1,1-[옥시비스(에틸레니옥시)]디에틸렌

1,1-[옥시비스(에틸레니옥시)]디에틸렌
1,1-[옥시비스(에틸레니옥시)]디에틸렌 구조식 이미지
카스 번호:
764-99-8
한글명:
1,1-[옥시비스(에틸레니옥시)]디에틸렌
동의어(한글):
1,1-[옥시비스(에틸레니옥시)]디에틸렌
상품명:
Diethylene glycol divinyl ether
동의어(영문):
Dvedeg;Divinylcarbitol;1,1’-[Oxybis(2,1;Bis(2-vinyloxyethyl)ether;ether,bis(2-vinyloxyethyl);1,5-Divinyloxy-3-oxapentane;DIETHYLENGLYCOLDIVINYLETHER;divinyletherdiethylenglykolu;Ether, bis[2-(vinyloxy)ethyl];3,6,9-Trioxaundeca-1,10-diene
CBNumber:
CB3730649
분자식:
C8H14O3
포뮬러 무게:
158.2
MOL 파일:
764-99-8.mol
MSDS 파일:
SDS

1,1-[옥시비스(에틸레니옥시)]디에틸렌 속성

녹는점
-21°C
끓는 점
198-199 °C (lit.)
밀도
0.968 g/mL at 25 °C (lit.)
증기압
17Pa at 20℃
굴절률
n20/D 1.446(lit.)
인화점
160 °F
저장 조건
Store below +30°C.
물리적 상태
투명한 액체
색상
무색 내지 거의 무색
수용성
물에 불용성.
감도
Light Sensitive
BRN
1752316
InChIKey
SAMJGBVVQUEMGC-UHFFFAOYSA-N
LogP
1.8 at 23℃
CAS 데이터베이스
764-99-8(CAS DataBase Reference)
NIST
Ethene, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-(764-99-8)
EPA
Ethene, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- (764-99-8)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험 카페고리 넘버 36/38
안전지침서 26-36
WGK 독일 2
RTECS 번호 KN3850000
TSCA Yes
HS 번호 2909 19 90
독성 LD50 oral in rat: 3730mg/kg
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H227 가연성 액체 인화성 액체 구분 4 경고 P210, P280, P370+P378, P403+P235,P501
H303 삼키면 유해할 수 있음 급성 독성 물질 - 경구 구분 5 P312
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P370+P378 화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
P403+P235 환기가 잘 되는 곳에 보관하고 저온으로 유지하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
2
0 0

1,1-[옥시비스(에틸레니옥시)]디에틸렌 C화학적 특성, 용도, 생산

화학적 성질

diethylene glycol divinyl ether is monomeric in character and is used as a chemical intermediate or as a crosslinking agent. Addition of isocyanic acid produces secondary diisocyanates. Divinyl ethers hydrolyze to the glycol and acetaldehyde. Chlorine or bromine add to the double bonds. Reaction with an alcohol in the presence of water produces a diacetal. Polymerization of divinyl ether of diethylene glycol with acidic catalysts produce crosslinked gels. Unsaturated polyesters, crosslinked with styrene, have been made noncorrosive to metals through use of divinyl ethers to reduce hydroxyl ond acid numbers.

화학적 성질

Diethylene glycol divinyl ether (DEGDVE) is a colorless and transparent liquid with a boiling point of 198 °C under atmospheric pressure. It is miscible with alcohol, ether, ester and aromatic hydrocarbon, but only slightly soluble in water. Both DEGMVE and DEGDVE are chemical active and easy to be polymerized, and a small amount of NaOH is often added as a polymerization inhibitor.

용도

Diethylene glycol divinyl ether is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

주요 응용

Diethylene glycol divinyl ether (DEGDVE) has attracted much attention due to the homopolymerization and structural diversity of copolymerization products, and it is often used as a cross-linking agent in various functional materials. Hydrogels are hydrophilic network polymers that absorb large amounts of water but are insoluble in water. The properties of high water content and insolubility in water make the materials widely used in biomedical fields such as drug delivery systems, biosensors, contact lenses, catheters, and wound dressings. Using DEGDVE as a cross-linking agent and 60Co as γ-radiation light source, hydrogels were prepared by radiation copolymerization of hydrophilic ethylene glycol monovinyl ether, hydrophobic BVE, and acidic acrylic acid. The resulting hydrogels were pH- and temperature-sensitive functional materials.
Using DEGDVE as a cross-linking agent, 2-acrylamido-2-methylpropanesulfonic acid and sodium styrene sulfonate as monomers, a plugging agent with high-temperature resistance and salt resistance was synthesized by emulsion polymerization, which has practical significance in solving the problem of water production in oil wells and plays a vital role in improving oil recovery ratio.
A three-dimensional substance with a special space structure can be synthesized by cross-linking copolymerization with DEGDVE and used as a modified substrate material. For example, cross-linking copolymerization of methyl vinyl sulfide with DEGDVE gave a solid polymer with a crown structure, which was modified and used as active matrices of solid superbases for ethynylation of acetone and vinylation of diethylene glycol or ethylene glycol.

1,1-[옥시비스(에틸레니옥시)]디에틸렌 준비 용품 및 원자재

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