알릴글리시딜에테르
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알릴글리시딜에테르 속성
- 녹는점
- -100 °C
- 끓는 점
- 154 °C(lit.)
- 밀도
- 0.962 g/mL at 25 °C(lit.)
- 증기 밀도
- 3.9 (vs air)
- 증기압
- 4.7 mm Hg ( 25 °C)
- 굴절률
- n
20/D 1.433(lit.)
- 인화점
- 135 °F
- 저장 조건
- Store at <= 20°C.
- 용해도
- 50g/L(20°C)
- 물리적 상태
- 액체
- 색상
- 무색의
- Specific Gravity
- 0.962
- 수용성
- 50g/L(20℃)
- BRN
- 105871
- Henry's Law Constant
- (x 10-6 atm?m3/mol): 3.83 at 20 °C (approximate - calculated from water solubility and vapor pressure)
- 노출 한도
- NIOSH REL: TWA 5 ppm (22 mg/m3), STEL 10 ppm (44 mg/m3), IDLH 50 ppm; OSHA PEL: ceiling 10 ppm; ACGIH TLV: TWA 5 ppm, STEL 10 ppm.
- 안정성
- 안정적인. 타기 쉬운. 강한 산화제, 산, 염기와 호환되지 않습니다. 공기와 접촉하면 보관 시 과산화물을 형성할 수 있습니다.
- InChIKey
- LSWYGACWGAICNM-UHFFFAOYSA-N
- LogP
- 0.45 at 25℃
- CAS 데이터베이스
- 106-92-3(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xn | ||
---|---|---|---|
위험 카페고리 넘버 | 10-20/22-37/38-40-41-43-52/53-62-68 | ||
안전지침서 | 24/25-26-36/37/39-61 | ||
유엔번호(UN No.) | UN 2219 3/PG 3 | ||
WGK 독일 | 3 | ||
RTECS 번호 | RR0875000 | ||
자연 발화 온도 | 264 °C | ||
TSCA | Yes | ||
위험 등급 | 3 | ||
포장분류 | III | ||
HS 번호 | 29109000 | ||
유해 물질 데이터 | 106-92-3(Hazardous Substances Data) | ||
독성 | LD50 orally in Rabbit: 922 mg/kg LD50 dermal Rabbit 2550 mg/kg | ||
IDLA | 50 ppm | ||
기존화학 물질 | KE-29751 |
알릴글리시딜에테르 C화학적 특성, 용도, 생산
화학적 성질
Allyl glycidyl ether is a stable, colorless, flammable liquid with a pleasant odor. It is incompatible with strong oxidizers agents, acids, and bases. It may form peroxides in storage if in contact with air.물리적 성질
Clear, colorless, watery, combustible liquid with a strong, pleasant odor. An odor threshold value of 47 mg/m3 was reported (quoted, Verschueren, 1983).용도
Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered as the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyltrimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethane.생산 방법
AGE is manufactured through the condensation of allyl alcohol and epichlorohydrin with subsequent dehydrochlorination with caustic to form the epoxy ring.일반 설명
A colorless liquid with a pleasant odor. Flash point 135°F. Slightly less dense than water and insoluble in water. Hence floats on water. Poisonous by ingestion and mildly toxic by inhalation and skin contact. Very irritating to skin and eyes. Used to make other chemicals.공기와 물의 반응
Flammable. Insoluble in water.반응 프로필
Allyl glycidyl ether reacts violently with oxidizing agents. Can form peroxides. Polymerizes readily [Handling Chemicals Safely 1980. p.128].위험도
Skin, eye, and upper respiratory tract irri- tant, and dermatitis. Questionable carcinogen.건강위험
Occupational workers exposed to allyl glycidyl ether develop severe symptoms of poisoning that include, but are not limited to, irritation of the eyes, redness, pain, blurred vision, deep skin burns, respiratory system; causes damage of the mucous membranes, dermatitis, burning sensation, shortness of breath, headache, drowsiness, dullness, nausea, vomiting, pulmonary edema, narcosis, possible hematopoietic and reproductive effects. Acute exposure may cause CNS depression. The major target organs include the eyes, skin, respiratory system, blood, and the reproductive system.화재위험
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.색상 색인 번호
Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered to be the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyl trimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethaneSafety Profile
Confirmed animal carcinogen. Poison by ingestion. Moderately toxic by inhalation and skin contact. Mutation data reported. A severe skin and eye irritant. Can cause central nervous system depression and pulmonary edema. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical.When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDSAllyl glycidyl ether has an LD50 of 390 mg/kg (mouse, oral) and an LD50 of 1600 mg/kg (rat, oral). In rabbits, the dermal LD50 is 2550 mg/kg. Inhalational toxicity has been estimated: LC50 = 270 ppm (mice, 4 h) and 670 ppm (rats, 8 h)
잠재적 노출
Used as a solvent and emulsifier; making epoxy resins, chlorinated compounds; and rubber.Carcinogenicity
In a 2-year inhalation carcinogenicity study in Osborne Mendel rats and B6C3F1 mice (50 of each sex at each exposure level), animals were exposed to concentrations of 0, 5, or 10 ppm AGE, 6 h/day, 5 days/ week. Although occasional respiratory epithelial tumors were observed, the NTP concluded the data provided only equivocal evidence of carcinogenicity in male rats and female mice. No evidence was obtained to support a carcinogenic effect in female rats. Some evidence was provided for a carcinogenic response in male mice, which included three adenomas of the respiratory epithelium, dysplasia in four mice, and focal basal cell hyperplasia of the respiratory epithelium in the nasal passages of seven mice .환경귀착
Biological. Bridié et al. (1979) reported BOD and COD values of 0.06 and 1.99 g/g using filtered effluent from a biological sanitary waste treatment plant. These values were determined using a standard dilution method at 20 °C for a period of 5 d. The ThOD for allyl glycidyl ether is 2.11 g/g.Chemical/Physical. Hydrolysis of the epoxide ring is likely forming 1-allyloxy-2,3- dihydroxypropane (Perez and Osterman-Golkar, 2000).
저장
Allyl glycidyl ether should be kept stored in a cool, dark, fi reproof area separated from strong oxidants, strong bases, and strong acids.운송 방법
UN2219 Allyl glycidal ether, Hazard Class: 3; Labels: 3-Flammable liquid비 호환성
May form explosive mixture with air. Contact with acids or bases may cause explosive polymerization. Contact with oxidizers or amines may cause fire and explosions.폐기물 처리
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.주의 사항
During use and/or handling of allyl glycidyl ether, occupational workers should not be near open flames, sparks, or smoking areas. For temperatures above 48°C, use a closedsystem ventilation and explosion-proof electrical equipment. Workers should use protective gloves, protective clothing, and avoid all contact.알릴글리시딜에테르 준비 용품 및 원자재
원자재
준비 용품
알릴글리시딜에테르 공급 업체
글로벌( 308)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 |
daisy@crovellbio.com | China | 5964 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 |
jack.li@time-chemicals.com | China | 1807 | 55 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 |
info@tnjchem.com | China | 2989 | 55 |
Shanxi Naipu Import and Export Co.,Ltd | +86-13734021967 +8613734021967 |
kaia@neputrading.com | China | 1011 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 |
sales@sdzschem.com | China | 2931 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8823 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |