다이에틸렌트라이아민

다이에틸렌트라이아민
다이에틸렌트라이아민 구조식 이미지
카스 번호:
111-40-0
한글명:
다이에틸렌트라이아민
동의어(한글):
1,4,7-트리아자헵탄;2,2-디아미노디에틸아민;2,2-이미노비스(에탄아민);N-(2-아미노에틸)-1,2-에탄디아민;N-(2-아미노에틸)에틸렌디아민;비스(2-아미노에틸)아민;비스(베타-아미노에틸)아민;1,2-에탄디아민,N-(2-아미노에틸)-;다이에틸렌트라이아민;디에틸렌트리아민;디에틸렌트리아민(DETA);디에틸렌트리아민;1,4,7-트라이아자헵탄;2,2'-다이아미노다이에틸아민;2,2'-다이아미노에틸아민;2,2'-이미노다이에틸아민;2,2'-이미노비스(에탄아민);3-아자-1,5-펜탄다이아민;ChS-P 1 DETA;N-(2-아미노에틸)에틸렌다이아민
상품명:
Diethylenetriamine
동의어(영문):
DETA;N1-(2-aMinoethyl)ethane-1,2-diaMine;DIEN;DETA Diethylenetriamine;DIETHYLENTRIAMINE;BIS(2-AMINOETHYL)AMINE;diethylenetriamine(deta);1,2-Ethanediamine,N-(2-aminoethyl)-;Diethylenetriamin;3-Azapentane-1,5-diamine
CBNumber:
CB2852838
분자식:
C4H13N3
포뮬러 무게:
103.17
MOL 파일:
111-40-0.mol
MSDS 파일:
SDS

다이에틸렌트라이아민 속성

녹는점
-40 °C
끓는 점
206 °C
밀도
0.955 g/mL at 25 °C(lit.)
증기 밀도
3.6 (vs air)
증기압
0.08 mm Hg ( 20 °C)
굴절률
n20/D 1.484(lit.)
인화점
90 °C
저장 조건
Store below +30°C.
용해도
클로로포름, 메탄올(약간)에 용해됨
물리적 상태
액체
산도 계수 (pKa)
pK1:4.42(+3);pK2:9.21(+2);pK3:10.02(+1) (25°C)
색상
투명한
냄새
강한 암모니아성; 약하게 암모니아성.
수소이온지수(pH)
>12 (100g/l, H2O, 20℃)
폭발한계
1-10%(V)
수용성
혼용 가능
감도
Air Sensitive
BRN
605314
노출 한도
ACGIH: TWA 1 ppm (Skin)
NIOSH: TWA 1 ppm(4 mg/m3)
안정성
안정적이지만 공기 중 이산화탄소를 흡수합니다. 강한 산화제, 구리 및 그 합금과 호환되지 않습니다.
InChIKey
RPNUMPOLZDHAAY-UHFFFAOYSA-N
LogP
-1.58 at 20℃
CAS 데이터베이스
111-40-0(CAS DataBase Reference)
NIST
1,2-Ethanediamine, N-(2-aminoethyl)-(111-40-0)
EPA
Diethylenetriamine (111-40-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C,T+
위험 카페고리 넘버 21/22-34-43-37-26
안전지침서 26-36/37/39-45-28
유엔번호(UN No.) UN 2079 8/PG 2
WGK 독일 2
RTECS 번호 IE1225000
자연 발화 온도 676 °F
TSCA Yes
위험 등급 8
포장분류 II
HS 번호 29212900
유해 물질 데이터 111-40-0(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 1540 mg/kg
기존화학 물질 KE-01357
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H330 흡입하면 치명적임 급성 독성 물질 흡입 구분 1, 2 위험 GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
3 0

다이에틸렌트라이아민 MSDS


DETA

다이에틸렌트라이아민 C화학적 특성, 용도, 생산

용도

디 에틸렌 트리 아민 (DETA)은 종이 습식 강도 수지, 부식 방지제, 연료 첨가제, 에폭시 경화제, 섬유 유연제 및 아스팔트 첨가제의 제조에 일반적으로 사용됩니다.

개요

Diethylenetriamine is a hardener in epoxy resins of the Bisphenol A type. It has been reported as a sensitizer in ultrasonic baths for cleaning jewels, in synthetic lubricants and in carbonless copy paper.

화학적 성질

Diethylenetriamine is a corrosive yellow liquid and a solvent. It has a strong ammonia odor and is prone to absorbing moisture. It can dissolve in water, acetone, benzene, ether, methanol, but is not soluble in n-heptane.

생산 방법

Diethylenetriamine is produced by the reaction of ethylene dichloride with ammonia. Diethylenetriamine is used in biological studies, for polyamines inhibition to carbonic anhydrases by anchoring to the zinc-coordinated water molecule.

일반 설명

A yellow liquid with an ammonia-like odor. Less dense than water. Corrosive to metals and tissue. Vapors heavier than air. Burns, although possibly difficult to igntie. Toxic oxides of nitrogen produced during combustion. Used as a solvent for plastics and dyes and in chemical synthesis.

공기와 물의 반응

Soluble in water.

반응 프로필

Diethylenetriamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

건강위험

Brief contact with concentrated diethylenetriamine can produce severe local injury to the eyes and skin resembling the effect from strong base. Human subjects are susceptible to sensitization responses either as dermatitis or an asthma-like response. A time-weighted average of 1 p.p.m. is recommenced for diethylenetriamine (ACGIH 1986).

화재위험

Special Hazards of Combustion Products: Irritating vapors are generated when heated.

공업 용도

Diethylenetriamine is used as an intermediate in the production of reactive polyamide resins, and in the production of aminoamides and imidazolines from fatty acids. It is also used in the production of paper wet strength resins and piperazine. Diethylenetriamine serves as a solvent for sulfur, acid gases, resins and dyes (HSDB 1989).

색상 색인 번호

Diethylenetriamine is a hardener in epoxy resins of the Bisphenol A type. It has been reported to be a sensitizer when used in an ultrasonic bath for cleaning jewels, in synthetic lubricants, or in carbonless copy paper.

Safety Profile

Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion. Corrosive. A severe skin and eye irritant. High concentration of vapors causes irritation of respiratory tract, nausea, and vomiting. Repeated exposures can cause asthma and sensitization of skin. Combus uble when exposed to heat or flame; can react with oxidizing materials. Mxture with nitromethane is a shock-sensitive explosive. Ignites on contact with cellulose nitrate of high surface area. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.

Carcinogenicity

DETA has a strong ammonia-like odor, but it does not provide adequate warning of hazardous concentrations.
The 2003 ACGIH threshold limit valuetime- weighted average (TLV-TWA) for diethylene triamine is 1ppm (4.2mg/m3) with a notation for skin absorption.

신진 대사

Diethylenetriamine is readily absorbed through the gastrointestinal tract and 96% of the administered dose is excreted within 48 h (USEPA 1983a). Roughly equal amounts are excreted in the feces and urine with at least 4 metabolites being detected (but not identified) in the latter. Only a small proportion (<2%) was recovered as expired carbon dioxide. Any residual remaining in the animal was found primarily in kidney, liver, bladder and large intestine.

Purification Methods

Dry the amine with Na and distil, preferably under reduced pressure, or in a stream of N2. [Beilstein 4 IV 1284.]

다이에틸렌트라이아민 준비 용품 및 원자재

원자재

준비 용품


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