ChemicalBook
Chinese English Japanese Germany Korea

아조비스이소부티로니트릴

아조비스이소부티로니트릴
아조비스이소부티로니트릴 구조식 이미지
카스 번호:
78-67-1
한글명:
아조비스이소부티로니트릴
동의어(한글):
2,2'-아조비스(아이소뷰티로나이트릴);아조비스이소부티로니트릴;아조디이소부티로니트릴;아조비스이소부티로니트릴;알파,알파'-아조비스이소부틸니트릴;2,2’-아조비스
상품명:
2,2'-Azobis(2-methylpropionitrile)
동의어(영문):
AIBN;AIVN;AZDH;V-60;Vazo;vazo64;chkhz57;Vazo 64;AIBN-64;ChKhZ 57
CBNumber:
CB2494212
분자식:
C8H12N4
포뮬러 무게:
164.21
MOL 파일:
78-67-1.mol

아조비스이소부티로니트릴 속성

녹는점
102-104 °C (dec.)(lit.)
끓는 점
281.68°C (rough estimate)
밀도
1.11
굴절률
n20/D1.495
인화점
4℃
저장 조건
2-8°C
색상
Crystals from EtOH
수용성
Insoluble
Merck
13,920
BRN
1708400
안정성
Stability Flammable solid. Shock sensitive. Thermally unstable. May be explosive in combination with acetone or heptane. Incompatible with oxidizing agents.
InChIKey
OZAIFHULBGXAKX-VAWYXSNFSA-N
CAS 데이터베이스
78-67-1(CAS DataBase Reference)
NIST
2,2'-Azo-bis-isobutyronitrile(78-67-1)
EPA
Azobis(isobutyronitrile) (78-67-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 E,Xn,F,Xi
위험 카페고리 넘버 2-11-20/22-52/53-67-65-48/20-38-63-66-36
안전지침서 39-41-47-61-62-36/37-16-26
유엔번호(UN No.) UN 3234 4.1
WGK 독일 2
RTECS 번호 UG0800000
F 고인화성물질 4.4
위험 등급 4.1
포장분류 II
HS 번호 29269090
유해 물질 데이터 78-67-1(Hazardous Substances Data)
독성 LDLo orl-rat: 670 mg/kg 34ZIAG 0,117,69
기존화학 물질 KE-01998
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H242 가열하면 화재를 일으킬 수 있음 자기반응성 물질 및 혼합물;유기과산화물 형식 C, D,형식 E, F
형식 G
위험
경고
P210, P220, P234, P280, P370+P378,P403+P235, P411, P420, P501
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
H336 졸음 또는 현기증을 일으킬 수 있음 특정표적장기 독성 물질(1회 노출);마취작용 구분 3 경고 P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음 특정 표적장기 독성 - 반복 노출 구분 2 경고 P260, P314, P501
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P220 의류 그리고 가연성 물질로부터 멀리하시오.
P234 원래의 용기에만 보관하시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P281 요구되는 개인 보호구를 착용하시오
P331 토하게 하지 마시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P337+P313 눈에 대한 자극이 지속되면 의학적인 조치· 조언를 구하시오.
P370+P378 화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
P403+P235 환기가 잘 되는 곳에 보관하고 저온으로 유지하시오.
NFPA 704
3
3 3

아조비스이소부티로니트릴 MSDS


Azodiisobutyrodinitrile

아조비스이소부티로니트릴 C화학적 특성, 용도, 생산

용도

정확하게는 2,2'(또는 α, α')-아조비스이소부틸로니트릴이라 한다. mw 164.21 mp 106℃ (분해) 라디칼 중합개시제로서 가장 많이 사용하는 아조화합물인 동시에 폴리염화비닐이다. 폴리스틸렌 등의 분해 발포제로서도 중요하다.

화학적 성질

white solid

화학적 성질

Azobisisobutylonitrile is a white crystalline compound.

용도

Used as an initiator in the synthesis of highly cross-linked Poly(divinylbenzene) (PDVB) polymers. 1 Used as an initiator in the polymerization process of 2-hydroxyethyl methacrylate (HEMA). 2

용도

foaming agent and inhibitor in plastic and elastomer materials

일반 설명

Insoluble in water and denser than water. Moderately toxic by ingestion. Readily ignited by sparks or flames. Burns intensely and persistently. Toxic oxides of nitrogen produced during combustion. Used as a catalyst, in vinyl polymerizations and a blowing agent for plastics.

공기와 물의 반응

Dust may form an explosive mixture in air. Insoluble in water.

반응 프로필

Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. Self-accelerating decomposition may occur if the specific control temperature is not maintained. These materials are particularly sensitive to temperature rises. 2,2'-Azobis(2-methylpropionitrile) is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

위험도

Toxic by ingestion.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. Easily oxidized, unstable. Violent exothermic decomposition when heated. Solution in acetone may decompose explosively. Explodes when heated with heptane. When heated to decomposition it emits toxic fumes of NO, and CN-. See also NITRILES. A free-radcal generator.

