함을 느끼면 의학적인 조치·조언을 구하시오.

플루오알루민산나트륨 C화학적 특성, 용도, 생산

화학적 성질

Sodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating); synthetic product is an amorphous powder. Odorless

물리적 성질

Habit: massive, granular, pseudocubic euhedral crystals.
Color: snow white, gray, reddish white, or brownish white.
Diaphaneity: transparent to translucent.
Luster: vitreous, greasy.
Streak: white.
Cleavage: [001], [110], [101].
Fracture: uneven.
Occurrence: large bed in a granitic vein in gray gneiss.
Melting point: 1009°C.

용도

Cryolite is commonly used as an electrolyte for aluminum electrolysis. Alumina is dissolved in molten cryolite is used to dissolve alumina during aluminium processing.

정의

A natural fluoride of sodium and aluminum or made synthetically from fluorspar, sulfuric acid, hydrated alumina, and sodium carbonate.

일반 설명

An odorless white solid or powder. Mp: 1291°C. Density: 2.95 g cm-3. Dust irritates the eyes and skin; inhaled dust irriates the nose, mouth and lungs. Insoluble in water. Synthesized by fusion of sodium fluoride and aluminum fluoride as a electrolyte in the reduction of alumina to aluminum metal. Occurs in nature as the mineral cryolite. Aqueous suspensions of powdered sodium aluminum fluoride are used as insecticides.

반응 프로필

SODIUM ALUMINUM FLUORIDE is non-combustible. Emits toxic fumes when heated to decomposition. Incompatible with strong oxidizing agents and strong acids. Decomposed by bases, which can generate soluble fluorides. Soluble in concentrated sulfuric acid.

농업용

Insecticide: Sodium aluminum fluoride is used as an insecticide on food crops and ornamentals, and also in aluminum refining and making ceramics, glass and polishes. Cryolite is used to control a variety of pests on cucurbits (melons, cantaloupe, water melon, pumpkins, all types of squash), fruiting vegetables (eggplant, pepper, broccoli, Brussels sprouts, cabbage, cauliflower, collards, head and leaf lettuce, kohlrabi), kiwi (in California only), pears, radish, cranberry and peaches, grapefruit, lemon, lime, orange, tangelo, tangerines, tomatoes, apples, potatoes, beans and grapes. Also on ornamental plants, woody shrubs and vines. Not listed for use in EU countries. Registered for use in the U.S

상품명

KRYOCIDE®; CHIOLITE®; CRYOLITE 93®; ICE-SPAR®; ICETONE®; KOYOSIDE®; KRIOLIT®; PROKIL® Sodium aluminum fluoride; VILLIAUMITE®

Safety Profile

Poison by ingestion. Used as a pesticide. Mutation data reported.When heated to decomposition it emits toxic fumes of Fand NazO. See also FLUORIDES.

잠재적 노출

Sodium aluminum fluoride is used in making pesticides, ceramics, glass, and polishes; in refining reduction of aluminum, flux, glass, and enamel.

운송 방법

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

비 호환성

Incompatible with strong acids such as sulfuric, strong oxidizers, hydrogen fluoride.

폐기물 처리

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

플루오알루민산나트륨 준비 용품 및 원자재

원자재

준비 용품


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