METHYL (1-TRIMETHYLSILYL)ACRYLATE

METHYL (1-TRIMETHYLSILYL)ACRYLATE 구조식 이미지
카스 번호:
18269-31-3
상품명:
METHYL (1-TRIMETHYLSILYL)ACRYLATE
동의어(영문):
Methyl 2-Trimethylsilylacrylate;METHYL (1-TRIMETHYLSILYL)ACRYLATE;2-Propenoic acid, 2-(trimethylsilyl)-, methyl ester
CBNumber:
CB1424461
분자식:
C7H14O2Si
포뮬러 무게:
158.27
MOL 파일:
18269-31-3.mol

METHYL (1-TRIMETHYLSILYL)ACRYLATE 속성

끓는 점
75 °C
밀도
0.888±0.06 g/cm3(Predicted)
용해도
Et2O、THF、EtOH 및 대부분의 유기용매에 용해된다.

안전

METHYL (1-TRIMETHYLSILYL)ACRYLATE C화학적 특성, 용도, 생산

물리적 성질

bp 75 °C/50 mmHg, 152 °C/690 mmHg.

용도

Methyl 2-Trimethylsilylacrylate is widely used as reactive, α-silyl Michael acceptor for conjugate addition of carbanions, enolate anions, organolithium reagents, and Grignard reagents; affords 3-cyclopentenecarboxylates and cyclohexanecarboxylates by [3 + 2] and [4 + 2] annulation methods; provides α-silyl esters and vinylsilanes by organolithium conjugate additions.

제조 방법

Methyl 2-Trimethylsilylacrylate is prepared by the reaction of (E)-2- (trimethylsilyl)vinyllithium with methyl chloroformate or by carbonation of the corresponding Grignard reagent prepared from (1-bromovinyl)trimethylsilane, giving 2-trimethylsilylacrylic acid. The methyl ester is prepared from the acid by direct esterification with absolute methanol in the presence of mineral acid, by reaction with diazomethane at low temperature, or by treatment with BF3·MeOH complex.

METHYL (1-TRIMETHYLSILYL)ACRYLATE 준비 용품 및 원자재

원자재

준비 용품


METHYL (1-TRIMETHYLSILYL)ACRYLATE 공급 업체

글로벌( 5)공급 업체
공급자 전화 이메일 국가 제품 수 이점
Chempro Tech Co., Ltd. --
China 6803 60
Guangzhou WeiBo Chemical Co., Ltd. --
weibochem@163.com China 6187 67
3B Scientific Corporation --
sales@3bsc.com United States 6744 47
Fluorochem Ltd --
vernam@fluorochem.co.uk United Kingdom 6383 65
Fluorochem Ltd. --
enquiries@fluorochem.co.uk United Kingdom 6406 74

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