프로필렌

프로필렌 속성

프로필렌 C화학적 특성, 용도, 생산

물성

인 브롬화물, 무색 액체, 자극 냄새, 공기 중의 강한 연기, 독성, 오용 또는 먼지와 액체의 흡입으로 알려진 삼 브롬화 인은 심각하게 유독합니다. 브롬화 수소와 아인산은 물의 존재 하에서 폭력적인 반응으로 형성되어 자극적 인 증기를 발생시키고 부식성 화상을 유발합니다. 증기와 액체는 눈, 점막, 피부 및 호흡기에 심한 자극을 주어 화상을 입을 수 있으며, 때때로 저농도의 증기를 흡입하면 호흡기가 손상 될 수 있습니다. 쉬운 가수 분해.

개요

Propylene is a colorless, fl ammable gas that follows ethylene as the second simplest alkene hydrocarbon. It has an odor similar to garlic and has wide use in the chemical industry as an intermediate in the synthesis of other derivatives such as polypropylene, propylene oxide, isopropyl alcohol, acetone, and acrylonitrile. The production of propylene is similar to ethylene and is obtained through steam cracking of hydrocarbon feedstocks. Steam cracking is a process used to break molecules into smaller molecules by injecting the catalysts with steam.

화학적 성질

Propylene is a colorless gas. Slight odor. The Odor Threshold is 23 ppm.

용도

In polymerized form as polypropylene for plastics and carpet fibers. Chemical intermediate in the manufacture of acetone, isopropylbenzene, isopropanol, isopropyl halides, propylene oxide, acrylonitrile, cumene.

정의

A gaseous alkene. Propene is not normally present in the gaseous crude-oil fraction but can be obtained from heavier fractions by catalytic cracking. This is the principal industrial source. Propene is the organic starting material for the production of propan-2-ol, required for the manufacture of propanone (acetone), and the starting material for the production of polypropene (polypropylene).

일반 설명

PROPYLENE is a colorless gas with a faint petroleum like odor. PROPYLENE is shipped as a liquefied gas under its own vapor pressure. For transportation PROPYLENE may be stenched. Contact with the liquid can cause frostbite. PROPYLENE is easily ignited. The vapors are heavier than air. Any leak can either be liquid or vapor. PROPYLENE can asphyxiate by the displacement of air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. PROPYLENE is used to make other chemicals. Can cause explosion.

공기와 물의 반응

Highly flammable.

반응 프로필

During an experiment to produce lactic acid by oxidizing PROPYLENE with nitrogen peroxide, a violent explosion occurred. These mixtures (olefins and nitrogen peroxide) form extremely unstable nitrosates or nitrosites (Comp. Rend. 116:756 1893). Contact of very cold liquid PROPYLENE with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid PROPYLENE contacts water in a closed container.

위험도

Asphyxiant. Highly flammable, danger- ous fire risk, explosive limits in air 2–11%. Upper respiratory tract irritant. Questionable carcinogen.

건강위험

Moderate concentration in air causes dizziness, drowsiness, and unconsciousness. Contact with liquefied PROPYLENE will cause ``freezing burn.''

화재위험

Behavior in Fire: Containers may explode. Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back.

상품설명

테르피네올은 소나무 오일, 라벤더 오일, 감마선 오일, 오렌지 잎 오일, 오렌지 오일 및 오렌지 오일로도 알려져 있습니다. 이것은 테레빈 유에 알파 피넨이나 베타 피넨의 수화 작용으로 수분과 탈수에 의해 얻어지는 향신료의 일종입니다.

