1H,1H,2H,2H-Perfluorooctanesulfonic acid

1H,1H,2H,2H-Perfluorooctanesulfonic acid 구조식 이미지
카스 번호:
27619-97-2
상품명:
1H,1H,2H,2H-Perfluorooctanesulfonic acid
동의어(영문):
Perfluorohexyl ethyl sulfonic acid;Perfluorohexyl Ethyl sulphonic acid;3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctanesulphonic acid;perfluorohexyl ethyl sulfonate;(1H,1H,2H,2H)-Perfluorooctanesulfonic];2-(Perfluorohexyl)ethane-1-sulfonic acid;1H,1H,2H,2H-PERFLUOROOCTANESULFONIC ACID;2-(Perfluorohexyl)ethane-0-sulfonic acid;2-(Tridecafluorohexyl)ethanesulfonic acid;1H,1H,2H,2H-PERFLUOROOCTANESULPHONIC ACID
CBNumber:
CB3467468
분자식:
C8H5F13O3S
포뮬러 무게:
428.17
MOL 파일:
27619-97-2.mol
MSDS 파일:
SDS

1H,1H,2H,2H-Perfluorooctanesulfonic acid 속성

밀도
1,25 g/cm3
증기압
1.96Pa at 20℃
용해도
Acetone: Slightly soluble,Chloroform: Slightly soluble,DMSO: Slightly soluble,Methanol: Slightly soluble
물리적 상태
A low-melting solid
산도 계수 (pKa)
1.31±0.50(Predicted)
수용성
658g/L at 20℃
InChI
InChI=1S/C8H5F13O3S/c9-3(10,1-2-25(22,23)24)4(11,12)5(13,14)6(15,16)7(17,18)8(19,20)21/h1-2H2,(H,22,23,24)
InChIKey
VIONGDJUYAYOPU-UHFFFAOYSA-N
SMILES
C(S(O)(=O)=O)CC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
EPA
1-Octanesulfonic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro- (27619-97-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C,Xi
위험 카페고리 넘버 34
안전지침서 26-36/37/39-45
유엔번호(UN No.) 3265
위험 참고 사항 Corrosive
위험 등급 IRRITANT, CORROSIVE
HS 번호 2904990090
기존화학 물질 2015-3-6285
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
NFPA 704
0
3 0

1H,1H,2H,2H-Perfluorooctanesulfonic acid C화학적 특성, 용도, 생산

개요

1H,1H,2H,2H-Perfluorooctanesulfonic acid is an efficient fluorine-containing surfactant without perfluorooctane sulfonic acid, which has the characteristics of high temperature resistance, oxidant resistance, electrolytic stability, etc. It can reduce the concentration of chromic acid in plating workshop and inhibit the precipitation of chromic acid and chromium mist.

화학적 성질

White to Brown Solid.

용도

1H,1H,2H,2H-Perfluorooctanesulfonic acid is an aliphatic compound for fluorinated surfactant synthesis.

주요 응용

1H,1H,2H,2H-Perfluorooctanesulfonic acid can functionalize gallium nitride (GaN) to tune the optical properties, which can potentially be used in chemical sensor based applications. It can modify the surface characteristics of copper substrates that find usage in printed circuit boards as copper foils. It can also be coated on the indium tin oxide substrate, which may be utilized in organic light emitting diodes (OLEDs) and organic photovoltaics (OPVs).

일반 설명

1H,1H,2H,2H-Perfluorooctanesulfonic acid is a fluoroalkyl phosphonic acid that contains 8 fluorinated carbon atoms. It forms a self-assembled layer on the substrate due to the adhesion of the phosphonates. The surface adhesion is a component of the acid base linkage that is enhanced by the hydroxyl groups.

Toxicology

Toxicological studies of 1H,1H,2H,2H-Perfluorooctanesulfonic acid (6:2 FTS) induced cardiovascular abnormalities in zebrafish embryos and larvae showed that the acute toxicity of 6:2 FTS was lower than that of PFOS. 6:2 FTS could affect the development of zebrafish, including increasing the utilization of yolk sac and the length of the pharyngeal pouch, leading to pericardial edema and inhibiting beating of the heart. Then transgenic zebrafish CZ63 and CZ40 were used to further explore its cardiovascular toxicity. 6:2 FTS could induce vascular hyperplasia, inhibit atrial development, and reduce blood flow velocity in larvae at 72 hours postfertilization. In addition, 6:2 FTS enhanced CAT and GSH-Px activities, involved in calcium signalling and myocardial contraction, and affected MAPK, FoxO and p53 signalling pathways[3].

저장

2-8°C

Environmental considerations

Regulatory efforts are underway to limit the use of some Fluorinated additive material, mainly perfluorinated compounds (PFCs), due to concerns over their environmental persistency, bioaccumulation ability, and toxicity. Among the PFCs, perfluorosulfonates (PFSAs) and perfluorocarboxylates (PFCAs) are most widely detected in human and other biological samples, including those in pristine areas such as the Arctic. The longer-chained PFCs are known to be bioaccumulative and have toxic effects on biota. For example, neuroendocrine effects and peroxisome proliferation have been shown to occur. The perfluorinated sulfonamides are neutral compounds and are consequently not as water-soluble as the acids and are more volatile. It has been suggested that they are transformed into perfluorinated sulfonates (PFSAs) and PFCAs in the atmosphere. Since the perfluorinated acids have high water solubilities and low pKa values, they are dissociated at environmentally relevant pH values. They are primarily found in water or bound to particles, sediments, and soils[1-2].

1H,1H,2H,2H-Perfluorooctanesulfonic acid 준비 용품 및 원자재

원자재

준비 용품


1H,1H,2H,2H-Perfluorooctanesulfonic acid 공급 업체

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