BIS(TRIMETHYLSILYL)PEROXIDE
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BIS(TRIMETHYLSILYL)PEROXIDE 속성
- 녹는점
- <0°C
- 끓는 점
- 35 °C
- 밀도
- 0.829
- 인화점
- <40°C
- 저장 조건
- below 5° C
- 용해도
- 고졸 비양성자성 유기 용매.
- 물리적 상태
- 무색 용액
- Specific Gravity
- 0.829
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- CAS 데이터베이스
- 5796-98-5
안전
| 위험 카페고리 넘버 | 8-10 | ||
|---|---|---|---|
| 안전지침서 | 17-36/37/39 | ||
| 유엔번호(UN No.) | 3103 | ||
| TSCA | No | ||
| HS 번호 | 29319090 |
BIS(TRIMETHYLSILYL)PEROXIDE C화학적 특성, 용도, 생산
물리적 성질
bp 41°C/30 mmHg;7 n20 D 1.3970.용도
Bis(trimethylsilyl) peroxide (1) functions as an electrophilic hydroxylating agent for aliphatic, aromatic, and heteroaromatic anions.Reaction of their lithium or Grignard compounds with (1) often affords trimethylsiloxy intermediates, which undergo desilylation with HCl in methanol to give the corresponding alcohols in good yields. In the presence of a catalytic amount of trifluoromethanesulfonic acid, (1) reacts with aromatic compounds to produce the corresponding phenols after acidic workup.In these reactions the Me3SiO? moiety is considered as a synthon of the hydroxyl cation (i.e. OH+).
제조 방법
obtained in 80–96% yields by reaction of chlorotrimethylsilane with 1,4-diazabicyclo[2.2.2]octane· (H2O2)2,hexamethylenetetramine·H2O2,or hydrogen peroxide–urea in CH2Cl2.BIS(TRIMETHYLSILYL)PEROXIDE 준비 용품 및 원자재
원자재
준비 용품
BIS(TRIMETHYLSILYL)PEROXIDE 공급 업체
글로벌( 31)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15371 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32480 | 60 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 |
info@antaichem.com | CHINA | 9641 | 58 |
| Chemwill Asia Co.,Ltd. | 86-21-51086038 |
chemwill_asia@126.com | CHINA | 23931 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 |
jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006608290; 18621169109 |
market03@meryer.com | China | 40241 | 62 |
| 3B Pharmachem (Wuhan) International Co.,Ltd. | 821-50328103-801 18930552037 |
3bsc@sina.com | China | 15848 | 69 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 |
Sales-CN@TCIchemicals.com | China | 24539 | 81 |
| Energy Chemical | 021-021-58432009 400-005-6266 |
sales8178@energy-chemical.com | China | 44751 | 61 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 |
Sales-JP@TCIchemicals.com | Japan | 28398 | 80 |