(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03

(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 구조식 이미지
카스 번호:
72952-73-9
상품명:
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03
동의어(영문):
Pentadienyltrimethylsilane;5-(Trimethylsilyl)-1,3-pentadiene;trimethyl(penta-2,4-dienyl)silane;Silane, trimethyl(2E)-2,4-pentadien-1-yl-;(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03
CBNumber:
CB2502210
분자식:
C8H16Si
포뮬러 무게:
140.3
MOL 파일:
72952-73-9.mol

(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 속성

끓는 점
127°C
밀도
0.758±0.06 g/cm3(Predicted)
인화점
18°C
용해도
헥산, 벤젠, CH2Cl2, 에테르, THF에 용해됨

안전

위험 카페고리 넘버 11-36/37/38
안전지침서 16-26-36
유엔번호(UN No.) 1993

(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 C화학적 특성, 용도, 생산

물리적 성질

bp 41 °C/36 mmHg or 105 °C/760 mmHg; n20/ D 1.4570.

용도

5-Trimethylsilyl-1,3-pentadiene is a useful pentadienylation reagent; an allyl silane; a precursor for 1-trimethylsilyldienes and intramolecular Diels–Alder substrates).

제조 방법

5-Trimethylsilyl-1,3-pentadiene may be prepared in 85% yield by the reaction of pentadienyllithium with chlorotrimethylsilane in THF at room temperature.1–3 Generally the product is ≈95% (E) isomer as judged by IR (strong band at 1000 cm?1) or NMR(trans coupling constant of 15.2 Hz for proton at C-3, 5.92 ppm).

(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 준비 용품 및 원자재

원자재

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