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(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염

(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염
(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염 구조식 이미지
카스 번호:
22248-79-9
한글명:
(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염
동의어(한글):
(Z)-2-클로로-1-(2,4,5-트라이클로로페닐)바이닐다이메틸인산염;(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐디메틸인산염;(Z)-2-클로로-1-(2,4,5-트라이클로로페닐)바이닐다이메틸인산염((Z)-2-CHLORO-1-(2,4,5-...;테트라클로빈포스
상품명:
Tetrachlorvinphos
동의어(영문):
ROL;CVMP;ipo8;Rabon;Ravap;Appex;Rabond;Vinfos;Gardon;Dust M
CBNumber:
CB1673649
분자식:
C10H9Cl4O4P
포뮬러 무게:
365.96
MOL 파일:
22248-79-9.mol

(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염 속성

녹는점
97-98 °C(lit.)
끓는 점
399.5±42.0 °C(Predicted)
밀도
1.520±0.06 g/cm3(Predicted)
증기압
6.0×10-6 Pa (20 °C)
저장 조건
0-6°C
수용성
11mg l-1(20°C)
물리적 상태
solid
Merck
13,9267
CAS 데이터베이스
22248-79-9(CAS DataBase Reference)
NIST
Tetrachlorvinphos(22248-79-9)
IARC
2B (Vol. 30, Sup 7, 112) 2017
EPA
Tetrachlorvinphos (22248-79-9)

안전

위험품 표기 Xn,N,F
위험 카페고리 넘버 21/22-50/53-36-20/21/22-11-22
안전지침서 36-60-61-36/37-16
유엔번호(UN No.) UN 3077 9/PG 3
RTECS 번호 TB9100000
HS 번호 29199000
유해 물질 데이터 22248-79-9(Hazardous Substances Data)
독성 LD50 in male, female rats (mg/kg): 1100, 1125 orally (Gaines)
기존화학 물질 KE-05920

(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염 MSDS


Tetrachlorvinphos

(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염 C화학적 특성, 용도, 생산

개요

Tetrachlorvinphos was initially registered for use in the United States in 1966 for use on various food crops, livestock, and pet animals, and in around buildings. Its use on food crops were voluntarily canceled in the United States in 1987; however, it is used on food crops in developing countries. Tetrachlorvinphos is sold under the trade names Rabon and Gardona.

화학적 성질

Powder.Partially soluble in chloroform; slightly soluble in water.

화학적 성질

Technical tetrachlorvinphos is a tan-to-brown crystalline solid. Tetrachlorvinphos is stable at ,100 C and slowly hydrolyzed at 50°C. Aromatic odor.
Soluble in water at 24°C 15 ppm; limited solubility in most aromatic hydrocarbons.

용도

Insecticide.

용도

Tetrachlorvinphos is used to control lepidopterous and dipterous larvae in fruit and lepidopterous larvae in cotton, maize, rice, tobacco and vegetables. It is also used against nuisance flies in animal houses, animal ectoparasites and stored product pests.

용도

Tetrachlorvinphos is commonly used as a feed additive to control flies in livestock and as dusts, sprays, dips, and collar ingredient to control ticks and fleas on domestic pets. It is extensively used in poultry. In horses, its formulations are commonly used as a feed additive (feed-through tetrachlorvinphos) larvicide. In addition, tetrachlorvinphos is also used in the control of public health pests, manure flies associated with livestock, and poultry as a feed additive.

위험도

Cholinesterase inhibitor. Questionable carcinogen.

Carcinogenicity

When rats were given diets with 0, 4250, or 8500 ppm tetrachlorvinphos for 80 weeks, both males and females had a high incidence of thyroid C-cell hyperplasia, and females had increased incidences of adrenal cortical adenomas and thyroid C-cell adenomas .

환경귀착

Tetrachlorvinphos is nonpersistent in the environment. The primary route of dissipation is through biotic degradation. Based on its use pattern, risks of contamination of groundwater or surface water by tetrachlorvinphos are minimal.

신진 대사 경로

The chemical structure of tetrachlorvinphos is very close to that of chlorfenvinphos and the routes of metabolic breakdown have been shown to be very similar. Technical tetrachlorvinphos is usually >95% Z-isomer, unlike chlorfenvinphos which is an E/Z mixture. As with chlorfenvinphos, the major routes of detoxification are by dealkylation and hydrolysis to yield desmethyltetrachlorvinphos and 2,2’,4’,5’- tetrachloroacetophenone plus dimethyl phosphate, respectively. Further metabolism of the chloroacetophenone moiety then leads, via reduction or hydrolysis and glutathione-dependent displacement of the side chain chlorine substituent, to the formation of 1-(2,4,5-trichlophenyl) ethane-l,Z-diol and 1-(2,4,5-trichlorophenyl)ethan-l-owl hich are conjugated with glucose or glucuronic acid to afford the ultimate metabolites. Oxidation of the β carbon atom to give 2,4,5-trichloromandelic acid followed by decarboxylation leads to the formation of 2,4,5-trichlorobenzoic acid which is conjugated with glycine in some mammals as the final metabolite. The metabolic routes were summarised by Beynon et al. (1973).

Degradation

Tetrachlorvinphos is hydrolysed slowly in neutral, acidic and slightly alkaline aqueous solutions but hydrolysed rapidly in strongly alkaline solutions to metabolites 3 and 5 (PM). Dureja et al. (1987) reported the photochemical degradation of tetrachlorvinphos in water, ethanol, ether and hexane irradiated with a xenon lamp. In polar solvents, the main product was desmethyltetrachlorvinphos (2), whereas in non-polar solvents such as hexane the reaction yielded dimethyl phosphate (3), 2,4,5-trichloroacet ophenone (4) and 2,2’,4’,5’-tetrachloroacetophenone (5). Interconversion of the Z- and Ε-isomers has been observed on leaves (Beynon and Wright, 1969). These pathways are shown in Scheme 1.

Toxicity evaluation

Acute oral LD50 for rats: 4,000-5,000 mg/kg

(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염 준비 용품 및 원자재

원자재

준비 용품


(Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염 공급 업체

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