갈륨 트리클로리드

갈륨 트리클로리드
갈륨 트리클로리드 구조식 이미지
카스 번호:
13450-90-3
한글명:
갈륨 트리클로리드
동의어(한글):
갈륨트리클로리드;갈륨트리클로리드;삼염화 갈륨;염화 갈륨;염화 갈륨 (GaCl3);염화 갈륨(III);트라이클로로갈레인
상품명:
GALLIUM(III) CHLORIDE
동의어(영문):
GaCl3;Nsc94002;granular;Wln: ga G3;gallium(iii);ium(III) chL;Trichlorogallium;GALLIUM CHLORIDE;trichlorogallane;GalliuM trchloride
CBNumber:
CB3275575
분자식:
Cl3Ga
포뮬러 무게:
176.08
MOL 파일:
13450-90-3.mol

갈륨 트리클로리드 속성

녹는점
78 °C(lit.)
끓는 점
35 °C
밀도
2.47 g/mL at 25 °C(lit.)
증기압
1 mm Hg ( 48 °C)
인화점
−26 °F
물리적 상태
염주
색상
하얀색
Specific Gravity
2.47
수용성
물에 매우 잘 녹습니다. 벤젠, 사염화탄소 및 이황화탄소에 용해됨
감도
Moisture Sensitive
Merck
14,4348
안정성
안정적이지만 물과 격렬하게 반응합니다.
InChIKey
UPWPDUACHOATKO-UHFFFAOYSA-K
CAS 데이터베이스
13450-90-3(CAS DataBase Reference)
EPA
Gallium trichloride (13450-90-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C,N,F+
위험 카페고리 넘버 14-34-51/53-12-67-65
안전지침서 26-27-28-36/37/39-45-61-33-29-16-62
유엔번호(UN No.) UN 3260 8/PG 2
WGK 독일 3
RTECS 번호 LW9100000
F 고인화성물질 3-10
TSCA Yes
위험 등급 8
포장분류 II
HS 번호 28273990
유해 물질 데이터 13450-90-3(Hazardous Substances Data)
기존화학 물질 KE-17443
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P310 즉시 의료기관(의사)의 진찰을 받으시오. 삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.
NFPA 704
0
3 1

갈륨 트리클로리드 C화학적 특성, 용도, 생산

화학적 성질

white crystals or powder

용도

Gallium(III) chloride is a catalyst for a number of transformations including the ring opening and recyclization of epoxides and the trimerization of alkynes. It is used to detect the solar neutrions.

생산 방법

The trichloride salt of trivalent gallium is prepared by the action of either hydrogen chloride or chlorine on the metal.

일반 설명

Colorless needles. Used as a raw material in the production of metallic gallium and in the processing of mono crystal semiconductor compounds.

공기와 물의 반응

Water soluble.

반응 프로필

GALLIUM(III) CHLORIDE acts as a weak inorganic acid. Materials in this group are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

건강위험

(Non-Specific -- Gallium Compounds) In view of the toxicity of gallium and its compounds, as shown by experiments, all persons involved in work with these substances should undergo periodic medical examinations, during which special attention should be paid to the condition of the liver, respiratory organs, and skin.

화재위험

Emits toxic chloride fumes when heated to decomposition. Decomposes upon sufficient heating.

잠재적 노출

Used as a raw material in the produc tion of metallic gallium; and in the processing of mono crystal, semiconductor compounds.

운송 방법

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN1759 Corrosive solids, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name required.

Purification Methods

The pure compound can be obtained by redistillation in a stream of Cl2 or Cl2/N2 followed by vacuum sublimation or zone refining. It forms colourless needles which give gallium dichloride [Ga(GaCl4), m 172.4o] on heating. It dissolves in H2O with liberation of heat. It is soluble in Et2O and can be extracted from an HCl solution with Et2O. [Laubengayer & Schirmer J Am Chem Soc 62 1579 1940, D.nges in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 846 1963.]

갈륨 트리클로리드 준비 용품 및 원자재

원자재

준비 용품


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