2,3-디클로로-1,4-나프토퀴논

2,3-디클로로-1,4-나프토퀴논
2,3-디클로로-1,4-나프토퀴논 구조식 이미지
카스 번호:
117-80-6
한글명:
2,3-디클로로-1,4-나프토퀴논
동의어(한글):
2,3-디클로로-1,4-나프토퀴논;디클로로-α-나프토퀴논;디클론;디클론(DICHLONE)
상품명:
2,3-Dichloro-1,4-naphthoquinone
동의어(영문):
CNQ;usr604;Phygon;Quintar;DICHLON;USR 604;ent3776;Diclone;DICHLONE;Uniroyal
CBNumber:
CB3469109
분자식:
C10H4Cl2O2
포뮬러 무게:
227.04
MOL 파일:
117-80-6.mol
MSDS 파일:
SDS

2,3-디클로로-1,4-나프토퀴논 속성

녹는점
194-197 °C (lit.)
끓는 점
275 °C (2 mmHg)
밀도
1.4057 (rough estimate)
증기압
0Pa at 20℃
굴절률
1.5410 (estimate)
인화점
275°C/2mm
저장 조건
Store below +30°C.
물리적 상태
미세 결정성 분말
색상
노란색
수용성
0.008g/L
Merck
14,3045
BRN
1073511
LogP
2.9 at 23℃
CAS 데이터베이스
117-80-6(CAS DataBase Reference)
NIST
1,4-Naphthalenedione, 2,3-dichloro-(117-80-6)
EPA
Dichlone (117-80-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N
위험 카페고리 넘버 22-36/38-50/53
안전지침서 26-60-61
유엔번호(UN No.) UN 2811 6.1/PG 3
WGK 독일 3
RTECS 번호 QL7525000
TSCA Yes
위험 등급 6.1
포장분류 III
HS 번호 29147090
유해 물질 데이터 117-80-6(Hazardous Substances Data)
독성 LD50 orally in rats: 1300 mg/kg (Bailey, White)
기존화학 물질 KE-10157
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273 환경으로 배출하지 마시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
2 0

2,3-디클로로-1,4-나프토퀴논 MSDS


2,3-Dichloro-1,4-naphthoquinone

2,3-디클로로-1,4-나프토퀴논 C화학적 특성, 용도, 생산

화학적 성질

YELLOW FINE CRYSTALLINE POWDER

용도

Fungicide for agriculture and textiles; herbicide.

일반 설명

2,3-Dichloro-1,4-naphthoquinone is a yellow crystalline solid dissolved in a water-emulsifiable liquid carrier. Can cause illness by inhalation, skin absorption and/or ingestion. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Can easily penetrate the soil and contaminate groundwater and nearby streams. Used as a fungicide.

공기와 물의 반응

Insoluble in water.

반응 프로필

2,3-Dichloro-1,4-naphthoquinone is a halogenated ketone. Ketones are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.

건강위험

INHALATION: Irritation to mucous membrane. EYES: Irritation. SKIN: Irritation. INGESTION: Can cause CNS depression.

화재위험

Special Hazards of Combustion Products: Highly toxic fumes are imminent.

농업용

Fungicide: Not currently registered in the U.S. Not approved for use in the EU. Dichlone is used as a fungicide for foliage and to control blue algae in ponds, swimming pools and lakes. As a substitute for copper and sulfur to control rot on fruit trees, vegetables, field crops, ornamentals, resident and commercial outdoor areas.

상품명

ALGISTAT®; COMPOUND 604®; PHYGON®; PHYGON® PASTE; PHYGON® SEED PROTECTANT; PHYGON® XL; QUINTAR®; QUINTAR® 540F; SANQUINON®; UNIROYAL® 604; USR® 604; U.S. RUBBER® 604

Safety Profile

Poison by ingestion and intraperitoneal routes. Mildly toxic by skin contact. A skin, eye, and mucous membrane irritant. Large doses can cause central nervous system depression. Questionable carcinogen with experimental carcinogenic and neoplastigenic data. A fungcide and algicide. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORIDES.

환경귀착

Plant. In plants, dichlone loses both chlorine atoms and are replaced by sulphydryl groups to give a substituted dimercapto compound (Hartley and Kidd, 1987).
Photolytic. The UV absorption band for dichlone is 330 nm (Gore et al., 1971). Irradiation of dichlone in a variety of organic solvents (benzene, isopropanol, ethanol) using UV light produced a number of dehalogenated compounds. In the absence or presence of oxygen, 2-chloro-1,4-naphthoquinone, 1,4-naphthoquinone and 1,4-naphthalenediol were produced. Further irradiation in the presence of oxygen yielded phthalic acid and phthalic anhydride as the major products. In a mixture of benzene and isopropanol, dichlone degraded to the minor products: 2-chloro-3-hydroxy-1,4-naphthoquinone, 2- chloro-3-phenoxy-1,4-naphthoquinone, 2,3-dichloro-4-hydroxy-1-keto-2-phenyl-1,2- dihydronaphthalene and isopropyl-1-chloro-2,3-dioxo-1-indanecarboxylate (Ide et al., 1979).
Chemical/Physical. Emits toxic fumes of chlorine when heated to decomposition (Sax and Lewis, 1987).

Purification Methods

Crystallise the quinone from EtOH. [Beilstein 7 IV 2426.]

2,3-디클로로-1,4-나프토퀴논 준비 용품 및 원자재

원자재

준비 용품


2,3-디클로로-1,4-나프토퀴논 공급 업체

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Alchem Pharmtech,Inc.
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