1-브로모헥사데칸

1-브로모헥사데칸
1-브로모헥사데칸 구조식 이미지
카스 번호:
112-82-3
한글명:
1-브로모헥사데칸
동의어(한글):
1-브로모헥사데칸;브로민화세틸(브롬화세틸);세틸브롬화물;1-브로모헥사데케인;브로민화세틸(브롬화세틸)
상품명:
1-Bromohexadecane
동의어(영문):
CETYL BROMIDE;1-Bromhexadecan;BROMOHEXADECANE;Hexadecylbromid;Palmitylbromide;1-BROMOHEXADECANE;HEXADECYL BROMIDE;1-bromo-hexadecan;1-HEXADECYL BROMIDE;N-HEXADECYL BROMIDE
CBNumber:
CB3211988
분자식:
C16H33Br
포뮬러 무게:
305.34
MOL 파일:
112-82-3.mol
MSDS 파일:
SDS

1-브로모헥사데칸 속성

녹는점
16-18 °C(lit.)
끓는 점
190 °C11 mm Hg(lit.)
밀도
0.999 g/mL at 25 °C(lit.)
증기 밀도
10.6 (vs air)
증기압
<1 mm Hg ( 20 °C)
굴절률
n20/D 1.4609(lit.)
인화점
>230 °F
저장 조건
Inert atmosphere,Room Temperature
용해도
혼합하기가 어렵습니다.
물리적 상태
녹은 후에 액체
색상
투명한 호박색에서 갈색-검정색까지
Specific Gravity
1.000 (20/4℃)
수용성
불용성
BRN
773989
Dielectric constant
3.71
안정성
안정적인. 강한 산화제와 호환되지 않습니다. 타기 쉬운.
InChIKey
HNTGIJLWHDPAFN-UHFFFAOYSA-N
LogP
8.54
CAS 데이터베이스
112-82-3(CAS DataBase Reference)
NIST
Hexadecane, 1-bromo-(112-82-3)
EPA
Hexadecane, 1-bromo- (112-82-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 26-36
WGK 독일 3
TSCA Yes
HS 번호 29033036
기존화학 물질 KE-03673
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
예방조치문구:
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
NFPA 704
0
0 0

1-브로모헥사데칸 MSDS


1-Bromohexadecane

1-브로모헥사데칸 C화학적 특성, 용도, 생산

화학적 성질

colourless to yellow liquid or solid.soluble in ether, alcohol, insoluble in water.

용도

1-Bromohexadecane is used in the preparation of soluble carbon nano-onions by covalent functionalization with hexadecyl chains. It is also used to synthesize [2-(methacryloyloxy)ethyl]dimethylhexadecylammonium bromide monomer, required for the synthesis of novel methacrylate based adsorbents.

용도

1-Bromohexadecane has been used:
in the preparation of soluble carbon nano-onions by covalent functionalization with hexadecyl chains
as extraction solvent in determination of endocrine-disrupting phenols (EDPs) in water samples by ultrasound-assisted emulsification microextraction (MS-USAEME) method
in the preparation of [2-(methacryloyloxy)ethyl]dimethylhexadecylammonium bromide monomer, required for the synthesis of novel methacrylate based adsorbents
in the synthesis of surfactant, N-hexadecyl ethylenediamine triacetic acid (HED3A)

제조 방법

Synthesis of 1-Bromohexadecane from hexadecanol by bromination: put hexadecanol into the reaction pot and stir, heat, melt and put in red phosphorus. Add bromine drop by drop at 100℃ with sufficient stirring on one side, control 120-130℃, about 6h drop by drop, continue the reaction and drain the hydrogen bromide. Cool to below 50 ℃, add saturated and sodium chloride, stirring and washing, resting stratification, parting off the lower waste stream, then wash with water to neutral, distillation, collect 220-230 ℃ (2kPa) fraction, to obtain 1-bromohexadecane.

Purification Methods

Shake the bromide with H2SO4, wash with H2O, dry with K2CO3 and fractionally distil it in vacuo.[Beilstein 1 IV 542.]

1-브로모헥사데칸 준비 용품 및 원자재

원자재

준비 용품


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