MELIBIOSE

MELIBIOSE 구조식 이미지
카스 번호:
585-99-9
상품명:
MELIBIOSE
동의어(영문):
monohydrate;D-Glucose, 6-O-.alpha.-D-galactopyranosyl-;NSC 2028;MELIBIOSE;Melibiose9;Melibiose-H2O;á-D-Melibiose;MELIBIOSE, D-;alpha-D(+)-Mel;D-(+)-MELIBIOSE
CBNumber:
CB1322130
분자식:
C12H22O11
포뮬러 무게:
342.3
MOL 파일:
585-99-9.mol
MSDS 파일:
SDS

MELIBIOSE 속성

녹는점
182 °C (dec.) (lit.)
알파
+138 - +143° (D/20)(c=1, dil. NH4OH,18hr)(calculated on the dried basis)
끓는 점
774.5±60.0 °C(Predicted)
밀도
1.68±0.1 g/cm3(Predicted)
저장 조건
Sealed in dry,Room Temperature
용해도
H2O: 용해성0.1g/mL, 투명, 무색
물리적 상태
결정성 분말
산도 계수 (pKa)
12.45±0.20(Predicted)
색상
하얀색
optical activity
[α]20/D +137±3°, 10 hr, c = 5% in H2O
수용성
100mg/ml의 물에 불용성
Merck
5820
BRN
93360
안정성
흡습성
LogP
-3.200 (est)
CAS 데이터베이스
585-99-9(CAS DataBase Reference)
EPA
Melibiose (585-99-9)

안전

WGK 독일 3
TSCA Yes
HS 번호 29400090

MELIBIOSE C화학적 특성, 용도, 생산

화학적 성질

White powder

용도

Melibiose has been used in a study to improve the preparation of benzoylated ethyl 1-thioglycosides. It has also been used in a study to investigate the effect of water plasticization on the molecular mobility and crystallization tendency of amorphous disaccharides.

정의

A disaccharide con- sisting of two glucose units in an alpha (1- 6)glycosidic linkage. It is an effector molecule that permits activation of the lac operon by binding to the repressor molecule.

일반 설명

Melibiose is a carbon substrate.

Purification Methods

Melibiose crystallises as a hydrate from water or aqueous EtOH. The anomer is obtained by recrystallising 1g from a mixture of 0.35mL of H2O and 0.2mL of EtOH. It crystallises easily with m 179o and mutarotates from [] D 20 +166o to +142.3o (220minutes, c 4, H2O). Crystallisation from MeOH gives the anhydrous form which hydrates to the monohydrate in air. The anomer dihydrate m 85-86o mutarotates from [] D 20 +123.5o to +143.1o (c 4, H2O for anhydrous). [Fletcher & Diehl J Am Chem Soc 74 5774 1952, Beilstein 1 7 III/IV 3075, 17/7 V 206.]

MELIBIOSE 준비 용품 및 원자재

원자재

준비 용품


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