아세토인

아세토인
아세토인 구조식 이미지
카스 번호:
513-86-0
한글명:
아세토인
동의어(한글):
아세토인;아세틸메틸카르비놀;아세틸메틸카르비놀(ACETYLMETHYLCARBINOL);아세틸 메틸 카빈올
상품명:
Acetoin
동의어(영문):
AMC;3-HYDROXY-2-BUTANONE;3-HYDROXYBUTAN-2-ONE;ACETYL METHYL CARBINOL;Acetion;(S)-Acetoin;2-Hydroxy-3-butanone;Natural Acetoin;2-Butanone,3-hydroxy-;3-hydroxyl-2-butanone
CBNumber:
CB2492258
분자식:
C4H8O2
포뮬러 무게:
88.11
MOL 파일:
513-86-0.mol
MSDS 파일:
SDS

아세토인 속성

녹는점
15 °C (monomer)
끓는 점
148 °C(lit.)
밀도
1.013 g/mL at 25 °C(lit.)
증기압
86hPa at 20℃
FEMA
2008 | ACETOIN
굴절률
n20/D 1.417(lit.)
인화점
123 °F
저장 조건
2-8°C
용해도
H2O: 0.1 g/mL, 투명
물리적 상태
액체(단량체) 또는 분말 또는 결정(이량체)
산도 계수 (pKa)
13.21±0.20(Predicted)
색상
연한 노란색에서 녹색 노란색 또는 흰색에서 노란색
냄새
버터 냄새
?? ??
버터 같은
수용성
녹는
Merck
14,64
JECFA Number
405
BRN
385636
안정성
흡습성
InChIKey
ROWKJAVDOGWPAT-UHFFFAOYSA-N
LogP
0.1 at 25℃
CAS 데이터베이스
513-86-0(CAS DataBase Reference)
NIST
2-Butanone, 3-hydroxy-(513-86-0)
EPA
2-Butanone, 3-hydroxy- (513-86-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,F
위험 카페고리 넘버 10-36/38-38-11
안전지침서 26-36-36/37
유엔번호(UN No.) UN 2621 3/PG 3
WGK 독일 1
RTECS 번호 EL8790000
TSCA Yes
위험 등급 3
포장분류 III
HS 번호 29144090
유해 물질 데이터 513-86-0(Hazardous Substances Data)
독성 skn-rbt 500 mg/24H MOD CNREA8 33,3069,73
기존화학 물질 KE-20420
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P233 용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P240 용기와 수용설비를 접지 및 접합시키시오.
P241 폭발 방지용 장비[전기적/환기/조명/...]을(를) 사용하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
2
1 0

아세토인 MSDS


Acetoin

아세토인 C화학적 특성, 용도, 생산

화학적 성질

Acetoin is a yellowish liquid with a bland, woody, yogurt odor and a fatty creamy “tub” butter taste. It is useful as a flavor ingredient in butter, milk, yogurt or strawberry flavors.

출처

Reported found in fresh apple, butter, cheddar cheese, coffee, cocoa, honey, wheat bread and wine

용도

Acetoin is a produced via fermentation of wines, dairy products and sugars by fermentive bacteria. Acetoin is used in food flavoring and fragrances and is also found in some fruits and vegetables.

정의

ChEBI: A methyl ketone that is butan-2-one substituted by a hydroxy group at position 3.

일반 설명

A light-yellow colored liquid. Slightly denser than water. Hence sinks in water. Boiling point 280°F. Flash point between 100 and 141°F. Used to make other chemicals.

공기와 물의 반응

Flammable. Slightly soluble in water.

반응 프로필

3-Hydroxy-2-butanone is a ketone and alcohol. Ketones are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.

건강위험

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.

화재위험

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Experimental reproductive effects. LWdly toxic by subcutaneous route. A moderate skin irritant. Flammable liquid. When heated to decomposition it emits acrid smoke and fumes. See also KETONES

Purification Methods

Wash acetoin with EtOH until colourless, then with diethyl ether or acetone to remove biacetyl. Dry it in air by suction and dry further in a vacuum desiccator. [Beilstein 1 IV 3991.]

아세토인 준비 용품 및 원자재

원자재

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