비스 (클로로메틸) 케톤
|
|
비스 (클로로메틸) 케톤 속성
- 녹는점
- 43 °C
- 끓는 점
- 73 °C733.4 mm Hg(lit.)
- 밀도
- 1.383 g/mL at 25 °C(lit.)
- 증기 밀도
- 4.38 (vs air)
- 증기압
- <0.1 mm Hg ( 20 °C)
- 굴절률
- 1.4400
- 인화점
- 193 °F
- 저장 조건
- Refrigerator (+4°C) + Poison room
- 용해도
- 알코올: 매우 용해됨
- 물리적 상태
- 크리스탈
- 색상
- 흰색 또는 무색
- Specific Gravity
- 1.383
- 수소이온지수(pH)
- 4.2 (10g/l, H2O, 20℃)
- 수용성
- 27.9g/L(20℃)
- Merck
- 14,3052
- BRN
- 605456
- Dielectric constant
- 14.0（20℃）
- CAS 데이터베이스
- 534-07-6(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | T+,F | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 24-26/28-34-68-36/37/38-11 | ||
| 안전지침서 | 26-36/37/39-45-28A-1-28-16 | ||
| 유엔번호(UN No.) | UN 3286 3/PG 2 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | UC1430000 | ||
| F 고인화성물질 | 19 | ||
| TSCA | Yes | ||
| 위험 등급 | 6.1 | ||
| 포장분류 | II | ||
| HS 번호 | 29147090 | ||
| 유해 물질 데이터 | 534-07-6(Hazardous Substances Data) | ||
| 독성 | mmo-sat 1250 ng/plate MUREAV 157,111,85 | ||
| 기존화학 물질 | KE-10204 |
비스 (클로로메틸) 케톤 C화학적 특성, 용도, 생산
화학적 성질
White or colorless crystals용도
1,3-Dichloroacetone was used as acceptor substrate in the cross-aldol reaction with donor substrates such as acetone, cyclopentanone and cyclohexanon일반 설명
A crystalline solid. Denser than water and insoluble in water. Inhalation of dust or powder may cause adverse health reactions.공기와 물의 반응
Insoluble in water.반응 프로필
A halogenated ketone. Ketones are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.건강위험
1,3-Dichloroacetone may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control water may give off poisonous gases. Runoff from fire control or dilution water may cause pollution.화재위험
When heated to decomposition, 1,3-Dichloroacetone emits highly toxic fumes of chlorides. 1,3-Dichloroacetone may burn but does not ignite readily. Container may explode in heat of fire.Safety Profile
Poison by inhalation. Mutationdata reported. A systemic irritant by ingestion andinhalation routes. Dangerous; whenheated to decomposition it emits highly toxic fumes ofCl-.잠재적 노출
Formerly extensively used in textiles (especially polyester fabrics) and still employed in polyurethane foams, textile backcoating and adhesives.운송 방법
UN2649 1,3-Dichloroacetone, Hazard class: 6.1; Labels: 6.1—Poisonous materials.Purification Methods
Crystallise it from CCl4, CHCl3 or *benzene and/or distil under vacuum [Conant & Quayle Org Synth Coll Vol I 211 1941, Hall & Sirel J Am Chem Soc 74 836 1952]. It is dimorphic [Daasch & Kagarise J Am Chem Soc 77 6156 1955]. The oxime has m 130-131o, b 106o/25mm [Arzneimittel-Forsch 8 638 1958]. [Beilstein 1 IV 3219.]비스 (클로로메틸) 케톤 준비 용품 및 원자재
원자재
준비 용품
(2-(TRIFLUOROMETHYL)THIAZOL-4-YL)METHANAMINE
2-(4-(CHLOROMETHYL)THIAZOL-2-YL)GUANIDINE
(S)-((2-Guanidino-4-thiazolyl)methylisothiourea dihydrochloride
플루코나졸
3-(2-Guanidino-thiazol-4-yl-methylthio)-propionitrile
FAMOTI디NE
5-CHLORO-4-(CHLOROMETHYL)-1,2,3-THIADIAZOLE, 97%, 97
NIZA티딘
4-(Chloromethyl)thiazole
디클로로아세톤
4-Chloromethyl-2-phenyl-oxazole
4-CHLOROMETHYL-2-METHYLTHIAZOLE HYDROCHLORIDE
디클로로(2,3-)-1-프로판올
비스 (클로로메틸) 케톤 관련 검색:
시트르산(구연산) 달라폰 클로로아세톤 아세토초산 o-아니시다이드 2,6-디클로로인도페놀 나트륨 염 2, 6-디클로로페놀인도페놀 2,6-디클로로인도페놀 나트륨 염 나트륨 부티르산 부탄 산 디클로로아세톤 사염화-1,4-벤조퀴논 비스 (클로로메틸) 케톤
1,1,3-Trichloroacetone
2,3-Dichloropropionitrile
2,6-DICHLORO-1,4-BENZOQUINONE
1，1，3，3-Tetrachloroacetone
Hexachloroacetone
1,1,3,3-Tetrafluoro-1,3-dichloroacetone