디메틸클로로실란

디메틸클로로실란
디메틸클로로실란 구조식 이미지
카스 번호:
1066-35-9
한글명:
디메틸클로로실란
동의어(한글):
디메틸클로로실란;클로로디메틸실란;클로로다이메틸실레인
상품명:
Chlorodimethylsilane
동의어(영문):
DMCS;DMSC;DIMETHYLCHLOROSILANE;Chlorodimethylhydrosilane;CD5470;CFS-359;orodimethyL;JACS-1066-35-9;Co-Formula CFS-359;Dimethylchlorsilane
CBNumber:
CB3694606
분자식:
C2H7ClSi
포뮬러 무게:
94.62
MOL 파일:
1066-35-9.mol

디메틸클로로실란 속성

녹는점
−111 °C(lit.)
끓는 점
34.7 °C(lit.)
밀도
0.852 g/mL at 25 °C(lit.)
증기 밀도
4 (vs air)
증기압
8.56 psi ( 20 °C)
굴절률
n20/D 1.383(lit.)
인화점
−20 °F
저장 조건
2-8°C
용해도
유기용매와 섞일 수 있음.
물리적 상태
액체
색상
무색의
Specific Gravity
0.868
폭발한계
3.0-20.0%(V)
수용성
물과 반응
감도
Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN
1633434
InChIKey
YGHUUVGIRWMJGE-UHFFFAOYSA-N
CAS 데이터베이스
1066-35-9(CAS DataBase Reference)
NIST
Silane, chlorodimethyl-(1066-35-9)
EPA
Silane, chlorodimethyl- (1066-35-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F,C,F+
위험 카페고리 넘버 11-34-12-35-20-14/15
안전지침서 16-26-36/37/39-45-9-43
유엔번호(UN No.) UN 2988 4.3/PG 1
WGK 독일 1
F 고인화성물질 10-21
TSCA Yes
위험 등급 3
포장분류 I
HS 번호 29310095
유해화학물질 필터링 2016-1-729(신규화학물질)
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 클로로디메틸실란 및 이를 25% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H224 극인화성 액체 및 증기 인화성 액체 구분 1 위험
H261 물과 접촉시 인화성가스를 발생시킴 물반응성 물질 및 혼합물 구분 2
구분 3
위험
경고
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H331 흡입하면 유독함 급성 독성 물질 흡입 구분 3 위험 GHS hazard pictograms P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P231+P232 불활성 기체 하에서 취급하고, 습기를 방지하시오.
P233 용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
4
3 0
W

디메틸클로로실란 MSDS


Chlorodimethylsilane

디메틸클로로실란 C화학적 특성, 용도, 생산

화학적 성질

Colorless clear liquid

용도

Chlorodimethylsilane is used to prepare vinyldimethylsilanols for palladium-catalyzed cross-coupling with aryl iodides. Chlorodimethylsilane in combination with a tertiary amine such as triethylamine is another useful reagent for the synthesis of hydrodimethylsilyl ethers, especially for large scale preparations.

주요 응용

The popular uses of chlorodimethylsilane are listed as below:
Will form high-boiling polymeric by-products with aqueous work-up.
A monomer ('building block') in the production of silicone polymers. Silicone polymers may be oils, greases, rubbers and resins and have a wide-range of uses.
In the electronics industry for the production of ultra-pure polysilicon and in the manufacture of semiconductors and photovoltaics.
Although the end uses of products made from chlorodimethylsilane will vary, it can be assumed that due to its highly reactive nature, no residual unreacted material will be present in any of the final products.

일반 설명

A colorless fuming liquid with a pungent, burning odor. Flash point -18°F. Boiling point 95°F. Density about 6.9 lb / gal. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.

공기와 물의 반응

Highly flammable. Reacts violently on contact with water to liberate heat and hydrogen chloride gas.

반응 프로필

Chlorosilanes, such as DIMETHYLCHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.

건강위험

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

화재위험

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

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