잠재적 노출

Azobisisobutylonitrile is both a nitrile and azo compound. Used as a polymerization initiator, free radical generator (or initiator); as a catalyst in vinyl polymerizations; as a blowing agent for elastomers and plastics.

운송 방법

UN3234 Self-reactive solid type C, temperature controlled materials, Hazard Class: 4.1; Labels: 4.1- Flammable solid, Technical Name Required.

비 호환성

Flammable; dust may form explosive mixture with air. Unstable and easily oxidized material; keep away from oxidizers, strong acids. Keep at temperature not ≧30° C (this may vary by manufacturer). Risk of explosion from heat, shock, friction. Warming causes production of tetramethylsuccinonitrile and cyanide fumes. Keep away from acetone and other ketones, alcohols, lithium, aluminum, aldehydes, and hydrocarbons, such as heptane. Azo compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. This chemical is sensitive to prolonged exposure to heat. This chemical is incompatible with strong oxidizing agents.

아조비스이소부티로니트릴 준비 용품 및 원자재

원자재

준비 용품

4-[4-(BROMOMETHYL)PHENYL]-1,2,3-THIADIAZOLE 다이클로로아세틸 염화물 super absorbent resin synthesized by microwave cation ion radiation 4-(PIPERIDINE-1-CARBONYL)PHENYLBORONIC ACID 2,1,3-Benzothiadiazol-5-ylmethanol 4-(2-CYANOETHYLAMINOCARBONYL)PHENYLBORONIC ACID 디디아이 2,1,3-Benzothiadiazole-5-carbaldehyde 3-(2-CYANOETHYLAMINOCARBONYL)PHENYLBORONIC ACID graft copolymer PAA-G-PIPA microsphere 2-(Bromomethyl)benzoic acid 2,6-디클로로벤즈알데히드 5-Dibenzosuberenone 2-(DIPHENYLPHOSPHINO)ETHYLTRIETHOXYSILANE 프탈라이드 4-Benzofurazancarboxaldehyde 2-TRIFLUOROMETHYLQUINOLINE-7-CARBOXYLIC ACID 4-(1,2,3-THIADIAZOL-4-YL)BENZALDEHYDE a new kind of liquid crystal copolymer 3,7-dichloro-8-dichloro methyl quinoline METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE 1-(3-CHLORO-4-((CYCLOPROPYLAMINO)METHYL)PHENYL)ETHANONE 3-QUINOLIN-2-YLPROPANOIC ACID 4-(1,2,3-THIADIAZOL-4-YL)BENZYLAMINE HYDROCHLORIDE o-클로로벤질클로라이드 Maleic acid-allyl alcohol copolymer dimethylacrolyl phenoxy propanestyrene copolymer optical plastics METHYL ALPHA-BROMO-2-CHLOROPHENYLACETATE 5-(BROMOMETHYL)-2,1,3-BENZOTHIADIAZOLE amphoteric super absorbent resin synthesized by microwave radiation 켈테인 3-PHENOXYPHENYLACETONITRILE 3-CHLORO-4-((CYCLOPROPYLAMINO)METHYL)BENZALDEHYDE 11-Bromoundecanoic acid 데플라자코르트 3-(PIPERIDINOMETHYL)BENZALDEHYDE 2-Nitroacetophenone 2,4-Dichlorobenzyl chloride 2-Nitrobenzyl bromide 4-(PYRROLIDIN-1-YLMETHYL)BENZENEBORONIC ACID, PINACOL ESTER 97%1-[4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZYL]PYRROLIDINE

아조비스이소부티로니트릴 공급 업체

글로벌( 370)공급 업체
공급자 전화 팩스 이메일 국가 제품 수 이점
Dayang Chem (Hangzhou) Co.,Ltd.
17705817739 +86-571-88938639
+86-571-88938652,+86-571- 88492614 info@dycnchem.com CHINA 52932 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58
Jinan Qinmu Fine Chemical Co.,Ltd.
18660799346 18363098612
+86 531 8316 6650 sales@qinmuchem.com CHINA 1009 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503282
alice@crovellbio.com China 5941 58
Shanghai Yunao International Trade Co., Ltd
+8617621705551 +86-021-17621705551
sarahwillbe@shanghaihg.cn China 277 58
Capot Chemical Co.,Ltd.
+86(0)13336195806 +86-571-85586718
+86-571-85864795 sales@capotchem.com China 20012 60
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 15419 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com China 22607 55
Shanghai Time Chemicals CO., Ltd.
+8618017249410 +86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com China 1807 55
Hangzhou FandaChem Co.,Ltd.
008615858145714
+86-571-56059825 fandachem@gmail.com China 9156 55

아조비스이소부티로니트릴 관련 검색:

Copyright 2019 © ChemicalBook. All rights reserved