4-t-부틸카테콜

4-t-부틸카테콜
4-t-부틸카테콜 구조식 이미지
카스 번호:
98-29-3
한글명:
4-t-부틸카테콜
동의어(한글):
4-t-부틸카테콜;4-삼차부틸카테콜;4-삼차뷰틸카테콜;p-tert-뷰틸피로카테콜;4-tert-부틸피로카테콜;1,2-다이하이드록시-4-tert-뷰틸벤젠;4-(1,1-다이메틸에틸)-1,2-벤젠다이올;4-tert-뷰틸-1,2-다이하이드록시벤젠;4-tert-뷰틸-1,2-벤젠다이올;4-tert-뷰틸카테콜;5-tert-뷰틸카테콜;카테콜, 4-tert-뷰틸-
상품명:
4-tert-Butylcatechol
동의어(영문):
TBC;4-tbc;4-TERT-BUTYL-1,2-BENZENEDIOL;PTBC;4-t-Butylcatechol;P-TERT-BUTYL CATECHOL;4-TERT-BUTYLPYROCATECHOL;T-BUTYL CATECHOL;P-T-BUTYLCATECHOL;p-tert-Butylpyrocatechol
CBNumber:
CB1390571
분자식:
C10H14O2
포뮬러 무게:
166.22
MOL 파일:
98-29-3.mol
MSDS 파일:
SDS

4-t-부틸카테콜 속성

녹는점
52-55 °C(lit.)
끓는 점
285 °C(lit.)
밀도
1.049
증기압
<1 hPa (25 °C)
굴절률
n20/D 1.508
인화점
>230 °F
저장 조건
Store below +30°C.
용해도
메탄올: 가용성 1g/10mL, 투명, 무색~약한 노란색
산도 계수 (pKa)
9.92±0.10(Predicted)
물리적 상태
powder to lump
색상
White to Light yellow to Light red
냄새
10.00?%?in?디프로필렌 글리콜에서. 페놀성
수용성
0.2g/100mL(25℃)
감도
Hygroscopic
BRN
2043335
노출 한도
ACGIH: TWA 5 ppm (Skin)
NIOSH: TWA 5 ppm(20 mg/m3)
InChIKey
XESZUVZBAMCAEJ-UHFFFAOYSA-N
LogP
1.98 at 25℃
CAS 데이터베이스
98-29-3(CAS DataBase Reference)
NIST
1,2-Benzenediol, 4-(1,1-dimethylethyl)-(98-29-3)
EPA
p-tert-Butylcatechol (98-29-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C,N,T
위험 카페고리 넘버 22-34-43-21-51/53-21/22-39/23/24/25-20/21/22-10-50/53
안전지침서 26-36/37/39-45-61-24-60
유엔번호(UN No.) UN 2923 8/PG 3
WGK 독일 2
RTECS 번호 UX1400000
자연 발화 온도 160 °C
TSCA Yes
위험 등급 8
포장분류 III
HS 번호 29072900
독성 LD50 orally in Rabbit: 815 mg/kg LD50 dermal Rat 1331 mg/kg
기존화학 물질 KE-11368
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
2 0

4-t-부틸카테콜 MSDS


4-(1,1-Dimethylethyl)-1,2-benzenediol

4-t-부틸카테콜 C화학적 특성, 용도, 생산

개요

Para-tertiary butyl catechol is specially prepared by reacting the impure catechol fraction with tertiary butyl alcohol. Used for its various properties (inhibition of polymerization and as an antioxidizing agent) in the manufacture of rubber, plastics and paints, in the preparation of petrolatum products, and as an antioxidant in oils, it may induce vitiligo.

화학적 성질

white to cream flakes

용도

Polymerization inhibitor for styrene-butadiene and other olefins.
Inhibitor-remover packings and ready-to-use, disposable prepacked columns offer a quick and convenient means of removing small amounts of inhibitors which are added to reagents or solvents that would otherwise be unstable (e.g., they may polymerize, oxidize or darken) on storage.
The inhibitor removers are useful in applications which require that the stabilizer or inhibitor [i.e., hydroquinone (HQ), hydroquinone monomethyl ether (MEHQ, 4-methoxyphenol) or 4-tert-butylcatechol (TBC)] be removed prior to use.

일반 설명

4-tert-Butylcatechol,in the presence of O2 catalyzed by tyrosinase, yields 4-tert-butyl-o-benzoquinone. Electrochemical oxidation of 4-tert-Butylcatechol in the presence of 4-hydroxycoumarin as nucleophile has been studied using cyclic voltammetry and controlled-potential coulometry. It undergoes electrochemical trimerization via anodic oxidation and mechanism of trimerization has been studied using cyclic voltammetry and controlled-potential coulometry.

위험도

Toxic by ingestion and skin absorption.

색상 색인 번호

p-tert-Butyl catechol is specially prepared by reacting the impure catechol fraction with tertiary butyl alcohol. It is used for its various properties (inhibitor of polymerization and antioxidizing agent) in the manufacture of rubber, plastics, and paints, in the preparation of petrolatum products, and as an antioxidant in oils. It may induce vitiligo.

Safety Profile

A poison by intravenous route. Moderately toxic by ingestion and skin absorption. A severe skin and eye irritant. Mutation data reported. Combustible when exposed to heat or flame. To fight fire, use Con, dry chemical, fog, mist. When heated to decomposition it emits acrid and irritating fumes

Purification Methods

Distil it in a vacuum, then recrystallise it from pentane or pet ether (or *C6H6). [Beilstein

4-t-부틸카테콜 준비 용품 및 원자재

원자재

준비 용품


4-t-부틸카테콜 공급 업체

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