리시놀레 산
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리시놀레 산 속성
- 녹는점
- 22.5-24.5℃
- 알파
- D22 +6.67°; D26 +7.15° (c = 5 in acetone)
- 끓는 점
- bp10 245°
- 밀도
- 0.940 g/mL at 20 °C(lit.)
- 굴절률
- 1.4740 (589.3 nm, 25℃)
- 인화점
- 248°C
- 저장 조건
- -20°C
- 용해도
- 에 용해됨에탄올
- 산도 계수 (pKa)
- 4.78±0.10(Predicted)
- 물리적 상태
- 액체
- Specific Gravity
- 0.943 (20/4℃)
- 색상
- Colorless to Red to Green
- optical activity
- [α]/D 6.5±1.5°, c = 2 in acetone
- Merck
- 14,8211
- BRN
- 1727813
- 안정성
- 감광성
- InChIKey
- WBHHMMIMDMUBKC-GKUQOKNUSA-N
- LogP
- 5.607 (est)
- CAS 데이터베이스
- 141-22-0(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xi | ||
---|---|---|---|
위험 카페고리 넘버 | 36/37/38 | ||
안전지침서 | 26-36 | ||
WGK 독일 | 3 | ||
RTECS 번호 | VJ3150000 | ||
HS 번호 | 29181990 | ||
유해 물질 데이터 | 141-22-0(Hazardous Substances Data) | ||
기존화학 물질 | KE-20768 |
리시놀레 산 C화학적 특성, 용도, 생산
개요
Ricinoleic acid is an unsaturated omega-9 fatty acid and is an important component of the seed oil obtained from mature castor plants seeds. The compound is produced for industries by fractional distillation or saponification of hydrolysed castor oil. It is normally used in manufacturing personal care products such as deodorants. Much of ricinoleic acid characteristics and effects can be associated with castor oil.화학적 성질
Ricinoleic acid (synonym castor oil fatty acid) is an unsaturated fatty acid prepared from castor oil. When Ricinoleic acid is pyrolyzed (heated in the absence of air), it breaks down in undecylenic acid and n-heptaldehyde.appearance yellowish, clear, viscous liquid
specific gravity (at 25°C) 0.938 - 0.944
refractive index (at 25°C) 1.4695 - 1.4700
acid value mg KOH/g min.175
iodine value 82 - 90
saponification value mg KOH/g 180 - 190
hydroxyl value 150 - 160
unsaponifiable matter max. 1
colour Gardner max. 7
용도
- soaps: Ricinoleic acid can be reacted with various bases (caustic, ammonia, ethanolamines, etc.) to produce soaps having the desired characteristics (solubility, physical characteristics, polarity, etc.) depending on the final application. Some of them are: cutting oils, industrial lubricants, emulsifiers and metal working fluids. Transparent bar soaps & high solids liquids soaps are made possible by using Ricinoleic acid. The same for industrial germicides, disinfectants and heavy duty detergents (solubilization of phenolic and cresylic bodies).
- surface coating: it is used as an efficient pigment/dye dispersants in inks, coatings, plastics, cosmetics, etc.
- textiles: Ricinoleic acid provides polarity, surface wetting and lubricity.
- rubber: the sodium/potassium soaps of Ricinoleic acid are emulsifiers and foam stabilizers.
- vinyl polymers: it's sodium soap is useful as emulsifier, stabilizer and defoamer for emulsion polymerization of resins such as PVC & PVAc
- food additives: it's used in the production of PGPR (polyglycerol polyricinoleate) for use in chocolate.
정의
ChEBI: Ricinoleic acid is a (9Z)-12-hydroxyoctadec-9-enoic acid in which the 12-hydroxy group has R-configuration. It is a conjugate acid of a ricinoleate. It is a C18 unsaturated fatty acid that comprises 80% of the fatty acid content of castor oil.Carcinogenicity
Four rabbits given intermittent subcutaneous injections of 3120 mg/kg ricinoleic acid for 52 weeks developed subcutaneous neoplasms. The tumorigenic potential of ricinoleic acid injected intravaginally in groups of 20 mice was also studied. No tumors attributable to ricinoleic acid treatment were observed in three studies after 18–20 months.Purification Methods
Purify it as the methyl acetylricinoleate [Rider J Am Chem Soc 53 4130 1931], fractionally distilling it at 180-185o/0.3mm, then 87g of this ester is hydrolysed by refluxing with KOH (56g), water (25mL), and MeOH (250mL) for 10minutes. The free acid is separated on acidification and extracted into Et2O, dried (Na2SO4), filtered, evaporated and the residue is crystallised from acetone at -50o, and distilled in small batches, b 180o/0.005mm. The R-enantiomer has m +5.5o, b 245o/10mm and [] 26D +7.2o (c 5, Me2CO). [Bailey et al. J Chem Soc 3027 1957, Beilstein 3 IV 1026, 1207.]리시놀레 산 준비 용품 및 원자재
원자재
9-Octadecenoic acid, 12-(acetyloxy)-, methyl ester, (9Z)-
아세틸리시놀산메틸에스테르
Ricinelaidicacid
METHYL RICINOLEATE
(R-(Z))-메틸 12-히드록시-9-옥타데켄산염
운데실렌산
에틸알코올
준비 용품
리시놀레 산 공급 업체
글로벌( 337)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12453 | 58 |
Henan Bao Enluo International TradeCo.,LTD | +86-17331933971 +86-17331933971 |
deasea125996@gmail.com | China | 2503 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 7377 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21695 | 55 |
Shanghai Zheyan Biotech Co., Ltd. | 18017610038 |
zheyansh@163.com | CHINA | 3620 | 58 |
career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
Chengdu GLP biotechnology Co Ltd | 028-87075086 13350802083 |
scglp@glp-china.com | CHINA | 1824 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 |
sales@sdzschem.com | China | 2931 | 58 |
Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 |
sales@finerchem.com | China | 2966 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8822 | 58 |
리시놀레 산 관련 검색:
카스토 오일 지방산 부틸 리시노올산염 에틸렌 글리콜 모노리시놀린 산 (R-(Z))-메틸 12-히드록시-9-옥타데켄산염 리시놀레 산 칼슘 리시놀레산 피마자유 오레인산 산화아연 부틸 아세틸 리시놀산 아세틸리시놀산메틸에스테르
Ricinoleic acid isopropyl ester
POLYGLYCERYL-3 POLYRICINOLEATE
Sodium ricinolate
RICINOLEIC ACID ETHYL ESTER,Ricinoleic acid ethyl ester, (R)-12-Hydroxy-cis-9-octadecenoic acid ethyl ester
MAGNESIUM RICINOLEATE
RICINOLEIC ACID CETYL ESTER,RICINOLEIC ACID N-HEXADECYL ESTER,Ricinoleic Acid Hexadecyl Ester
PROPYLENE GLYCOL MONORICINOLEATE