Safety Profile

A simple asphpant. No irritant effects from hgh concentrations in gaseous form. When compressed to liquid form, can cause skin burns from freezing effects of rapid evaporation on tissue. Questionable carcinogen. Flammable gas and very dangerous fire hazard when exposed to heat, flame, or oxidlzers. Explosive in the form of vapor when exposed to heat or flame. Under unusual conditions, i.e., 955 atm pressure and 327'℃, it has been known to explode. Explodes on contact with trifluoromethyl hypofluorite. Explosive polymerization is initiated by lithium nitrate + sulfur dioxide. Reacts with oxides of nitrogen to form an explosive product. Dangerous; can react vigorously with oxidizing materials. To fight fire, stop flow of gas. Used in production of fabricated polymers, fibers, and solvents, in production of plastic products and resins. For effects of simple asphyxiants, see ARGON.

잠재적 노출

Propylene is used in production of fabricated polymers, fibers, polypropylene resins; solvents, isopropyl alcohol, propylene dimer, and trimer as gasoline components and detergent raw materials; propylene oxide; cumene, synthetic glycerol; isoprene, and oxo-alcohols.

Carcinogenicity

Exposure of rats and mice to 200, 1000, or 5000 ppm propene 7 h/day, 5 days/week for 18–24 months did not reveal any carcinogenic effects in either species. In another study with exposures of 5,000 and 10,000 ppm, rats exhibited non-neoplastic lesions in the nasal cavity. These consisted of hyperplasia in female rats exposed to the high concentrations, and squamous metaplasia in female rats exposed to both concentrations and in male rats exposed to the low concentration. Inflammatory changes occurred also in male rats of both exposure groups.

환경귀착

Propene degrades in the atmosphere by reaction with photochemically produced hydroxyl radicals with a half-life of 14.6 h. It also reacts in air with ozone and nitrate radicals with half-lives of 1 and 4 days, respectively. In soil, volatilization is expected to be the primary fate due to propene’s high vapor pressure. Volatilization also occurs from water, while remaining propene is readily degraded by microorganisms. This results in propene being unlikely to bioaccumulate or bioconcentrate in soil or aquatic organisms.

운송 방법

UN1077 Propylene, Hazard Class: 2.1; Labels: 2.1-Flammable gas. UN1075 Petroleum gases, liquefied or Liquefied petroleum gas, Hazard Class: 2.1; Labels: 2.1- Flammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the com- pressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylin- ders without the express written permission of the owner.

Purification Methods

Purify it by freeze-pump-thaw cycles and trap-to-trap distillation. [Beilstein 1 IV 725.]

비 호환성

Propylene forms explosive mixture with air. Violent reaction with oxidizers (chlorates, nitrates, per- oxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, and many other compounds. Able to form unstable peroxides; can polymerize, especially in heat, direct sunlight, oxidizers and other chemicals.

폐기물 처리

Return refillable compressed gas cylinders to supplier. Use a licensed professional waste disposal service to dispose of this material, perhaps using controlled incineration. All federal, state, and local environ- mental regulations must be observed.

프로필렌 준비 용품 및 원자재

원자재

준비 용품

프로필렌 공급 업체

공급자	전화	이메일	국가	제품 수	이점
Guangzhou Yuejia Gas Co., Ltd	400-6377517 19876107228	linfeng@yigas.cn	China	39	58
Central China Special Gas (CCSG) Co., Ltd	0734-8755555 15674722888	lyq@ccsg.cn	China	405	58
Jinan Wanli Gas Co., LTD	13245484555	3864308976@qq.com	China	146	58
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Spectrum Chemical Manufacturing Corp.	021-021-021-67601398-809-809-809 15221380277	marketing_china@spectrumchemical.com	China	9643	60
TOKYO CHEMICAL INDUSTRY CO., LTD.	03-36680489	Sales-JP@TCIchemicals.com	Japan	28364	80
Chizhou Kailong Import and Export Trade Co., Ltd.		xg01_gj@163.com	China	9413	50
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51389	80
Shanghai wechem chemical co., ltd	18824865657	2684615189@qq.com	China	428	58
AoboRui (Tianjin) Co., Ltd.	022-65675308 18310521067	23034325@qq.com	China	99	55

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