라우릴알코올

라우릴알코올
라우릴알코올 구조식 이미지
카스 번호:
112-53-8
한글명:
라우릴알코올
동의어(한글):
1-히드록시도데칸;도데킬알코올;라우린산알코올;1-도데칸올;1-도데킬알코올;도데칸올;라우르산알코올;라우릴알코올;로릴알코올;페티알콜;라우릴알콜;납;C.I.염료금속4;납플레이크;로릴알코올;1-도데실 알코올;1-도데카놀;1-하이드록시도데케인;n-도데실 알코올;도데실 알코올
상품명:
1-Dodecanol
동의어(영문):
Fatty alcohol;LAURYL ALCOHOL;DODECANOL;dodecyl;lauryl;DODECAN-1-OL;Pisol;Lauric Alcohol;DODECYL ALCOHOL;Lorol
CBNumber:
CB1334632
분자식:
C12H26O
포뮬러 무게:
186.33
MOL 파일:
112-53-8.mol
MSDS 파일:
SDS

라우릴알코올 속성

녹는점
22-26 °C(lit.)
끓는 점
260-262 °C(lit.)
밀도
0.833 g/mL at 25 °C(lit.)
증기 밀도
7.4 (vs air)
증기압
0.1 mm Hg ( 20 °C)
FEMA
2617 | LAURYL ALCOHOL
굴절률
n20/D 1.442(lit.)
인화점
>230 °F
저장 조건
Store below +30°C.
용해도
물: 23°C에서 약간 용해됨1g/L
물리적 상태
액체
산도 계수 (pKa)
15.20±0.10(Predicted)
색상
APHA: ≤10
냄새
전형적인 지방 알코올 냄새; 달콤한.
폭발한계
4%
?? ??
밀랍같은
수용성
불용성
JECFA Number
109
Merck
14,3405
BRN
1738860
Dielectric constant
6.5(24℃)
InChIKey
LQZZUXJYWNFBMV-UHFFFAOYSA-N
LogP
5.4 at 23℃
CAS 데이터베이스
112-53-8(CAS DataBase Reference)
NIST
1-Dodecanol(112-53-8)
EPA
1-Dodecanol (112-53-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,N
위험 카페고리 넘버 38-50-50/53-36/38-36/37/38
안전지침서 61-37/39-29-26-60-36
유엔번호(UN No.) UN 3077 9/PG 3
WGK 독일 1
RTECS 번호 JR5775000
자연 발화 온도 500 °F
TSCA Yes
위험 등급 9
포장분류 III
HS 번호 29051700
유해 물질 데이터 112-53-8(Hazardous Substances Data)
독성 LD50 orally in Rabbit: > 5000 mg/kg
기존화학 물질 KE-12888
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P337+P313 눈에 대한 자극이 지속되면 의학적인 조치· 조언를 구하시오.
P391 누출물을 모으시오.
NFPA 704
1
3 0

라우릴알코올 MSDS


Dodecyl alcohol

라우릴알코올 C화학적 특성, 용도, 생산

물리적 성질

1-Dodecanol is a white low melting crystalline solid that has a melting point of 24°C.The air odor threshold for dodecyl alcohol (isomer not specified) is reported to be 7.1 ppb.

화학적 성질

Lauryl alcohol has a characteristic fatty odor; unpleasant at high concentrations, but delicate and floral on dilution. 1-Dodecanol is a saturated 12-carbon fatty alcohol obtained from coconut oil fatty acids. It has a fatty, waxy flavor and is used in detergents, lubricating oils, and pharmaceuticals.

출처

Reported found in the oil of Mexican lime and in the oil from flowers of Furcraea gigantean. Also reported found in apple, banana, sour cherry, citrus peel oils, melon, pineapple, potato, thymus, cheeses, butter, milk powder, chicken and beef fat, cooked pork, beer, whiskies, white wine, peanuts, beans, mushrooms, mango, coriander seed and leaf, rice, Bourbon vanilla, endive, crab, clam, Cape gooseberry, pawpaw and maté.

용도

1-Dodecanol is used in chemical formulations for a variety of purposes, including as an emulsion stabilizer, a skin-conditioning emollient, and a viscosity-increasing agent.

제조 방법

Commercially 1-Dodecanol may be prepared by hydrogenation of lauric acid; normally employed as a replacement for the corresponding aldehyde.

생산 방법

1-Dodecanol is produced commercially by the oxo process and from ethylene by the Ziegler process, which involves oxidation of trialkylaluminum compounds. It can also be produced by sodium reduction or high-pressure hydrogenation of esters of naturally occurring lauric acid.

정의

ChEBI: 1-Dodecanol is a fatty alcohol that is dodecane in which a hydrogen from one of the methyl groups is replaced by a hydroxy group. It is registered for use in apple and pear orchards as a Lepidopteran pheromone/sex attractant, used to disrupt the mating behaviour of certa n moths whose larvae destroy crops.

일반 설명

Colorless thick liquid with a sweet odor. Floats on water. Freezing point is 75°F.

반응 프로필

Dodecyl alcohol is an alcohol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.

건강위험

Liquid will cause burning of the eyes and may irritate skin.

Safety Profile

Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. A severe human skin irritant. Questionable carcinogen with experimental tumorigenic data. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use dry chemical, CO2. When heated to decomposition it emits acrid smoke and irritating fumes

Carcinogenicity

1-Dodecanol showed weak tumor-promoting activity when applied three times a week for 60 weeks to the skin of mice that had previously received an initiating dose of dimethylbenz[a]anthracene. Papillomas developed in 2 of 30 mice after 39 and 49 weeks of treatment.

Purification Methods

Crystallise dodecanol from aqueous EtOH, and distil it through a spinning-band column under vacuum. [Ford & Marvel Org Synth 10 62 1930, Beilstein 1 IV 1844.]

라우릴알코올 준비 용품 및 원자재

원자재

준비 용품


라우릴알코올 공급 업체

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